Method for transferring carbon nanotube array and method for forming carbon nanotube structure

Patent metadata

Field	Value
Publication number	US-9469540-B2
Application number	US-201414521237-A
Country	US
Kind code	B2
Filing date	Oct 22, 2014
Priority date	Jun 18, 2014
Publication date	Oct 18, 2016
Grant date	Oct 18, 2016

Abstract

A method for transferring a carbon nanotube array is provided. A substitute substrate, a growing substrate, and a carbon nanotube array grown on the growing substrate are provided. The carbon nanotube array has a bottom surface adjacent to the growing substrate and a top surface away from the growing substrate. The substitute substrate is placed on the top surface of the carbon nanotube array and PVA solution is sandwiched between the substitute substrate and the carbon nanotube array. The PVA solution is frozen between the substitute substrate and the carbon nanotube array. The substitute substrate is separated from the growing substrate to separate the bottom surface of the carbon nanotube array from the growing substrate. The solvent in the solid PVA solution is removed and only PVA is left between the substitute substrate and the carbon nanotube array. A method for forming a carbon nanotube structure is also provided.

First claim

What is claimed is:

1. A method for transferring a carbon nanotube array, the method comprising:
providing a substitute substrate, a growing substrate, and a carbon nanotube array grown on the growing substrate; the carbon nanotube array comprises a bottom surface adjacent to the growing substrate and a top surface away from the growing substrate; and the carbon nanotube array comprises an ability to have a carbon nanotube structure drawn therefrom;
placing the substitute substrate on the top surface of the carbon nanotube array and sandwiching a liquid solution of polyvinyl alcohol between the substitute substrate and the carbon nanotube array, and the liquid solution of polyvinyl alcohol comprising polyvinyl alcohol dissolved in a solvent;
solidifying the liquid solution of polyvinyl alcohol between the substitute substrate and the carbon nanotube array into solid medium;
separating the substitute substrate from the growing substrate, thereby separating the bottom surface of the carbon nanotube array from the growing substrate; and
removing the solvent in the solid medium and leaving the polyvinyl alcohol between the substitute substrate and the carbon nanotube array, and the carbon nanotube array still having the ability to have a carbon nanotube structure drawn therefrom.

2. The method of claim 1 , wherein the carbon nanotube structure is a carbon nanotube film or a carbon nanotube wire.

3. The method of claim 1 , wherein the carbon nanotube structure comprises a plurality of carbon nanotubes joined end to end.

4. The method of claim 1 , wherein the liquid solution of polyvinyl alcohol is in a shape of a plurality of droplets, mist, or film.

5. The method of claim 4 , wherein a diameter of the droplets and a thickness of the film is in a range from about 10 nanometers to about 300 microns.

6. The method of claim 1 , wherein the sandwiching the liquid solution of polyvinyl alcohol between the substitute substrate and the carbon nanotube array comprises:
forming the liquid solution of polyvinyl alcohol on the top surface of the carbon nanotube array; and
contacting a surface of the substitute substrate and the liquid solution of polyvinyl alcohol on the top surface with each other.

7. The method of claim 6 , wherein the solidifying the liquid solution of polyvinyl alcohol between the substitute substrate and the carbon nanotube array comprises contacting the substitute substrate, having a temperature below a freezing point with the liquid solution of polyvinyl alcohol, on the top surface of the carbon nanotube array.

8. The method of claim 1 , wherein the sandwiching the liquid solution of polyvinyl alcohol between the substitute substrate and the carbon nanotube array comprises:
forming the liquid solution of polyvinyl alcohol on a surface of the substitute substrate; and
contacting the top surface of the carbon nanotube array and the liquid solution of PVA polyvinyl alcohol on the surface of the substitute substrate with each other.

9. The method of claim 8 , wherein the solidifying the liquid solution of polyvinyl alcohol between the substitute substrate and the carbon nanotube array comprises exposing a lamination of the growing substrate, the carbon nanotube array, the liquid solution of polyvinyl alcohol, and the substitute substrate to an environment having an internal temperature below a freezing point of the solvent in the liquid solution of polyvinyl alcohol.

