Selective catalytic reduction catalyst system

Patent metadata

Field	Value
Publication number	US-9468915-B2
Application number	US-201414208928-A
Country	US
Kind code	B2
Filing date	Mar 13, 2014
Priority date	Mar 14, 2013
Publication date	Oct 18, 2016
Grant date	Oct 18, 2016

Abstract

Described are SCR catalyst systems comprising a first SCR catalyst composition and a second SCR catalyst composition arranged in the system, the first SCR catalyst composition having a faster DeNOx response time when exposed to ammonia than the second catalyst composition and the second SCR catalyst composition has a higher steady state DeNOx performance than the first catalyst composition. The SCR catalyst systems are useful in methods and systems to catalyze the reduction of nitrogen oxides in the presence of a reductant.

First claim

What is claimed is:

1. A selective catalytic reduction (SCR) catalyst hybrid system for removing NOx from engine exhaust, the system comprising a first SCR catalyst composition and a second SCR catalyst composition arranged in the system, the first SCR catalyst composition having a faster DeNOx response time when exposed to ammonia than the second catalyst composition and the second SCR catalyst composition has a higher steady state DeNOx performance than the first catalyst composition;
wherein the first catalyst composition comprises vanadia/titania stabilized with tungsten; and
wherein the second catalyst composition comprises a metal-exchanged zeolite, excluding Cu-exchanged or Fe-exchanged ZSM-5 or Beta zeolites.

2. The system of claim 1 , wherein the first SCR catalyst composition provides a target DeNOx percentage at a lower ammonia storage level than the second SCR catalyst composition to provide the same DeNOx percentage, and wherein the system provides higher DeNOx steady state performance than a system with only the first catalyst composition.

3. The system of claim 2 , wherein under acceleration conditions in which sudden increases of exhaust temperature are produced, ammonia desorbed from the hybrid system due to the temperature increase is less than ammonia desorbed from a system having only the second catalyst composition.

4. The catalyst system of claim 1 , wherein the metal comprises Cu.

5. The catalyst system of claim 1 , wherein the first SCR catalyst composition promotes higher N 2 formation and lower N 2 O formation than the second SCR catalyst composition, and the second SCR catalyst composition promotes lower N 2 formation and higher N 2 O formation for a temperature range of 200° C. to 600° C.

Assignees

• Basf Corp

Inventors

• Vaarkamp Marius
• Huennekes Edgar V
• Kuhlmann Arne
• Kah Stefan

Classifications

• B01D53/9404

  Removing only nitrogen compounds · CPC title

• B01D2255/20707

  Titanium · CPC title

• B01D2255/40

  Mixed oxides · CPC title

• B01D53/9477

  with catalysts positioned on separate bricks, e.g. exhaust systems · CPC title

• B01D2255/2092

  Aluminium · CPC title