Solid-state batteries utilizing template layers for electrode formation and methods for forming the same

Patent metadata

Field	Value
Publication number	US-9455437-B2
Application number	US-201414509776-A
Country	US
Kind code	B2
Filing date	Oct 8, 2014
Priority date	Oct 8, 2014
Publication date	Sep 27, 2016
Grant date	Sep 27, 2016

Abstract

Embodiments provided herein describe solid-state lithium batteries and methods for forming such batteries. A first current collector is provided. A first layer is formed above the first current collector. The first layer includes lithium and cobalt. The first layer is annealed. A second layer is formed above the annealed first layer. The second layer includes lithium and cobalt, and the annealed first layer and the second layer jointly form a first electrode. An electrolyte is formed above the first electrode. A second electrode is formed above the electrolyte. A second current collector is formed above the second electrode.

First claim

What is claimed:

1. A method for forming a solid-state battery, the method comprising:
providing a first current collector;
forming a first layer above the first current collector, wherein the first layer consists of lithium-cobalt oxide;
annealing the first layer;
forming a second layer above the annealed first layer, wherein the second layer comprises lithium, cobalt, and at least one of aluminum, manganese, vanadium, titanium, nickel, or a combination thereof, and the annealed first layer and the second layer jointly form a first electrode;
forming an electrolyte above the first electrode;
forming a second electrode above the electrolyte; and
forming a second current collector above the second electrode.

2. The method of claim 1 , wherein the annealing the first layer comprises heating the first layer at a temperature of between 600° C. and 800° C.

3. The method of claim 2 , wherein a thickness of the first layer is between 1 micrometer (μm) and 5 μm.

4. The method of claim 3 , wherein the thickness of the thickness of the first layer is between 1 μm and 3 μm.

5. The method of claim 4 , wherein the second layer comprises lithium-cobalt oxide doped with at least one of aluminum, manganese, vanadium, titanium, nickel, or a combination thereof.

6. The method of claim 5 , wherein a thickness of the first electrode is between 10 μm and 20 μm.

7. The method of claim 1 , wherein the electrolyte comprises lithium-phosphorous oxynitride, and the second electrode comprises lithium.

8. The method of claim 5 , wherein the second layer consists of lithium-cobalt oxide doped with at least one of aluminum, manganese, vanadium, titanium, nickel, or a combination thereof.

9. The method of claim 8 , wherein the first current collector comprises gold, platinum, or a combination thereof, and wherein the second current collector comprises at least one of scandium, titanium, vanadium, chromium, manganese, iron, cobalt, nickel, copper, yttrium, zirconium, lanthanum, hafnium, molybdenum, tantalum, tungsten, titanium nitride, or a combination thereof.

10. The method of claim 1 , wherein the forming of the first layer, the forming of the second layer, the forming of the electrolyte, and the forming of the second electrode are performed using physical vapor deposition (PVD).

11. A method for forming a solid-state lithium battery, the method comprising:
providing a first current collector, wherein the first current collector is formed above a substrate;
forming a first layer above the first current collector, wherein the first layer consists of lithium-cobalt oxide and has a thickness of between 1 micrometer (μm) and 5 μm;
annealing the first layer;
forming a second layer directly on the annealed first layer, wherein the second layer comprises lithium-cobalt oxide doped with at least one of aluminum, manganese, vanadium, titanium, nickel, or a combination thereof, and the annealed first layer and the second layer jointly form a first electrode, the first electrode having a thickness of between 10 μm and 20 μm;
forming an electrolyte above the first electrode;
forming a second electrode about the electrolyte; and
forming a second current collector above the second electrode.

12. The method of claim 11 , wherein the second layer consists of lithium-cobalt oxide doped with at least one of aluminum, manganese, vanadium, titanium, nickel, or a combination thereof.

13. The method of claim 12 , wherein the electrolyte comprises lithium-phosphorous oxynitride, and the second electrode comprises lithium.

14. The method of claim 13 , wherein the annealing the first layer comprises heating the first layer at a temperature of between 600° C. and 800° C.

15. The method of claim 14 , wherein the forming of the first layer, forming of the second layer, the forming of the electrolyte, and the forming of the second electrode are performed using physical vapor deposition (PVD).

16. A method for forming a solid-state lithium battery, the method comprising:
providing a substrate;
forming a first current collector above the substrate;
forming a first layer above the first current collector, wherein the first layer consists of lithium-cobalt oxide and has a thickness of between 1 micrometer (μm) and 5 μm;
heating the first layer at a temperature of between 600° C. and 800° C.;
forming a second layer about the first layer, wherein the second layer comprises lithium-cobalt oxide doped with at least one of aluminum, manganese, vanadium, titanium, nickel, or a combination thereof, and the first layer and the second layer jointly form a first electrode, the first electrode having a thickness of between 10 μm and 20 μm;
forming a solid electrolyte about the first electrode;
forming a second electrode above the solid electrolyte, wherein the second electrode comprises lithium; and
forming a second current collector above the second electrode.

17. The method of claim 16 , wherein the forming of the first layer, the forming of the second layer, the forming of the solid electrolyte, and the forming of the second electrode are performed using physical vapor deposition (PVD).

18. The method of claim 17 , wherein the solid electrolyte comprises lithium-phosphorous oxynitride.

19. The method of claim 18 , wherein the substrate has a plurality of site-isolated regions defined thereon, and the forming of the first current collector, the forming of the first layer, the forming of the second layer, the forming of the solid electrolyte, the forming of the second electrode, and the forming of the second current collector cause a first solid-state lithium battery to be formed above a first of the plurality of site-isolated regions using a first set of processing conditions, and further comprising:
forming a second solid-state lithium battery above a second of the plurality of site-isolated regions using a second set of processing conditions, the second set of processing conditions being different than the first set of processing conditions;
evaluating the first solid-state lithium battery and the second solid-state lithium battery; and
based on the evaluating, selecting one of the first set of processing conditions and the second set of processing conditions.

20. The method of claim 19 , wherein each of the first set of processing conditions and the second set of processing conditions comprises processing temperatures, component thicknesses, component chemical compositions, processing gas compositions, sputter deposition conditions, or a combination thereof, and wherein the evaluating the first solid-state lithium battery and the second solid-state lithium battery comprises testing for at least one of volumetric energy density, average voltage during discharge, utilization at various discharge rates, cycle life, and number of charge and discharge cycles until a selected amount of initial capacity is retained.

Assignees

• Intermolecular Inc

Inventors

• Anapolsky Abraham
• Le Minh Huu
• Van Duren Jeroen

Classifications

• H01M4/0421

  involving vapour deposition · CPC title

• C23C14/568

  Transferring the substrates through a series of coating stations (C23C14/562 takes precedence) · CPC title

• H01M10/0525

  Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

• C23C14/3414

  Metallurgical or chemical aspects of target preparation, e.g. casting, powder metallurgy · CPC title

• H01M10/052

  Li-accumulators · CPC title