Methods for producing C2 to C5 paraffins using a hybrid catalyst comprising gallium metal oxide
US-12030036-B2 · Jul 9, 2024 · US
US9468918B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9468918-B2 |
| Application number | US-201514702268-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 1, 2015 |
| Priority date | Dec 18, 2009 |
| Publication date | Oct 18, 2016 |
| Grant date | Oct 18, 2016 |
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An aluminum phosphate-modified metal-supported crystalline silicoaluminophosphate NOx-reducing catalyst includes metal-supported crystalline silicoaluminophosphate particles having a surface modified with aluminum phosphate.
Opening claim text (preview).
The invention claimed is: 1. An aluminum phosphate-modified metal-supported crystalline silicoaluminophosphate NOx-reducing catalyst, comprising: metal-supported crystalline silicoaluminophosphate particles having aluminum phosphate on a surface of the particles, the content of aluminum phosphate in the catalyst being 0.1 to 40% by weight in terms of Al 2 O 3 +P 2 O 5 based on the metal-supported crystalline silicoaluminophosphate particles. 2. The aluminum phosphate-modified metal-supported crystalline silicoaluminophosphate NOx-reducing catalyst according to claim 1 , wherein the value of x in (Al 2 ) X .(PO 4 ) 3 representing the aluminum phosphate is 0.1 to 3. 3. The aluminum phosphate-modified metal-supported crystalline silicoaluminophosphate NOx-reducing catalyst according to claim 1 , wherein the crystalline silicoaluminophosphate particles are at least one member selected from the group consisting of SAPO-5, SAPO-11, SAPO-34, and SAPO-37. 4. The aluminum phosphate-modified metal-supported crystalline silicoaluminophosphate NOx-reducing catalyst according to claim 1 , wherein the crystalline silicoaluminnphosphate is SAPO-34. 5. The aluminum phosphate-modified metal-supported crystalline silicoaluminophosphate NOx-reducing catalyst according to claim 1 , wherein the supported metal is a metal of an element selected from the group 8, 9, 10, 11, and 12 elements of the periodic table or a mixture thereof (including an alloy). 6. The aluminum phosphate-modified metal-supported crystalline silicoaluminophosphate NOx-reducing catalyst according to claim 1 , wherein the amount of the metal supported is in a range of 0.1 to 10% by weight in terms of metal.
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