Zwitterionic copolymer coatings and related methods
US-2024279504-A1 · Aug 22, 2024 · US
US9464149B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9464149-B2 |
| Application number | US-201514927572-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 30, 2015 |
| Priority date | Feb 1, 2015 |
| Publication date | Oct 11, 2016 |
| Grant date | Oct 11, 2016 |
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The present disclosure relates to a heat-shrinkable tube having tearability, which is made of a fluororesin, and particularly, to a heat-shrinkable tube having excellent tear straightness. Further, the present disclosure relates to a tube having high heat-shrinkage rate at low temperature. A tube including at least a fluororesin as a base resin, in which the thickness of the entanglement unit of a polymer observed on a cross-section in a longitudinal direction of the tube after being shrunk at 200° C. by 35% or more is 1 μm to 9 μm, has excellent tear straightness.
Opening claim text (preview).
The invention claimed is: 1. A heat-shrinkable tube having tearability, comprising at least a fluororesin as a base resin, wherein the tube has a shrinkage rate of 35% or more when heated at 200° C., and a thickness of an entanglement unit of a polymer observed on a cross-section in a longitudinal direction of the tube after being shrunk at 200° C. by 35% or more is 1 μm to 9 μm. 2. The tube of claim 1 , wherein the tube has an outer diameter of 1.39 mm. 3. The tube of claim 1 , wherein the tube has a shrinkage rate of 40% or more when heated at 200° C., and a thickness of an entanglement unit of a polymer observed on a cross-section in a longitudinal direction of the tube after being shrunk at 200° C. by 40% or more is 1 μm to 9 μm. 4. The tube of claim 3 , wherein the fluororesin is a copolymer comprising tetrafluoroethylene and hexafluoropropylene as constituent monomers. 5. The tube of claim 3 , wherein a ratio exhibiting tear straightness is in a range between 50% to 50% and 48% to 52%. 6. The tube of claim 3 , wherein the tube has an outer diameter of 1.39 mm. 7. The tube of claim 1 , wherein the fluororesin is a copolymer comprising tetrafluoroethylene and hexafluoropropylene as constituent monomers. 8. The tube of claim 7 , wherein a ratio exhibiting tear straightness is in a range between 50% to 50% and 48% to 52%. 9. The tube of claim 7 , wherein the tube has an outer diameter of 1.39 mm. 10. The tube of claim 1 , wherein a ratio exhibiting tear straightness is in a range between 50% to 50% and 48% to 52%. 11. The tube of claim 10 , wherein the tube has an outer diameter of 1.39 mm. 12. A heat-shrinkable tube having tearability, comprising at least a fluororesin as a base resin, wherein the tube has a shrinkage rate of 44% or more when heated at 200° C., and a thickness of an entanglement unit of a polymer observed on a cross-section in a longitudinal direction of the tube after being shrunk at 200° C. by 44% or more is 1 μm to 9 μm. 13. The tube of claim 12 , wherein the fluororesin is a copolymer comprising tetrafluoroethylene and hexafluoropropylene as constituent monomers. 14. The tube of claim 12 , wherein a ratio exhibiting tear straightness is in a range between 50% to 50% and 48% to 52%. 15. The tube of claim 12 , wherein the tube has an outer diameter of 1.39 mm.
made of rubber or flexible plastics · CPC title
Heat shrinkable · CPC title
Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels · CPC title
using tubular layers or sheathings · CPC title
by stretching tubes {(in general B29C55/22, B29C55/28)} · CPC title
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