Spark plug

Patent metadata

Field	Value
Publication number	US-9466951-B2
Application number	US-201314441315-A
Country	US
Kind code	B2
Filing date	Jun 13, 2013
Priority date	Nov 8, 2012
Publication date	Oct 11, 2016
Grant date	Oct 11, 2016

Abstract

A spark plug having an insulator formed of an alumina-based sintered material which contains an Si component and a rare earth element component that satisfy the following conditions (1) and (2): (1) an oxide-reduced amount of the Si component (mass %) is greater than or equal to 0.05 and less than or equal to 0.45; and (2) a ratio of an oxide-reduced amount of the rare earth element component to an oxide-reduced amount of the Si component is greater than or equal to 2.5 and less than or equal to 4.5, and which has alumina grains and an alumina grain boundary phase including a complex oxide crystal phase satisfying the following condition (3): (3) the complex oxide crystal phase contains at least two components selected from among an Al component, an Si component, a Group 2 element component, and a rare earth element component.

First claim

Having described the invention, the following is claimed:

1. A spark plug having an insulator formed of an alumina-based sintered material which contains an Si component and a rare earth element component in such amounts that satisfy the following conditions (1) and (2):
(1) an oxide-reduced amount of the Si component (mass %) is greater than or equal to 0.05 and less than or equal to 0.45; and
(2) a ratio of an oxide-reduced amount of the rare earth element component to the oxide-reduced amount of the Si component is greater than or equal to 2.5 and less than or equal to 4.5,

and which has alumina grains and an alumina grain boundary phase including a complex oxide crystal phase satisfying the following condition (3):
(3) the complex oxide crystal phase contains at least two components selected from among an Al component, an Si component, a Group 2 element component, the Group included in the periodic table defined by Recommendations 1990, IUPAC, (hereinafter may be referred to simply as a Group 2 component), and a rare earth element component.

2. A spark plug according to claim 1 , wherein the alumina-based sintered material contains the Al component in an oxide-reduced amount of 97 mass % or more, with respect to the total mass of the alumina-based sintered material as 100 mass %.

3. A spark plug according to claim 1 , wherein the alumina-based sintered material contains the Group 2 component in such an amount that satisfies the following condition (4):
(4) a ratio of an oxide-reduced amount of an Mg component to an oxide-reduced amount of the Group 2 component is greater than or equal to 0.05 and less than or equal to 0.35;
the alumina grains have a mean grain size of 2 to 6.5 μm; and
the complex oxide crystal phase includes crystals containing the Al component.

4. A spark plug according to claim 1 , wherein the alumina-based sintered material contains the Group 2 component and the rare earth element component in such amounts that satisfy the following condition (5):
(5) a ratio of an oxide-reduced amount of the Group 2 component to the oxide-reduced amount of the rare earth element component is greater than or equal to 0.25 and is less than or equal to 0.95.

5. A spark plug according to claim 4 , wherein, in an arbitrary cut surface of the insulator formed of the alumina-based sintered material, a total area corresponding to the alumina grains, a total area corresponding to portions of the complex oxide crystal phase, and a total area of pores satisfy the following conditions:
a ratio of a total area corresponding to the complex oxide crystal phase portions to the total area corresponding to the alumina grains is greater than or equal to 0.46; and a ratio of a total area corresponding to the pores to the total area corresponding to the alumina grains is less than or equal to 0.024.

Assignees

• Ngk Spark Plug Co

Inventors

• Takaoka Katsuya
• Uegaki Hironori
• Kurono Hirokazu
• Honda Toshitaka

Classifications

• C04B2235/3418

  Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint · CPC title

• C04B2235/96

  Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance · CPC title

• C04B2235/786

  Micrometer sized grains, i.e. from 1 to 100 micron · CPC title

• H01T13/38 Primary

  Selection of materials for insulation · CPC title

• C04B2235/3206

  Magnesium oxides or oxide-forming salts thereof · CPC title