System and method for obtaining nuclear magnetic resonance measurements on reservoir fluids for prediction of fluid properties

Patent metadata

Field	Value
Publication number	US-9459330-B2
Application number	US-201313827549-A
Country	US
Kind code	B2
Filing date	Mar 14, 2013
Priority date	Mar 5, 2013
Publication date	Oct 4, 2016
Grant date	Oct 4, 2016

Abstract

A nuclear magnetic resonance (NMR) measurement system for high pressure and temperature measurements on fluids is disclosed. The system has a sensor assembly that includes a sample holder having a body formed from a non-magnetic metal and defining an interior cavity for receiving a fluid sample, a frame member disposed in the interior cavity of the sample holder, an antenna coil disposed in the interior cavity about the frame member, an inlet that allows the fluid sample to enter the interior cavity, an outlet that allows for the fluid sample to be flushed from the interior cavity, and a magnet assembly having a central bore in which the sample holder is disposed. Adjacent to the sample holder are pulsed field gradient coils for performing diffusion measurements. The system further includes pulse sequencer circuitry that supplies signals to the antenna coil. When the interior cavity of the sample holder is filled with the fluid sample, the antenna coil and the frame member are at least partially submerged in the fluid sample, and the antenna coil obtains NMR measurements of the fluid sample in response to the signals. Related methods and apparatuses are also disclosed herein.

First claim

What is claimed is:

1. A nuclear magnetic resonance (NMR) measurement system comprising:
a sensor assembly comprising a sample holder having a body defining an interior cavity for receiving a fluid sample, a frame member disposed in the interior cavity of the sample holder, an antenna coil disposed in the interior cavity about the frame member, an inlet that allows the fluid sample to enter the interior cavity, an outlet that allows for the fluid sample to be flushed from the interior cavity, and a magnet assembly having a central bore in which the sample holder is disposed; and
pulse sequencer circuitry that supplies signals to the antenna coil;
wherein, when the interior cavity of the sample holder is filled with the fluid sample, the antenna coil and the frame member are at least partially submerged in the fluid sample, and the antenna coil is configured to obtain NMR measurements of the fluid sample in response to the signals wherein the NMR measurements comprise at least one of a longitudinal relaxation time distribution (T 1 ), a transverse relaxation time distribution (T 2 ), a diffusion distribution (D), or a hydrogen index (HI) a computing system having non-transitory memory that stores a database comprising laboratory measurements for a plurality of reservoir fluid samples, wherein the computing system is configured to receive the obtained NMR measurements, provide the obtained NMR measurements as inputs to a model-independent mapping function based on radial basis functions, predicting a fluid property based on an output of the model-independent mapping function;
wherein the model-independent mapping function is determined using a database comprising NMR and fluid property measurements obtained on a plurality of reservoir fluids at a plurality of temperatures and pressures.

2. A method for predicting a fluid property of a reservoir fluid comprising:
placing a nuclear magnetic resonance system into a downhole environment;
obtaining a sample of the reservoir fluid and transferring the sample into a sample holder of a sensor assembly of the nuclear magnetic resonance (NMR) measurement system, such that the sample fills the sample holder, the sample holder having a radio frequency antenna disposed therein that is submerged in the sample when filled, and wherein the sample holder is disposed within a magnet assembly and adjacent to a pair of pulse field gradient coils;
obtaining NMR measurements on the sample at a given temperature and pressure;
using the NMR measurements, temperature, and pressure as inputs to a model-independent mapping function based on radial basis functions; and
predicting the fluid property based on an output of the model-independent mapping function;
wherein the model-independent mapping function is determined using a database comprising NMR and fluid property measurements obtained on a plurality of reservoir fluids at a plurality of temperatures and pressures.

3. The method of claim 2 , wherein the fluid property comprises at least one of viscosity, density, molecular composition, SARA fractions, formation volume factor, gas-oil ratio, or compressibility.

4. The method of claim 2 , wherein the radial basis functions are Gaussian functions.

5. The method of claim 2 , wherein obtaining the NMR measurements includes supplying a bipolar pulse field gradient sequence to the pair of pulse field gradient coils.

6. The method of claim 2 , wherein obtaining the NMR measurements at the given temperature and pressure comprises obtaining at least one of a longitudinal relaxation time distribution (T 1 ), a transverse relaxation time distribution (T 2 ), a diffusion distribution (D), or hydrogen index (HI).

7. The method of claim 2 , wherein the model-independent mapping function is expressed using the following equation:

F
→

⁡

(

x
→

)

=

∑

i
=
1

N

⁢

⁢

c
→

i

⁢

exp
(

-



x
→

-

x
→

i



2

2
⁢

s
i
2

)

∑

i
=
1

N

⁢

⁢

exp
(

-



x
→

-

x
→

i



2

2
⁢

s
i
2

)

wherein {right arrow over (F)}({right arrow over (x)}) represents the fluid property, N represents the number of measurements in the database, {right arrow over (x)} i represents a vector containing database inputs for

Assignees

• Schlumberger Technology Corp

Inventors

• Freedman Robert
• Anand Vivek
• Tabrizi Payam
• Torres Ricardo Y
• Grant Douglas W
• Catina Daniel
• Ganesan Krishnamurthy

Classifications

• G01V3/32

  operating with electron or nuclear magnetic resonance · CPC title

• G01N24/081 Primary

  Making measurements of geologic samples, e.g. measurements of moisture, pH, porosity, permeability, tortuosity or viscosity · CPC title

• G01R33/305

  specially adapted for high-pressure applications · CPC title

• G01R33/30 Primary

  Sample handling arrangements, e.g. sample cells, spinning mechanisms · CPC title