Catalyst for epoxide polymerisation and for the copolymerisation of epoxide with carbon dioxide

Patent metadata

Field	Value
Publication number	US-9458286-B2
Application number	US-201314041075-A
Country	US
Kind code	B2
Filing date	Sep 30, 2013
Priority date	Apr 4, 2011
Publication date	Oct 4, 2016
Grant date	Oct 4, 2016

Abstract

The invention relates to a catalyst for catalysing the polymerisation of epoxides, and which is to be improved such that it allows a more efficient reaction to be carried out. This is achieved by providing a catalyst obtainable by mixing a) at least one double metal cyanide compound, b) at least one organic complexing agent, and c) at least one primary alcohol with 6 to 24 C atoms. In addition, the invention relates to a method for the polymerisation of epoxides, and to the use of the claimed catalyst for the polymerisation of epoxides and the copolymerisation of epoxides with carbon dioxide.

First claim

The invention claimed is:

1. A catalyst for catalyzing the polymerization of epoxides comprising a reaction product of or a complex compound of:
a) a double metal cyanide compound;
b) an organic complexing agent selected from the group consisting of ethanol, i-propyl alcohol, n-butyl alcohol, i-butyl alcohol, sec-butyl alcohol, tert-butyl alcohol, monoglyme, diglyme, 1,4-dioxane, furan and mixtures thereof; and
c) a primary alcohol with 20 to 24 C atoms.

2. The catalyst according to claim 1 , wherein the double metal cyanide compound is a chemical reaction product of a salt having the formula (1a)
M 1 d′ X g′   (1a),

where M 1 is a Zn, Fe, Co, Mn, Cu, Sn, Pb or Ni ion, X is an anion and d′ and g′ are integers >0 and assume values such that the salt M 1 d′ X g′ is electroneutral, with at least one complex of the formula (1b)
M 4 h′ [M 2 (CN) e′ ] f′   (1b),

where M 4 is an alkali metal ion, M 2 is a Co, Cr, Mn, Ir, Rh, Ru, V or Fe ion and h′, e′ and f′ are integers >0 and assume values such that the complex M 4 h′ [M 2 (CN) e′ ] f′ is electroneutral.

3. The catalyst according to claim 1 , wherein the catalyst has a structure of formula (2)
M 1 d [M 2 (CN) e ] f *x M 3 (X) g *y H 2 O* z L*a A  (2),

where M 1 is a Zn, Fe, Co, Ni, Mn, Cu, Sn or Pb ion,
M 2 is a Co, Fe, Cr, Mn, Ir, Rh, Ru or V ion,
M 3 is a Zn, Fe, Co, Ni, Mn, Cu, Sn, Pb, Cr, Ir, Rh, Ru or V ion,
X is an anion, L is the organic complexing agent and A is the primary alcohol with 20 to 24 C atoms,
d, e, f and g are integers >0 and assume values such that the complex M 1 d [M 2 (CN) e ] f *x M 3 (X) g is electroneutral, and
0.1≦x≦5; 0.1≦y≦1; 0.1≦z≦1 and 0.01≦a≦5.

4. The catalyst according to claim 1 , wherein the total proportion by weight of organic complexing agent and primary alcohol is 15 to 50 wt %, based on the total weight of the catalyst.

5. A method for polymerizing epoxides, which comprises bringing together at least one epoxide and the catalyst according to claim 1 .

6. The method according to claim 5 , wherein the method is carried out in the presence of at least one solvent.

7. The method according to claim 5 , wherein the method is carried out as a method for the copolymerization of at least one epoxide and carbon dioxide.

Assignees

• Henkel Ag & Co Kgaa

Inventors

• Zander Lars
• Kunze Christiane
• Klein Johann
• Paetzold Eckhard
• Marquardt Marion
• Kragl Udo

Classifications

• B01J2231/14

  Other (co) polymerisation, e.g. of lactides or epoxides · CPC title

• C08G59/686 Primary

  containing nitrogen · CPC title

• B01J31/0202 Primary

  Alcohols or phenols · CPC title

• C08G64/34

  and cyclic ethers · CPC title