Liquid crystal composition and liquid crystal display element using same

Patent metadata

Field	Value
Publication number	US-9464230-B2
Application number	US-201314428767-A
Country	US
Kind code	B2
Filing date	Mar 22, 2013
Priority date	Mar 22, 2013
Publication date	Oct 11, 2016
Grant date	Oct 11, 2016

Abstract

This liquid crystal composition includes at least one compound represented by general formula (i), and at least one compound represented by general formula (ii) (in the formulae: R i1 , R i2 , and R ii1 each independently represent a C1-8 alkyl group; one or at least two non-adjacent-CH 2 — groups in these alkyl groups may each independently be substituted with —CH═CH—, —C≡C—, —O—, —CO—, —COO—, or —OCO—; the hydrogen in these alkyl groups may be substituted with fluorine or chlorine; X i1 , X i2 , X i3 , X i4 , X i11 , and X ii2 each independently represent hydrogen or fluorine; and A ii1 , A ii2 , and A ii3 each independently represent a trans-1,4-cyclohexylene group, or a 1,4-phenylene group which may have the hydrogen therein substituted with fluorine or chlorine).

First claim

The invention claimed is:

1. A liquid crystal composition, comprising:
one or more compounds represented by general formula (i) below;
one or more compounds selected from compounds represented by general formulae (ii-1) to (ii-4) below;
compounds represented by general formula (XI-1), formula (2.2), and formula (1.3) below; and
at least one compound selected from compounds represented by formula (10.1), formula (11.1), and formula (15.1) below,
wherein a total content of the compounds represented by any of general formula (i) and said one or more compounds selected from compounds represented by general formulae (ii-1) to (ii-4) relative to a total amount of the composition is 13% by mass or more and 28% by mass or less:

wherein in the formulae, R i1 , R i2 , and R ii1 each independently represent an alkyl group having 1 to 8 carbon atoms where one —CH 2 — or two or more nonadjacent —CH 2 — in the alkyl group represented by R ii1 may each be independently substituted with —CH═CH—, —C≡C—, —O—, —CO—, —COO—, or —OCO— and a hydrogen atom in the alkyl group represented by R ii1 may be substituted with fluorine atom or a chlorine atom; X i1 , X i2 , X i3 , X i4 , X ii1 , and X ii2 each independently represent a hydrogen atom or a fluorine atom; A ii1 , A ii2 , and A ii3 each independently represent a trans-1,4-cyclohexylene group or a 1,4-phenylene group which may have a hydrogen atom substituted with a fluorine atom or a chlorine atom;
in formula (ii-1), R 10 represents an alkyl group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, or an alkoxy group having 1 to 4 carbon atoms;
in formula (ii-2), R 10 represents an alkyl group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, or an alkoxy group having 1 to 4 carbon atoms;
in formula (ii-3), R 10 represents an alkyl group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, or an alkoxy group having 1 to 4 carbon atoms; and
in formula (ii-4), R 10 represents an alkyl group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, or an alkoxy group having 1 to 4 carbon atoms;

wherein the formula, R 11 represents an alkyl group having 1 to 5 carbon atoms, an alkenyl group having 2 to 5 carbon atoms, or an alkoxy group having 1 to 4 carbon atoms;

2. The liquid crystal composition according to claim 1 , wherein X i2 in general formula (i) represents a fluorine atom.

3. The liquid crystal composition according to claim 1 , further comprising a compound represented by general formula (L) below:

wherein the formula, R L1 and R L2 each independently represent an alkyl group having 1 to 8 carbon atoms where one —CH 2 — or two or more nonadjacent —CH 2 — in the alkyl group may each be independently substituted with —CH═CH—, —C≡C—, —O—, —CO—, —COO—, or —OCO—,
OL represents 0, 1, 2, or 3,
B L1 , B L2 , and B L3 each independently represent a group selected from the group consisting of

(a) a 1,4-cyclohexylene group (where one —CH 2 — or two or more nonadjacent —CH 2 — present in this group may be substituted with —O—) and
(b) a 1,4-phenylene group (where one —CH═ or two or more nonadjacent —CH═ present in this group may be substituted with —N═),
wherein one or more hydrogen atoms in the group (a) or (b) described above may each independently be substituted with a cyano group, a fluorine atom, or a chlorine atom,
L L1 and L L2 each independently represent a single bond, —CH 2 CH 2 —, —(CH 2 ) 4 —, —OCH 2 —, —CH 2 O—, —COO—, —OCO—, —OCF 2 —, —CF 2 O—, —CH═N—N═CH—, —CH═CH—, —CF═CF—, or —C≡C—, and
when OL represents 2 or 3 and two or more L L2 are present, they may be the same or different and when OL represents 2 or 3 and two or more B L3 are present, they may be the same or different wherein compounds represented by general formula (i), (1.3), (2.2), (10.1), (11.1), and (15.1) are excluded from the general formula (L).

4. The liquid crystal composition according to claim 1 , further comprising a compound represented by general formula (M) below:

wherein the formula, R M1 represents an alkyl group having 1 to 8 carbon atoms where one —CH 2 — or two or more nonadjacent —CH 2 — in the alkyl group may each be independently substituted with —CH═CH—, —C≡C—, —O—, —CO—, —COO—, or —OCO—, PM represents 0, 1, 2, 3, or 4,
C M1 and C M2 each independently represent a group selected from the group consisting of

(d) a 1,4-cyclohexylene group (where one —CH 2 — or two or more nonadjacent —CH 2 — present in this group may be substituted with —O— or —S—) and
(e) a 1,4-phenylene group (where one —CH═ or two or more nonadjacent —CH═ present in this group may be substituted with —N═),
wherein one or more hydrogen atoms in the group (d) or (e) described above may each independently be substituted with a cyano group, a fluorine atom, or a chlorine atom,
K M1 and K M2 each independently represent a single bond, —CH 2 CH 2 —, —(CH 2 ) 4 —, —OCH 2 —, —CH 2 O—, —OCF 2 —, —CF 2 O—, —COO—, —OCO—, or —C≡C—,
when PM represents 2, 3, or 4 and two or more K M1 are present, they may be the same or different and when PM represents 2, 3, or 4 and two or more C M2 are present, they may be the same or different,
X M1 and X M3 each independently represent a hydrogen atom, a chlorine atom, or a fluorine atom, and
X M2 represents a hydrogen atom, a fluorine atom, a chlorine atom, a cyano group, a trifluoromethyl group, a fluoromethoxy group, a difluoromethoxy group, a trifluoromethoxy group, or a 2,2,2-trifluoroethyl group wherein a compound represented by general formula (ii) and general formula (XI-1) are excluded from the general formula (M).

5. A liquid crystal display element comprising the liquid crystal composition according to claim 1 .

6. A liquid crystal display element of an IPS mode, OCB mode, ECB mode, VA mode, VA-IPS mode, or a FFS mode, comprising the liquid crystal composition according to claim 1 .

7. A liquid crystal display comprising the liquid crystal display element according to claim 5 .

Assignees

• Dainippon Ink & Chemicals

Inventors

• Kawamura Joji
• Niwa Masahiro
• Negishi Makoto
• Iwashita Yoshinori

Classifications

• C09K2019/3077

  Cy-Cy-COO-Ph · CPC title

• C09K19/0216

  Super Birefringence Effect (S.B.E.); Electrically Controlled Birefringence (E.C.B.) · CPC title

• C09K2019/124

  Ph-Ph-Ph-Ph · CPC title

• C09K2019/123

  Ph-Ph-Ph · CPC title

• C09K2019/3071

  Cy-Cy-COO-Cy · CPC title