Method for producing low-halogen polybiphenylsulfone polymers

Patent metadata

Field	Value
Publication number	US-9469732-B2
Application number	US-201514814584-A
Country	US
Kind code	B2
Filing date	Jul 31, 2015
Priority date	Aug 20, 2009
Publication date	Oct 18, 2016
Grant date	Oct 18, 2016

Abstract

The present invention relates to a process for the production of low-halogen-content polybiphenyl sulfone polymers, to the resultant polybiphenyl sulfone polymers, to polybiphenyl sulfone polymers having less than 400 ppm content of polymer-bonded halogen, to thermoplastic molding compositions comprising these polybiphenyl sulfone polymers, and to their use for the production of moldings, of fibers, of films, of membranes, or of foams.

First claim

The invention claimed is:

1. A polybiphenyl sulfone polymer obtained by a process comprising
(a) providing components (a1) composed of at least one aromatic dihydroxy compound and (a2) composed of at least one aromatic sulfone compound having two halogen substituents, where component (a1) comprises 4,4′-dihydroxybiphenyl, and then
(b) reacting component (a2) with a molar excess of component (a1) in a solvent, where water and/or a metal hydroxide is added during or after the reaction,
wherein according to step (b) the addition of water and/or of a metal hydroxide takes place at a conversion of at least 90%, and
wherein the polymer has less than 400 ppm content of polymer-bonded halogen.

2. A thermoplastic molding composition comprising the polybiphenyl sulfone polymer according to claim 1 .

3. The thermoplastic molding composition according to claim 2 , further comprising at least one polymer selected from the group consisting of polyether sulfone (PES), polysulfone (PSU), polyetherimide, polyphenylene sulfide, polyetherether ketone, polyimide, and poly-p-phenylene.

4. A molding, fiber, film, membrane, or foam comprising the thermoplastic molding composition according to claim 2 .

5. A process for the production of moldings, of fibers, of films, of membranes, or of foams which comprises utilizing the polybiphenyl sulfone polymer according to claim 1 .

6. The polybiphenyl sulfone polymer according to claim 1 , where component (a2) is 4,4′-dichlorodiphenyl sulfone.

7. The polybiphenyl sulfone polymer according to claim 1 , where the metal hydroxide is an alkali metal hydroxide.

8. The polybiphenyl sulfone polymer according to claim 1 , where the solvent comprises N-methylpyrrolidone.

9. The polybiphenyl sulfone polymer according to claim 1 , where the molar ratio of component (a1) to (a2) is from 1.005 to 1.2.

10. The polybiphenyl sulfone polymer according to claim 1 , where component (a1) comprises at least 50% by weight of 4,4′-dihydroxybiphenyl.

11. The polybiphenyl sulfone polymer according to claim 1 , where component (a1) is 4,4′-dihydroxybiphenyl.

12. The polybiphenyl sulfone polymer according to claim 1 , where at least one aromatic organic monochloro compound is added as component (a3) during or after the reaction according to step (b).

13. The polybiphenyl sulfone polymer according to claim 12 , where component (a3) is 4-monochloro-diphenyl sulfone.

14. The polybiphenyl sulfone polymer according to claim 12 , where the ratio ((a1)−(a2))/(a3) multiplied by two is from 0.98 to 1.02, where (a1), (a2), and (a3) are the molar amounts of components (a1), (a2), and (a3) used.

15. The polybiphenyl sulfone polymer according to claim 14 , where the ratio ((a1)−(a2))/(a3) multiplied by two is one.

16. The polybiphenyl sulfone polymer according to claim 1 , where, following step (b), according to step (c) a reaction takes place with at least one aliphatic organic halogen compound.

17. The polybiphenyl sulfone polymer according to claim 1 , where, following step (b), according to step (c) a reaction takes place with at least one alkyl chloride.

18. The polybiphenyl sulfone polymer according to claim 17 , where the alkyl chloride is methyl chloride.

Assignees

• Basf Se

Inventors

• Weber Martin
• Maletzko Christian
• Lange Gerhard
• ERBES Jörg
• Dietrich Matthias
• Inchaurrondo Nicolas
• Sigwart Christoph

Classifications

• C08L81/06

  Polysulfones; Polyethersulfones · CPC title

• C08G75/23 Primary

  Polyethersulfones · CPC title

• C08G75/20 Primary

  Polysulfones · CPC title

• C08J5/18

  Manufacture of films or sheets · CPC title

• C08J2381/06

  Polysulfones; Polyethersulfones · CPC title