Integrated reactors, methods of making same, and methods of conducting simultaneous exothermic and endothermic reactions

Patent metadata

Field	Value
Publication number	US-9452402-B2
Application number	US-201314053500-A
Country	US
Kind code	B2
Filing date	Oct 14, 2013
Priority date	Aug 17, 1999
Publication date	Sep 27, 2016
Grant date	Sep 27, 2016

Abstract

Integrated Combustion Reactors (ICRs) and methods of making ICRs are described in which combustion chambers (or channels) are in direct thermal contact to reaction chambers for an endothermic reaction. Superior results were achieved for combustion chambers which contained a gap for free flow through the chamber. Particular reactor designs are also described. Processes of conducting reactions in integrated combustion reactors are described and results presented. Some of these processes are characterized by unexpected and superior results.

First claim

We claim:

1. An integrated reactor, comprising:
alternating layers of exothermic and endothermic reaction chambers, comprising at least 2 layers of endothermic reaction chambers alternating with at least one layer comprising an exothermic reaction chamber;
wherein the exothermic reaction chamber comprises an exothermic reaction catalyst;
wherein the endothermic reaction chambers comprise an endothermic reaction catalyst;
wherein the exothermic reaction chamber comprises a wall that is adjacent at least one of the endothermic reaction chambers;
wherein the endothermic reaction catalyst comprises a porous catalyst insert that can be conveniently inserted and removed from the endothermic reaction chamber;
and wherein the integrated reactor possesses a volumetric heat flux characteristic of at least 1 W/cc as measured according to the Volumetric Heat Flux Measurement Test.

2. The reactor of claim 1 wherein the porous catalyst insert fills the endothermic reaction chamber.

3. The reactor of claim 2 wherein the integrated reactor possesses a volumetric heat flux characteristic of 1 W/cc to 120 W/cc as measured according to the Volumetric Heat Flux Measurement Test.

4. The reactor of claim 2 wherein the integrated reactor possesses a volumetric heat flux characteristic of 10 W/cc to 120 W/cc as measured according to the Volumetric Heat Flux Measurement Test.

5. The reactor of claim 1 wherein the exothermic reaction chamber comprises multiple apertures along its length adapted for staged introduction of fuel or oxidant into the exothermic reaction chamber.

6. The reactor of claim 5 wherein the integrated reactor possesses a volumetric heat flux characteristic of 1 W/cc to 120 W/cc as measured according to the Volumetric Heat Flux Measurement Test.

7. The reactor of claim 5 wherein the integrated reactor possesses a volumetric heat flux characteristic of 10 W/cc to 120 W/cc as measured according to the Volumetric Heat Flux Measurement Test.

8. The reactor of claim 1 wherein the wall comprises steel, or high temperature nickel based superalloy.

9. The reactor of claim 8 wherein the integrated reactor possesses a volumetric heat flux characteristic of 10 W/cc to 120 W/cc as measured according to the Volumetric Heat Flux Measurement Test.

10. The reactor of claim 9 wherein the integrated reactor possesses a NO x output of less than 100 ppm as measured according to the standard NO x test measurement.

11. The reactor of claim 9 wherein the integrated reactor possesses a NO x output in the range of about 5 to 20 ppm as measured according to the standard NO x test measurement.

12. The reactor of claim 9 wherein the integrated reactor possesses a NO x output in the range of about 5 to 100 ppm as measured according to the standard NO x test measurement.

13. The reactor of claim 1 wherein the integrated reactor possesses a volumetric heat flux characteristic of 1 W/cc to 120 W/cc as measured according to the Volumetric Heat Flux Measurement Test.

14. The reactor of claim 13 wherein the integrated reactor possesses a NO x output of less than 100 ppm as measured according to the standard NO x test measurement.

15. The reactor of claim 13 wherein the integrated reactor possesses a NO x output in the range of about 5 to 20 ppm as measured according to the standard NO x test measurement.

16. The reactor of claim 1 wherein the integrated reactor possesses a volumetric heat flux characteristic of 10 W/cc to 120 W/cc as measured according to the Volumetric Heat Flux Measurement Test.

Assignees

• Battelle Memorial Institute

Inventors

• Tonkovich Anna Lee
• Roberts Gary
• Perry Steven T
• Fitzgerald Sean P
• Wegeng Robert S
• Wang Yong
• Vanderwiel David
• Marco Jennifer L

Classifications

• B01J8/0285 Primary

  Heating or cooling the reactor (for tubular reactors in furnaces B01J8/062) · CPC title

• C01B2203/1035

  Catalyst coated on equipment surfaces, e.g. reactor walls · CPC title

• C01B3/501

  by diffusion · CPC title

• Y10T29/49826

  Assembling or joining · CPC title

• C01B2203/1276

  Mixing of different feed components · CPC title