Thermoplastic and water-dispersible injection moldable materials and articles

Patent metadata

Field	Value
Publication number	US-9456931-B2
Application number	US-201314092087-A
Country	US
Kind code	B2
Filing date	Nov 27, 2013
Priority date	Nov 27, 2013
Publication date	Oct 4, 2016
Grant date	Oct 4, 2016

Abstract

A tampon applicator that is water-sensitive (e.g., water-soluble, water-dispersible, etc.) in that it loses its integrity over time in the presence of water is provided. The tampon applicator can be discreetly disposed of in a toilet without the risk of clogging sewer pipes. The tampon applicator includes a molded thermoplastic composition containing at least one partially hydrolyzed polyvinyl alcohol a plasticizer. The desired water-sensitive characteristics of the tampon applicator may be achieved in the present invention by selectively controlling a variety of aspects of the thermoplastic composition from which the applicator is formed, such as the nature of the components employed, the relative amount of each component, the manner in which the composition is formed, and so forth.

First claim

What is claimed is:

1. A flushable tampon applicator, the tampon applicator comprising an outer tube for housing a tampon and comprising an inner tube, at least a portion of which extends into the outer tube, wherein the outer tube includes an outer, body-contacting surface, wherein the inner tube is moveable relative to the outer tube and configured to expel a tampon from the outer tube, further wherein at least one of the outer tube and the inner tube comprises a thermoplastic composition, the thermoplastic composition comprising:
from about 50 wt. % to about 98 wt. % of partially hydrolyzed polyvinyl alcohols, the partially hydrolyzed polyvinyl alcohols comprising a first polyvinyl alcohol, a second polyvinyl alcohol, and a third polyvinyl alcohol, wherein the viscosity of the first polyvinyl alcohol is less than the viscosity of the second polyvinyl alcohol, wherein the weight percentage ratio of the first polyvinyl alcohol to the second polyvinyl alcohol ranges from about 1 to about 20, wherein the first polyvinyl alcohol and the second polyvinyl alcohol each have a degree of hydrolysis ranging from about 80 mole % to about 90 mole %, and wherein the third polyvinyl alcohol has a viscosity that is greater than the viscosity of the first polyvinyl alcohol and the second polyviny alcohol; and
from about 2 wt. % to about 50 wt. % of a plasticizer; wherein at least one of the outer tube and the inner tube is a molded part.

2. The tampon applicator of claim 1 , wherein the first polyvinyl alcohol has a viscosity ranging from about 1 centipoise to about 3.5 centipoise and the second polyvinyl alcohol has a viscosity ranging from about 3.5 centipoise to about 15 centipoise.

3. The tampon applicator of claim 1 , wherein the weight percentage ratio of the second polyvinyl alcohol to the third polyvinyl alcohol ranges from about 1 to about 10.

4. The tampon applicator of claim 1 , wherein the tampon applicator has a peak elongation of from about 40% to about 200%.

5. The tampon applicator of claim 1 , wherein the tampon applicator has a modulus of from about 100 MPa to about 2000 MPa.

6. The tampon applicator of claim 1 , wherein the plasticizer is a polyhydric alcohol.

7. The tampon applicator of claim 6 , wherein the plasticizer is a polyol.

8. The tampon applicator of claim 6 , wherein the plasticizer is glycerol.

9. The tampon applicator of claim 1 , wherein the body-contacting surface of the outer tube includes a water-insoluble material.

10. The tampon applicator of claim 9 , wherein the ratio of the weight percentage of the water-insoluble material to the thermoplastic composition ranges from about 0.005 to about 1.

11. The tampon applicator of claim 9 , wherein the water-insoluble material comprises a wax, silicon, polytetrafluoroethylene, polyethylene, a polyester, polyamide, a thermoplastic elastomer, or a combination thereof.

12. The tampon applicator of claim 1 , wherein the thermoplastic composition has a melt flow rate of from about 40 grams per 10 minutes to about 160 grams per 10 minutes when subjected to a load of 2160 grams at a temperature of 190° C. according to ASTM Test Method D1238-E.

13. The tampon applicator of claim 1 , wherein the tampon applicator is injection molded.

14. The tampon applicator of claim 1 , wherein the tampon applicator disintegrates in tap water in less than about 18 hours, wherein the tap water has a temperature of less than about 25° C.

15. A method for forming an injection molded part, the method comprising:
injection molding a pelletized, water-dispersible, thermoplastic composition into a mold cavity, wherein the thermoplastic composition comprises from about 50 wt. % to about 98 wt. % of partially hydrolyzed polyvinyl alcohols, the partially hydrolyzed polyvinyl alcohols comprising a first polyvinyl alcohol, a second polyvinyl alcohol, and a third polyvinyl alcohol, wherein the viscosity of the first polyvinyl alcohol is less than the viscosity of the second polyvinyl alcohol, wherein the weight percentage ratio of the first polyvinyl alcohol to the second polyvinyl alcohol ranges from about 1 to about 20, wherein the first polyvinyl alcohol and the second polyvinyl alcohol each have a degree of hydrolysis ranging from about 80 mole % to about 90 mole %, and wherein the third polyvinyl alcohol has a viscosity that is greater than the viscosity of the first polyvinyl alcohol and the second polyvinyl alcohol; and from about 2 wt. % to about 50 wt. % of a plasticizer, wherein the composition has a melt flow rate of from about 40 grams per 10 minutes to about 160 grams per 10 minutes when subjected to a load of 2160 grams at a temperature of 190° C. according to ASTM Test Method D1238-E; and
shaping the thermoplastic composition into a molded part within the mold cavity.

16. The method of claim 15 , wherein the first polyvinyl alcohol has a viscosity ranging from about 1 centipoise to about 3.5 centipoise and the second polyvinyl alcohol has a viscosity ranging from about 3.5 centipoise to about 15 centipoise.

17. The method of claim 15 , wherein the weight percentage ratio of the second polyvinyl alcohol to the third polyvinyl alcohol ranges from about 1 to about 10.

18. The method of claim 15 , further comprising a co-injection molding process, wherein the injection molded part is a two layered molded part having an inner layer and an outer layer, wherein the inner layer comprises the injection-molded, thermoplastic composition and the outer layer is water-insoluble.

19. The method of claim 18 , wherein the outer layer comprises from about 1 wt. % to about 50 wt. % of the injection molded part and the inner layer comprises from about 50 wt. % to about 99 wt. % of the injection molded part.

20. The method of claim 18 , wherein the outer layer comprises a wax, silicon, polytetrafluoroethylene, polyethylene, a polyester, polyamide, a thermoplastic elastomer, or a combination thereof.

21. The method of claim 15 , wherein the molded part is a tampon applicator.

Assignees

• Kimberly Clark Co

Inventors

• Wang James H
• Wideman Gregory J
• Demarco Alphonse Carl
• Pickett Austin
• Mleziva Mark M

Classifications

• A61F13/2097

  method of manufacturing tampon applicators · CPC title

• A61F13/266 Primary

  Insertion devices, e.g. rods or plungers, separate from the tampon · CPC title

• B29K2105/251

  Particles, powder or granules (expandable particles B29K2105/046) · CPC title

• B29K2995/0062

  water-soluble · CPC title

• B29L2023/00

  Tubular articles (B29L2024/00 takes precedence {; catheters B29L2031/7542}) · CPC title