Reformer tube and apparatus and also process for producing a synthesis gas

Patent metadata

Field	Value
Publication number	US-9469534-B2
Application number	US-201414568825-A
Country	US
Kind code	B2
Filing date	Dec 12, 2014
Priority date	Dec 12, 2013
Publication date	Oct 18, 2016
Grant date	Oct 18, 2016

Abstract

The present invention relates to a reformer tube for producing synthesis gas, e.g., hydrogen, and an apparatus and a process for producing synthesis gas, in particular hydrogen. The reformer tube is configured for directing the flow of starting materials and at least one reaction product in volume streams for the purpose of producing a synthesis gas. The reformer tube has in its interior at least one flow directing device having a first guide device for diverting a first partial volume stream in a direction having a radial component directed away from the longitudinal axis of the reformer tube, and having a second guide device for diverting a second partial volume stream in a direction having a radial component directed towards the longitudinal axis of the reformer tube.

First claim

The invention claimed is:

1. A reformer tube for conducting the flow of starting materials and at least one reaction product in volume streams, said reformer tube comprising:
at least one flow directing device ( 30 ) within the interior ( 12 ) of said reformer tube ( 10 ), said at least one flow directing device ( 30 ) having a first guide device ( 31 ) for diverting a first partial volume stream ( 22 ) in a direction having a radial component directed away from the longitudinal axis ( 11 ) of the reformer tube ( 10 ) and having a second guide device ( 32 ) for diverting a second partial volume stream ( 23 ) in a direction having a radial component directed towards the longitudinal axis ( 11 ) of the reformer tube ( 10 ), and
a bed of catalyst material ( 50 ) positioned within the interior ( 12 ) of said reformer tube downstream of said at least one flow directing device ( 30 ),
wherein said first guide device ( 31 ) is positioned at a smaller distance from the longitudinal axis ( 11 ) of said reformer tube ( 10 ) than said second guide device ( 32 ).

2. The reformer tube according to claim 1 , wherein said tube is used for producing a synthesis gas.

3. The reformer tube according to claim 1 , wherein said flow directing device ( 30 ) is configured as one unit and the first guide device ( 31 ) and the second guide device ( 32 ) are combined within said unit, with the first and second guide devices ( 31 , 32 ) being mechanically joined to one another within the unit.

4. The reformer tube according to claim 3 , wherein said first guide device ( 31 ) and said second guide device ( 32 ) are arranged between two planes ( 34 , 35 ) which are substantially perpendicular to the longitudinal axis ( 11 ) of said reformer tube ( 10 ) in said flow directing device ( 30 ).

5. The reformer tube according to claim 1 , wherein said flow directing device is divided into angle sectors ( 38 ) around the longitudinal axis of said reformer tube, and said flow directing device ( 30 ) has a plurality of first and second guide devices ( 31 , 32 ) which extend radially and are each arranged alternately in neighboring angle sectors ( 38 ).

6. The reformer tube according to claim 1 , wherein said flow directing device is divided into angle sectors ( 38 ) around the longitudinal axis of said reformer tube, and said reformer tube ( 10 ) has a plurality of flow directing devices ( 30 ) which are arranged at different positions in the longitudinal extension direction of said reformer tube ( 10 ), with first and second guide devices ( 31 , 32 ) being arranged alternately in the longitudinal direction of said reformer tube ( 10 ) in the same angle sectors ( 38 ).

7. The reformer tube according to claim 1 , wherein said flow directing device ( 30 ) further comprises a separation element ( 40 ) for separating a volume stream present in the flow path before said flow directing device ( 30 ) in said reformer tube ( 10 ) into the first partial volume stream ( 22 ) and the second partial volume stream ( 23 ).

8. An apparatus for producing a synthesis gas, comprising: a reformer tube ( 10 ) according to claim 1 , a heating device for providing heat in order to heat said reformer tube ( 10 ), and also a membrane for separating off synthesis gas produced in said reformer tube ( 10 ).

9. A process for producing a synthesis gas, said process comprising:
flowing starting materials and at least one reaction product in volume streams through a reformer tube 10 according to according to claim 1 ,
wherein the first partial volume stream ( 22 ) is conducted by said first guide device ( 31 ) of said flow directing device ( 30 ) in a direction having a radial component directed away from the longitudinal axis ( 11 ) of said reformer tube ( 10 ) and the second partial volume stream ( 23 ) is conducted by said second guide device ( 32 ) of said flow directing device ( 30 ) in a direction having a radial component directed towards the longitudinal axis ( 11 ) of said reformer tube ( 10 ).

10. The process for producing a synthesis gas according to claim 9 , wherein said a first a bed of said catalyst material ( 50 ) is positioned upstream of said at least one flow directing device ( 30 ) and a second bed of said catalyst material ( 50 ) is positioned downstream of said at least one flow directing device ( 30 ), and said first and/or second partial volume stream ( 22 , 23 ) flows around said second bed of catalyst material ( 50 ) in said reformer tube ( 10 ).

11. The process for producing a synthesis gas according to claim 9 , wherein said synthesis gas is hydrogen.

12. The reformer tube according to claim 1 , wherein said first guide device and said second guide device are positioned at an angle of maximum 10° from the radial direction of said reformer tube.

13. The reformer tube according to claim 1 , wherein said at least one flow directing device ( 30 ) comprises a first circle and a second circular ring positioned around said first circle, and said first guide device is arranged in said first circle and said second guide device is arranged in said second circular ring.

14. The reformer tube according to claim 13 , wherein a plurality of first guide devices are arranged in said first circle and a plurality of second guide devices are arranged in said second circular ring.

15. The reformer tube according to claim 14 , wherein said flow directing device is divided into angle sectors ( 38 ) around the longitudinal axis of said reformer tube, and said first and second guide devices ( 31 , 32 ) are each arranged alternately in neighboring angle sectors ( 38 ) and extend radially within each of said sectors.

16. The reformer tube according to claim 13 , wherein said flow directing device ( 30 ) further comprises a separation element ( 40 ) for separating a volume stream present in the flow path before said flow directing device ( 30 ) in said reformer tube ( 10 ) into the first partial volume stream ( 22 ) and the second partial volume stream ( 23 ), said separation element ( 40 ) being positioned between said first circle and said second circular ring.

17. The reformer tube according to claim 16 , wherein said separation element is a tube section which is arranged coaxially with said first circle and said second circular ring.

18. The reformer tube according to claim 1 , wherein said first guide device ( 31 ) diverts the first partial volume stream ( 22 ) from a central region ( 13 ) of said reformer tube to a region close to the interior wall ( 14 ) of said reformer tube, and said second guide device ( 32 ) diverts the second partial volume stream ( 23 ) from the region close to the interior wall ( 14 ) of said reformer tube to the central region ( 13 ) of said reformer tube.

19. The reformer tube according to claim 1 , wherein said reformer tube 10 comprises a first a bed of catalyst material ( 50 ) positioned upstream of said at least one flow directing device ( 30 ) and a second bed of catalyst material ( 50 ) positioned downstream of said at least one flow directing device ( 30 ).

Assignees

• Linde Ag

Inventors

• Wawrzinek Klemens
• Nold Michael

Classifications

• C01B2203/0233

  the reforming step being a steam reforming step · CPC title

• B01J8/009

  Membranes, e.g. feeding or removing reactants or products to or from the catalyst bed through a membrane · CPC title

• C01B3/384 Primary

  with external heating of the catalyst · CPC title

• B01J2208/0084

  inside the bed, e.g. baffles · CPC title

• C01B2203/1058

  Nickel catalysts · CPC title