10. The method of claim 1 , wherein a weight percentage of the liquid solution of polyvinyl alcohol is equal to or smaller than 2%.

11. The method of claim 1 , wherein a weight percentage of the liquid solution of polyvinyl alcohol is from about 0.1% to about 2%.

12. The method of claim 1 , wherein the carbon nanotube array comprises a plurality of carbon nanotubes, and during the separating the carbon nanotube array from the growing substrate, substantially all carbon nanotubes are simultaneously detached from the growing substrate.

13. The method of claim 1 , wherein the carbon nanotube array comprises a plurality of carbon nanotubes, and the plurality of carbon nanotubes of the carbon nanotube array are detached from the growing substrate along a growing direction of the plurality of carbon nanotubes.

14. The method of claim 1 , wherein the growing substrate comprises a growing surface for growing the carbon nanotube array, and a moving direction of at least one of the substitute substrate and the growing substrate is substantially perpendicular to the growing surface of the growing substrate during the separating of the at least one of the substitute substrate and the growing substrate.

15. A method for transferring a carbon nanotube array, the method comprising:
providing a first substrate, a second substrate, and a carbon nanotube array grown on the first substrate, the carbon nanotube array having a bottom surface adjacent to the first substrate and a top surface away from the first substrate, and the carbon nanotube array having an ability to have a carbon nanotube structure drawn therefrom;
placing the second substrate on the top surface of the carbon nanotube array and sandwiching a liquid solution of polyvinyl alcohol between the second substrate and the carbon nanotube array, and the liquid solution of polyvinyl alcohol comprising polyvinyl alcohol dissolved in a solvent;
solidifying the liquid solution of polyvinyl alcohol between the second substrate and the carbon nanotube array into a solid medium;
separating the second substrate from the first substrate, thereby separating the bottom surface of the carbon nanotube array from the first substrate; and
removing the solvent in the solid medium and leaving the polyvinyl alcohol between the second substrate and the carbon nanotube array, and the carbon nanotube array still having the ability to have a carbon nanotube structure drawn therefrom.

16. A method for forming a carbon nanotube structure, the method comprising:
providing a substitute substrate, a growing substrate, and a carbon nanotube array grown on the growing substrate, the carbon nanotube array having a bottom surface adjacent to the growing substrate and a top surface away from the growing substrate, and the carbon nanotube array having an ability to have a carbon nanotube structure drawn therefrom;
placing the substitute substrate on the top surface of the carbon nanotube array and sandwiching a liquid solution of polyvinyl alcohol between the substitute substrate and the carbon nanotube array, and the liquid solution of polyvinyl alcohol comprising polyvinyl alcohol dissolved in a solvent;
solidifying the liquid solution of polyvinyl alcohol between the substitute substrate and the carbon nanotube array into a solid medium;
separating the substitute substrate from the growing substrate, thereby separating the bottom surface of the carbon nanotube array from the growing substrate;
removing the solvent in the solid medium and leaving the polyvinyl alcohol between the substitute substrate and the carbon nanotube array, and the carbon nanotube array still having the ability to have a carbon nanotube structure drawn therefrom; and
drawing a plurality of carbon nanotube segments joined end to end by van der Waals attractive force from the carbon nanotube array transferred to the substitute substrate.

Assignees

• Univ Tsinghua
• Hon Hai Prec Ind Co Ltd

Inventors

• Wei Yang
• Wei Hao-Ming
• Fan Shou-Shan

Classifications

• B32B2329/04

  Polyvinylalcohol · CPC title

• B32B2307/202

  Conductive · CPC title

• B32B37/025 Primary

  Transfer laminating · CPC title

• C01B31/0253 Primary

  Chemistry & Metallurgy · mapped topic

• B32B9/007

  comprising carbon, e.g. graphite, composite carbon · CPC title