System for dense loading of catalyst into bayonet tubes for a steam reforming exchanger-reactor using removable deflectors

Patent metadata

Field	Value
Publication number	US-9452400-B2
Application number	US-201314436146-A
Country	US
Kind code	B2
Filing date	Sep 24, 2013
Priority date	Oct 17, 2012
Publication date	Sep 27, 2016
Grant date	Sep 27, 2016

Abstract

The present invention describes a device and a method for dense and homogeneous loading of catalyst into the annular space of bayonet tubes employed in a steam reforming reactor, said device being constituted by a series of removable deflectors.

First claim

The invention claimed is:

1. A device for densely filling catalyst specially adapted to a steam reforming exchanger-reactor consisting of a plurality of bayonet tubes enclosed in a shell, the catalyst being constituted by particles occupying at least part of the annular space ( 4 ) included between an internal tube ( 5 ) and an external tube ( 6 ), the assembly of these two tubes constituting a bayonet tube, the width of said annular space being in the range 30 mm to 80 mm, and its height being in the range 10 to 20 meters, the catalyst particles being in the form of cylinders with an approximate height of 10 mm to 20 mm and an approximate diameter of 10 mm to 20 mm, said annular space ( 4 ) being divided into two or three substantially identical horizontal sectors, each sector extending the entire length of the bayonet tube, by means of a “centralizer” system disposed at the head of the annular space, each sector being equipped with its own system of deflectors, each system of deflectors consisting of:
a series of deflectors ( 7 ) distributed in a regular vertical manner along the annular space ( 4 ) and separated by a vertical distance in the range 50 cm to 150 cm;
said deflectors ( 7 ) being connected together via a chain ( 8 ) which winds around a spooler ( 10 ) located outside the tube to be filled, and the particles of catalyst being contained in:
a central feed hopper ( 1 ) for delivering the particles onto a conveyor belt or a shaker conveyor ( 2 ) supplying the annular space ( 4 ), via:
a funnel ( 3 ) via which the particles flow into the interior of the annular space ( 4 ).

2. A device for densely filling catalyst specially adapted to a stream reforming exchanger-reactor consisting of a plurality of bayonet tubes enclosed in a shell, the catalyst being constituted by particles occupying at least part of the annular space ( 4 ) included between an internal tube ( 5 ) and an external tube ( 6 ), the assembly of these two tubes constituting a bayonet tube, the width of said annular space being in the range 30 mm to 80 mm, and its height being in the range 10 to 20 meters, the catalyst particles being in the form of cylinders with an approximate height of 10 mm to 20 mm and an approximate diameter of 10 mm to 20 mm, said annular space ( 4 ) being divided into two or three substantially identical horizontal sectors, each sector extending the entire length of the bayonet tube, in which the upper portion of the annular space ( 4 ) is traversed by the internal tube ( 5 ) which traverses the external tube ( 6 ), which results in the use of two identical systems of deflectors ( 7 ) operating in parallel, in a manner equivalent to the case of an annular space divided into two sectors
said deflectors ( 7 ) being connected together via a chain ( 8 ) which winds around a spooler ( 10 ) located outside the tube to be filled, and the particles of catalyst being contained in:
a central feed hopper ( 1 ) for delivering the particles onto a conveyor belt or a shaker conveyor ( 2 ) supplying the annular space ( 4 ), via:

a funnel ( 3 ) via which the particles flow into the interior of the annular space ( 4 ).

3. The filling device according to claim 1 , in which each deflector ( 7 ) is in the form of a vane which is downwardly inclined at an angle alpha with respect to the vertical in the range 30° to 50°, each deflector occupying a portion of the horizontal surface area of the sector in the range 50% to 90% of said surface area of the sector.

4. The filling device according to claim 3 in which, when the diameter of the wall of the annular space ( 4 ) varies because portions of the external tube ( 6 ) have diameters which decrease from top to bottom, the system of deflectors ( 7 ) adapts itself to this variation in section, always satisfying the condition of occupation of said horizontal section in the range of 50% to 90% by adjusting the angle alpha, the smallest value being adapted to the portion with the smallest diameter and the largest value to the portion with the largest diameter, the articulation of the blade of the defector about its axis being free, and a second set of chains ( 8 ′) allowing the end of the blade of the deflector to be lifted to a greater or lesser extent order to vary the angle alpha.

5. The filling device according to claim 1 in which, when the diameter of the wall of the annular space ( 4 ) varies because portions of the external tube ( 6 ) have diameters which decrease from top to bottom, the system of deflectors ( 7 ) is provided, at its ends closest to the wall of the annular space ( 4 ), with lips ( 11 ) formed from rubber which can be used to adjust the length of the blades in order to conserve the coefficient of occupation of the section of the annular space in the case in which the internal diameter of the external tube of the bayonet is varied.

6. A method for loading catalyst using the device according to claim 1 , characterized by the following series of steps:
initially winding the loading system into the external spooler ( 10 ), the feed hopper ( 1 ) being filled with solid;
the loading system is then gradually introduced into the annular zone ( 4 ) via its upper portion until the first deflector ( 7 ) reaches a distance with respect to the bottom of the tube in the range 50 cm to 100 cm;
the conveyor belt ( 2 ) is started up so as to provide a flow rate of solid in the range 250 to 500 kg/h, which solid is introduced into the annular zone ( 4 ) or a sector of said annular zone ( 4 ) via the funnel ( 3 );
as and when the tube is filled, the loading system is raised from the annular zone ( 4 ) with the aid of the external spooler ( 10 ) in a manner such as to keep a constant distance between the first deflector ( 7 ) and the surface of the bed which is gradually being constituted, said distance being in the range 50 cm to 100 cm;
the system is wound up at a speed equivalent to the speed of loading of the tube, in the range 0.2 meter/min to 0.4 meter/min;
once the tube has been loaded and the loading system wound up, the system is displaced in order to load the next tube.

Assignees

• Ifp Energies Now

Inventors

• Sanz Elena
• Beaumont Robert
• Boyer Christophe

Classifications

• B01J2208/00778

  Kinetic energy reducing devices in the flow channel · CPC title

• B01J8/002

  with a moving instrument · CPC title

• B01J8/003 Primary

  in a downward flow · CPC title

• B01J8/06

  in tube reactors; the solid particles being arranged in tubes · CPC title

• B01J2208/00752

  Feeding · CPC title