Process for producing carbon substrates loaded with metal oxides and carbon substrates produced in this way

Patent metadata

Field	Value
Publication number	US-9463435-B2
Application number	US-201414500175-A
Country	US
Kind code	B2
Filing date	Sep 29, 2014
Priority date	Jul 17, 2008
Publication date	Oct 11, 2016
Grant date	Oct 11, 2016

Abstract

The present invention relates to a process for producing a carbon substrate loaded with metal oxides, in particular a carbon material which contains metal oxide nanoparticles and is preferably suitable for use in a catalyst and/or as a catalyst, wherein, in a first process step, nanoparticles of metal oxides are introduced into a matrix based on at least one organic polymer, in particular are dispersed therein, and, in a second process step, the polymer matrix containing the nanoparticles is subsequently carbonised to carbon, optionally followed by a third process step of activation.

First claim

The invention claimed is:

1. A carbon substrate loaded with metal oxides on the basis of a carbon material comprising metal oxide nanoparticles,
wherein the carbon substrate contains immobilized nanoparticles of metal oxides incorporated in a porous carbon matrix and wherein the carbon substrate is obtained by a process, wherein the process comprises the following process steps:
(i) in a first process step, nanoparticles of metal oxides are introduced or dispersed into a matrix based on at least one organic polymer,
(ii) then, in a second process step, the polymer matrix containing the nanoparticles is subsequently carbonized to carbon,
(iii) optionally followed by a third process step of activation,

wherein the first process step involves providing a dispersion of surface-modified or surface functionalized metal oxide nanoparticles in respective organic monomers or solutions or dispersions thereof, and polymerizing the resulting dispersion containing surface-modified or surface functionalized metal oxide nanoparticles and the organic monomers.

2. The carbon substrate according to claim 1 ,
wherein the carbon substrate has a porosity, determined as the total pore volume in accordance with Gurvich, in the range from 0.01 to 4 cm 3 /g.

3. The carbon substrate according to claim 1 ,
wherein 10 to 80 percent by volume of the total volume of the carbon substrate is formed by pores.

4. The carbon substrate according to claim 1 ,
wherein the carbon substrate has a BET surface area in the range from 100 to 2,000 m 2 /g and a volume-based content of metal oxide(s).

5. The carbon substrate according to claim 1 ,
wherein the carbon substrate has a volume-based content of metal oxide(s) and/or metal oxide nanoparticles in the carbon substrate in the range from 0.01 to 20 percent by volume based on the carbon substrate and
wherein the carbon substrate has a mass-based content of metal oxide(s) and/or metal oxide nanoparticles in the carbon substrate in the range from 0.1 to 25 percent by weight based on the carbon substrate.

6. The carbon substrate according to claim 1 ,
wherein the metal oxide nanoparticles have a mean particle size in the range from 0.1 to 1,000 nm.

7. The carbon substrate according to claim 1 ,
wherein the metal oxide nanoparticles are crystalline having a crystallinity of at least 70% and wherein the metal oxide nanoparticles have a BET surface area in the range from 1 to 2,000 m 2 /g.

8. The carbon substrate according to claim 1 ,
wherein the metal oxide nanoparticles are selected from nanoparticles of catalytically active metal oxides comprising metal oxides from the group consisting of titanium dioxide, silicon dioxide, aluminum oxide, tungsten oxide, vanadium oxide and iron oxides as well as mixture and alloys thereof.

9. The carbon substrate according to claim 1 , wherein the carbon substrate exhibits catalytic activity.

10. The carbon substrate according to claim 1 , configured in the form of a bipolar plate.

11. A carbon substrate loaded with metal oxides on the basis of a carbon material comprising metal oxide nanoparticles,
wherein the carbon substrate contains immobilized nanoparticles of metal oxides incorporated in a porous carbon matrix and
wherein the carbon substrate is obtained by a process, wherein the process comprises the following process steps:
(i) in a first process step, nanoparticles of metal oxides are introduced or dispersed into a matrix based on at least one organic polymer, wherein the metal oxide nanoparticles are crystalline having a crystallinity of at least 70% and wherein the metal oxide nanoparticles have a BET surface area in the range from 1 to 2,000 m 2 /g,
(ii) then, in a second process step, the polymer matrix containing the nanoparticles is subsequently carbonized to carbon,
(iii) optionally followed by a third process step of activation,

wherein the first process step involves providing a dispersion of previously surface-modified or surface functionalized metal oxide nanoparticles in respective organic monomers or solutions or dispersions thereof, and polymerizing the resulting dispersion containing surface-modified or surface functionalized metal oxide nanoparticles and the organic monomers.

Assignees

• Bluecher Gmbh

Inventors

• Schulz Christof
• Wiggers Hartmut

Classifications

• B01J2235/15

  X-ray diffraction · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/45

  Nanoparticles · CPC title

• B01J23/72

  Copper · CPC title

• B01J21/18 Primary

  Carbon · CPC title