Apparatuses and methods for removing impurities from a hydrocarbon stream

Patent metadata

Field	Value
Publication number	US-9453174-B2
Application number	US-201414315926-A
Country	US
Kind code	B2
Filing date	Jun 26, 2014
Priority date	Jun 26, 2014
Publication date	Sep 27, 2016
Grant date	Sep 27, 2016

Abstract

Methods and apparatuses for removing impurities from a hydrocarbon stream are provided herein. In an embodiment, a method for removing impurities from a hydrocarbon stream includes providing the hydrocarbon stream that includes carbon dioxide in an amount of greater than about 50 ppm by mole. Carbon dioxide is selectively adsorbed from the hydrocarbon stream to produce a treated hydrocarbon stream that has less than or equal to 50 ppm by mole of carbon dioxide. The adsorbed carbon dioxide is desorbed to produce a raffinate stream that includes the carbon dioxide. The carbon dioxide is separated from the raffinate stream using a solvent separation technique to produce a treated raffinate stream.

First claim

What is claimed is:

1. A method for removing impurities including water, sulfur-containing species, and carbon dioxide from a hydrocarbon stream containing methane, wherein the method comprises the steps of:
providing the hydrocarbon stream comprising methane, water, sulfur-containing species, and carbon dioxide in an amount of greater than 50 ppm by mole;
selectively adsorbing carbon dioxide, water, and sulfur from the hydrocarbon stream in an adsorption unit including a bed of silica gel adsorbent, followed by a bed of 5 A molecular sieve adsorbent, and followed by a bed of 13× molecular sieve adsorbent to produce a treated hydrocarbon stream having less than 50 ppm by mole of carbon dioxide and reduced amounts of water and sulfur compounds;
splitting the treated hydrocarbon stream into a slip stream and a product stream;
desorbing the adsorbed carbon dioxide to produce a raffinate stream comprising the carbon dioxide by using the slip stream as a desorbent stream;
separating carbon dioxide from the raffinate stream using a chemical or physical solvent separation technique to produce a treated raffinate stream having a higher carbon dioxide content than the treated hydrocarbon stream;
splitting the treated raffinate stream into a first portion and a second portion;
combining a first portion of the treated raffinate stream with the product stream for liquefaction; and
recycling a second portion of the treated raffinate stream to the adsorption step.

2. The method of claim 1 , wherein providing the hydrocarbon stream comprises providing the hydrocarbon stream comprising carbon dioxide in an amount of from greater than about 50 ppm to 3 mole % based on the total content of the hydrocarbon stream.

3. The method of claim 1 , wherein desorbing the adsorbed carbon dioxide comprises desorbing the adsorbed carbon dioxide using a portion of the treated raffinate stream.

4. The method of claim 1 , wherein separating the carbon dioxide from the raffinate stream further comprises separating the sulfur-containing species from the raffinate stream.

5. The method of claim 4 , wherein separating the carbon dioxide and the sulfur-containing species from the raffinate stream comprises separating the carbon dioxide and the sulfur-containing species from the raffinate stream using a physical solvent separation technique.

6. The method of claim 1 , wherein separating the carbon dioxide from the raffinate stream comprises separating the carbon dioxide from the raffinate stream using a chemical solvent separation technique.

7. The method of claim 6 , wherein separating the carbon dioxide from the raffinate stream comprises separating the carbon dioxide from the raffinate stream by contacting an aqueous amine solvent with the raffinate stream.

8. The method of claim 1 , further comprising providing an initial feed stream having a higher carbon dioxide content than the hydrocarbon stream.

9. The method of claim 8 , further comprising removing carbon dioxide from the initial feed stream using a membrane separation technique to produce the hydrocarbon stream.

Assignees

• Uop Llc

Inventors

• Acikgoz Saadet Ulas
• Doong Shain
• Zhou Lubo
• Sharma Bhargav

Classifications

• C10L2290/548

  Membrane- or permeation-treatment for separating fractions, components or impurities during preparation or upgrading of a fuel · CPC title

• C10L3/103

  Sulfur containing contaminants · CPC title

• C10L2290/12

  Regeneration of a solvent, catalyst, adsorbent or any other component used to treat or prepare a fuel · CPC title

• C10L3/104 Primary

  Carbon dioxide · CPC title

• C10L2290/542

  Adsorption of impurities during preparation or upgrading of a fuel · CPC title