Rubber composition, preparation method and vulcanized rubber thereof

Patent metadata

Field	Value
Publication number	US-9453122-B2
Application number	US-201214354222-A
Country	US
Kind code	B2
Filing date	Oct 26, 2012
Priority date	Oct 26, 2011
Publication date	Sep 27, 2016
Grant date	Sep 27, 2016

Abstract

A rubber composition, preparation method and vulcanized rubber thereof are provided. The rubber composition comprises uncrosslinked rubber and rubber particles having crosslinked structure dispersed therein, wherein the rubber particles having crosslinked structure are synthetic rubber particles and/or natural rubber particles with an average particle size of 20 to 500 nm and a gel content of 60% by weight or higher, and the uncrosslinked rubber is styrene-butadiene rubber, and wherein the weight ratio of the rubber particles having crosslinked structure to the uncrosslinked rubber is 1:99-20:80.

First claim

The invention claimed is:

1. A rubber composition, consisting of uncrosslinked rubber and rubber particles having radiation crosslinked structures, wherein the rubber particles having radiation crosslinked structures comprise synthetic and/or natural rubber particles with a gel content of at least 60 wt %, and wherein the uncrosslinked rubber comprises styrene-butadiene rubber, and further wherein the weight ratio of the rubber particles having radiation crosslinked structures to the uncrosslinked rubber ranges from 1:99 to 20:80, and
wherein the rubber composition comprises a continuous phase comprising the uncrosslinked styrene-butadiene rubber, and a dispersed phase comprising the rubber particles having radiation crosslinked structures, which are dispersed in the continuous phase with fine particle sizes ranging from 20 nm to 500 nm.

2. The rubber composition according to claim 1 , wherein the rubber particles having radiation crosslinked structures comprise one or more selected from natural rubber particles, styrene-butadiene rubber particles, carboxylated styrene-butadiene rubber particles, nitrile butadiene rubber particles, carboxylated nitrile butadiene rubber particles, chloroprene rubber particles, polybutadiene rubber particles, silicone rubber particles, acrylic rubber particles, and styrene-butadiene-vinylpyridine rubber particles.

3. The rubber composition according to claim 2 , wherein the rubber particles having radiation crosslinked structures comprise one or more selected from nitrile butadiene rubber particles, styrene-butadiene-vinylpyridine rubber particles, styrene-butadiene rubber particles, and carboxylated styrene-butadiene rubber particles.

4. The rubber composition according to claim 3 , wherein the rubber particles having radiation crosslinked structures comprise one or more selected from styrene-butadiene rubber particles, carboxylated styrene-butadiene rubber particles, and nitrile butadiene rubber particles.

5. The rubber composition according to claim 4 , wherein the rubber particles having radiation crosslinked structures comprise nitrile butadiene rubber particles.

6. The rubber composition according to claim 1 , wherein the rubber particles having radiation crosslinked structures are of homogeneous structures.

7. The rubber composition according to claim 1 , wherein the gel content of the rubber particles having radiation crosslinked structures is at least 75 wt %.

8. The rubber composition according to claim 7 , wherein the gel content of the rubber particles having radiation crosslinked structures is at least 80 wt %.

9. The rubber composition according to claim 1 , wherein the average particle size of the rubber particles having radiation crosslinked structures anges from 50 nm to 300 nm.

10. The rubber composition according to claim 9 , wherein the average particle size of the rubber particles having radiation crosslinked structures ranges from 50 nm to 200 nm.

11. The rubber composition according to claim 1 , wherein the weight ratio of the rubber particles having radiation crosslinked structures to the uncrosslinked rubber ranges from 1:99 to 10:90.

12. The rubber composition according to claim 11 , wherein the weight ratio of the rubber particles having radiation crosslinked structures to the uncrosslinked rubber ranges from 2:98 to 8:92.

13. The rubber composition according to claim 1 , wherein the composition is obtained by mixing and coagulating uncrosslinked rubber latex and latex of rubber particles having radiation crosslinked structures.

14. A preparation method for the rubber composition according to claim 1 , comprising:
(1) subjecting synthetic and/or natural rubber latex to radiation crosslinking, thereby providing radiation crosslinked structures onto the synthetic and/or natural rubber particles in the latex, wherein the synthetic and/or natural rubber particles have said gel content and said average particle size;
(2) mixing until homogeneous the above radiation crosslinked synthetic and/or natural rubber latex with latex of uncrosslinked styrene-butadiene rubber according to said weight ratio of the rubber particles having radiation crosslinked structures to the uncrosslinked rubber; and
(3) coagulating the above mixed latexes to obtain said rubber composition.

15. The preparation method according to claim 14 , wherein the synthetic and/or natural rubber latex comprises one or more selected from natural rubber latex, styrene-butadiene rubber latex, carboxylated styrene-butadiene rubber latex, nitrile butadiene rubber latex, carboxylated nitrile butadiene rubber latex, chloroprene rubber latex, polybutadiene rubber latex, silicone rubber latex or acrylic rubber latex, and styrene-butadiene-vinylpyridine rubber latex.

16. The preparation method according to claim 15 , wherein the synthetic and/or natural rubber latex comprises one or more selected from nitrile butadiene rubber latex, styrene-butadiene-vinylpyridine rubber latex, styrene-butadiene rubber latex, and carboxylated styrene-butadiene rubber latex.

17. The preparation method according to claim 16 , wherein the synthetic and/or natural rubber latex comprises one or more selected from styrene-butadiene rubber latex, carboxylated styrene-butadiene rubber latex, and nitrile butadiene rubber latex.

18. The preparation method according to claim 17 , wherein the synthetic and/or natural rubber latex comprises nitrile butadiene rubber latex.

19. A vulcanized rubber prepared by the rubber composition according to claim 1 , comprising vulcanized styrene-butadiene rubber matrix and nitrile butadiene rubber particles having radiation crosslinked structures with said average particle size dispersed in the vulcanized styrene-butadiene rubber matrix, wherein the vulcanized styrene-butadiene rubber matrix and the nitrile butadiene rubber particles having radiation crosslinked structures have said weight ratio.

Assignees

• China Petroleum & Chem Corp
• Beijing Res Inst Chemical Ind China Petroleum & Chemical Corp

Inventors

• Qiao Jinliang
• Cong Yuexin
• Zhang Xiaohong
• Li Ying
• Gao Jianming
• Zhang Qianmin
• Song Zhihai
• Sun Yanling
• Guo Meifang
• Song Peijun
• Cai Chuanlun
• Zhao Guoxun
• Shi Hongwei
• Qi Guicun
• Lai Jinmei
• Zhang Hongbin
• Wang Ya
• Li Binghai
• Wang Xiang

Classifications

• C08J3/28 Primary

  Treatment by wave energy or particle radiation · CPC title

• C08J3/005

  Processes for mixing polymers · CPC title

• C08L9/06

  Copolymers with styrene · CPC title

• C08J2309/08

  Latex · CPC title

• C08L2312/06

  by radiation · CPC title