Herbicidal mixtures comprising l-glufosinate and their use in corn cultures
US-2024407367-A1 · Dec 12, 2024 · US
US9468213B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9468213-B2 |
| Application number | US-201414243474-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 2, 2014 |
| Priority date | Feb 20, 2008 |
| Publication date | Oct 18, 2016 |
| Grant date | Oct 18, 2016 |
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The present invention relates, inter alia, to a novel herbicide formulation comprising:— (a) an aqueous phase; (b) an HPPD inhibitor in suspension in the aqueous phase; (c) an encapsulated chloroacetamide or an isoxazoline herbicide in suspension in the aqueous phase; (d) glyphosate and/or glufosinate or an agrochemically acceptable salt thereof, in solution in the aqueous phase. The invention further relates to a process for the preparation of an herbicide formulation of the invention and to a process for the control of unwanted vegetation.
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The invention claimed is: 1. An herbicide formulation comprising: (a) an aqueous phase; (b) an 4-hydroxyphenylpyruvate dioxygenase (HPPD) inhibitor in suspension in the aqueous phase, wherein the 4-hydroxyphenylpyruvate dioxygenase (HPPD) inhibitor is a triketone; (c) an encapsulated chloroacetamide and/or an isoxazoline herbicide in suspension in the aqueous phase; (d) glyphosate and/or glufosinate, or an agrochemically acceptable salt thereof, in solution in the aqueous phase; and (e) toluene sulfonic acid. 2. An herbicide formulation according to claim 1 , which is a pre-mix concentrate comprising: (a) an aqueous phase; (b) 10-600 g/l HPPD inhibitor in suspension in the aqueous phase; (c) 10-6000 g/l chloroacetamide and/or an isoxazoline herbicide which is encapsulated and in suspension in the aqueous phase; (d) 10-3000 g/l glyphosate and/or glufosinate, or an agrochemically acceptable salt thereof, in solution in the aqueous phase; and (e) a structuring agent; and (f) toluene sulfonic acid. 3. An herbicide formulation according to claim 1 , wherein the triketone is mesotrione or tembotrione. 4. An herbicide formulation according to claim 1 , wherein the chloroacetamide is present and is selected from the group consisting of alachlor, acetochlor, dimethenamid, metolachlor and S-metolachlor. 5. An herbicide formulation according to claim 4 , wherein the chloroacetamide is S-metolachlor. 6. An herbicide formulation according to claim 1 , wherein component (d) is potassium glyphosate. 7. A process for the preparation of an herbicide formulation according to claim 2 , said process comprising the steps of: (a) separately preparing (i) an HPPD inhibitor mill base, (ii) a chloroacetamide or an isoxazoline herbicide capsule suspension and (iii) a glyphosate and/or glufosinate soluble concentrate; (b) combining components (i), (ii) and (iii) above whilst mixing; (c) adding a structuring agent whilst still mixing; and (d) optionally adjusting the pH to from about 3 to 7. 8. A process for the control of unwanted vegetation, said process comprising the application of a herbicidally effective amount of a herbicide formulation according to claim 1 to a locus of the unwanted vegetation. 9. An herbicide formulation according to claim 1 , wherein the triketone is mesotrione. 10. An herbicide formulation according to claim 9 , wherein the chloroacetamide is present and is selected from the group consisting of alachlor, acetochlor, dimethenamid, metolachlor and S-metolachlor. 11. An herbicide formulation according to claim 10 , wherein component (d) is potassium glyphosate. 12. An herbicide formulation comprising: (a) an aqueous phase; (b) mesotrione; (c) an encapsulated chloroacetamide in suspension in the aqueous phase, wherein the chloroacetamide is metolachlor, S-metolachlor, or acetochlor; (d) glyphosate or an agrochemically acceptable salt thereof, in solution in the aqueous phase; and (e) toluene sulfonic acid in an appropriate amount to provide a pH of from about 3 to about 7. 13. An herbicide formulation according to claim 12 , wherein the chloroacetamide is S-metolachlor. 14. An herbicide formulation according to claim 13 , wherein component (d) is potassium glyphosate. 15. A process for the preparation of an herbicide formulation according to claim 12 , said process comprising the steps of: (a) separately preparing (i) a mesotrione mill base, (ii) an encapsulated chloroacetamide suspension and (iii) a glyphosate soluble concentrate; (b) combining components (i), (ii) and (iii) above whilst mixing; (c) adding a structuring agent whilst still mixing; and (d) adjusting the pH to from about 3 to about 7 via the toluene sulfonic acid. 16. A process for the control of unwanted vegetation, said process comprising the application of a herbicidally effective amount of a herbicide formulation according to claim 12 to a locus of the unwanted vegetation. 17. A process for the control of unwanted vegetation, said process comprising the application of a herbicidally effective amount of a herbicide formulation according to claim 13 to a locus of the unwanted vegetation. 18. A process for the control of unwanted vegetation, said process comprising the application of a herbicidally effective amount of a herbicide formulation according to claim 14 to a locus of the unwanted vegetation.
1,2-Diazoles; Hydrogenated 1,2-diazoles · CPC title
containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof · CPC title
containing acyclic or cycloaliphatic radicals · CPC title
five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2 · CPC title
with sulfur as the ring hetero atom · CPC title
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