Xylene separation process and apparatus

Patent metadata

Field	Value
Publication number	US-9464012-B2
Application number	US-201514885319-A
Country	US
Kind code	B2
Filing date	Oct 16, 2015
Priority date	Nov 20, 2014
Publication date	Oct 11, 2016
Grant date	Oct 11, 2016

Abstract

A simulated moving bed process using dual, parallel rotary valves configured or plumbed to be operated independently in which the step times of the rotary valves are staggered. In embodiments, the second rotary valve is programmed to step about halfway through the step time of the first rotary valve. Staggering the step time of the parallel rotary valves, rather than utilizing simultaneous stepping, results in increased net composite paraxylene concentration of the extract stream, allowing for increased capacity of the simulated moving bed process and/or reduced energy consumption.

First claim

What is claimed is:

1. A simulated moving bed process for separating para-xylene using at least a first rotary valve and a second rotary valve fluidly connected to each other and to plural adsorptive separation chambers, wherein each of said rotary valves direct the input of at least one multicomponent feed, at least one flushing medium, and at least one desorbent into, and the output of at least one raffinate and at least one extract from the adsorptive separation chambers, the improvement comprising staggering the step times of the first rotary valve and a second rotary valve based on a predetermined time differential between the steps.

2. The process of claim 1 , wherein the time differential between the first rotary valve step and the second rotary valve step equals the time differential between the second rotary valve step and the first rotary valve step.

3. The process of claim 1 , wherein the time differential between the first rotary valve step and the second rotary valve step is different than the time differential between the second rotary valve step and the first rotary valve step.

4. The process of claim 1 , wherein the second rotary valve steps within about 10 seconds of the midpoint of the step time of the first rotary valve.

5. The process of claim 1 , wherein the predetermined time differential varies between the plural adsorptive chambers.

6. The process of claim 1 , wherein the first rotary valve is operated at a different flow rate than the second rotary valve.

7. The process of claim 1 , wherein the at least one multicomponent feed is selected from an equilibrium mixture of xylenes, an enhanced para-xylene stream from a toluene disproportionation unit, an enhanced para-xylene stream from a toluene methylation unit, and filtrate from a crystallizer which is low in para-xylene.

8. A process for separating para-xylene in a simulated moving bed system comprising the steps of:
(a) introducing at least one multicomponent feed comprising at least one desired product through at least one conduit into a simulated moving bed adsorption apparatus comprising a first rotary valve and a second rotary valve in fluid communication with the at least one conduit and plural adsorptive separation chambers;
(b) after a predetermined step time, advancing the first rotary valve and a second rotary valve and flushing the at least one conduit in step (a) with at least one initial flushing medium to flush residue of said first multicomponent feed from the at least one conduit in step (a) into the apparatus;
(c) after a predetermined step time, advancing the first rotary valve and a second rotary valve and flushing the at least one conduit with a second flushing medium to flush residue of the initial flushing medium from the at least one conduit in step (a) into the apparatus;
(d) after a predetermined step time, advancing the first rotary valve and a second rotary valve and withdrawing an extract stream through the at least one conduit from the apparatus through the at least one conduit; and
(e) after a predetermined step time, advancing the first rotary valve and a second rotary valve and passing a desorbent through the at least one conduit into the apparatus;
wherein the predetermined step times for the first rotary valve and a second rotary valve are staggered.

9. The process of claim 8 , wherein the predetermined step time of the second rotary valve is about halfway through the predetermined step time of the first rotary valve.

10. The process of claim 8 , wherein the predetermined step time of the second rotary valve is less than the predetermined step time of the first rotary valve.

11. The process of claim 8 , wherein the second rotary valve steps within about 10 seconds of the midpoint of the step time of the first rotary valve.

12. The process of claim 8 , wherein the predetermined step time varies between the plural adsorptive separation chambers.

13. The process of claim 8 , wherein the first rotary valve is operated at a different flow rate than the second rotary valve.

14. The process of claim 8 , wherein the at least one multicomponent feed is selected from an equilibrium mixture of xylenes, an enhanced para-xylene stream from a toluene disproportionation unit, an enhanced para-xylene stream from a toluene methylation unit, and filtrate from a crystallizer which is low in para-xylene.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Porter John R
• Bender Timothy P
• Pilliod Dana L

Classifications

• B01D15/1828

  characterised by process features · CPC title

• C07C7/12 Primary

  by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers · CPC title

• B01D15/1835

  Flushing · CPC title

• B01D15/1807

  using counter-currents, e.g. fluidised beds · CPC title

• B01D15/1842

  characterised by apparatus features · CPC title