Coating composition for prevention of substrate oxidation

Patent metadata

Field	Value
Publication number	US-9449730-B2
Application number	US-201314374355-A
Country	US
Kind code	B2
Filing date	Jan 24, 2013
Priority date	Jan 25, 2012
Publication date	Sep 20, 2016
Grant date	Sep 20, 2016

Abstract

Disclosed herein is a coating composition for prevention of substrate oxidation/corrosion comprising energy level modulated conjugated polymer in combination with hydrophobic, spherical molecule in a suitable ratio. Particularly the invention relates to coating composition for protecting metal and alloy comprising the derivatives of polythiophene and polyphenylene vinylene with lower energy level, wherein the pores on the polymeric film are filled/blocked with hydrophobic, spherical molecule to enhance the efficiency of polymer against the corrosion.

First claim

The invention claimed is:

1. An article comprising a substrate and a coating on the substrate to provide the substrate with protection against oxidation and/or corrosion, wherein the coating is disposed with respect to the substrate such that a bottom surface of the coating is in direct contact with a top surface of the substrate over an entirety of the top surface of the substrate and, with the article in an oxidizing environment, a top surface of the coating is exposed to the oxidizing environment over an entirety of the top surface of the coating, the coating comprising band edge modulated conjugated polymers selected from the group consisting of derivatives of poly phenylene vinylene or polythiophene and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) in a specific ratio of 1:2 (% wt), wherein the derivatives of polythiophene and derivatives of poly phenylene vinylene are

wherein n is an integer greater than 1,

wherein n is an integer greater than 1, m is an integer greater than 1; and
wherein the substrate comprises a metal or a metal alloy.

2. The article according to claim 1 , wherein PCBM having van der Waals diameter in the range of 1.0 to 1.5 nm.

3. The composition according to claim 1 , wherein the substrate is a metal alloy selected from the group consisting of iron alloy, aluminum alloy, copper alloy, cobalt alloy, nickel alloy; wherein the iron alloy is steel.

4. The article according to claim 1 , wherein the band gaps of lower energy absorption onset of conjugated polymer of formula P1, P2, and P4 are 2.4, 2.7 and 2.0 eV respectively.

5. The article according to claim 1 , wherein the highest occupied molecular orbital energy level of conjugated polymers of formula P1, P2, and P4 are −6.0, −5.8, and −4.4 respectively.

6. The article according to claim 1 , wherein the charge carrier mobility of conjugated polymers of formula P1, and P2 are 1.7×10 −9 ; and 8.0×10 −10 cm 2 V −1 s −1 respectively.

7. The article according to claim 1 , wherein the conjugated polymer-PCBM blend has a water contact angle in the range of 90° to 110°.

8. A method for protecting an oxidizable or corrodible substrate against corrosion or oxidation which comprises applying thereto a coating composition to produce the article as claimed in claim 1 .

9. An article comprising a substrate and a coating on the substrate to provide the substrate with protection against oxidation and/or corrosion in an oxidizing environment, wherein the coating is disposed with respect to the substrate such that a bottom surface of the coating is in direct contact with a top surface of the substrate over an entirety of the top surface of the substrate and, with the article in the oxidizing environment, a top surface of the coating is exposed to the oxidizing environment over an entirety of the top surface of the coating, the coating comprising band edge modulated conjugated polymer and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) wherein the band edge modulated conjugated polymer is an alkyl derivative of polythiophene that is poly (3-hexylthiophene) having Formula P3

wherein n is an integer greater than 1; and
wherein the substrate comprises a metal or a metal alloy.

10. The article according to claim 9 , wherein PCBM having van der Waals diameter in the range of 1.0 to 1.5 nm.

11. The article according to claim 9 , wherein the substrate is a metal alloy selected from the group consisting of iron alloy, aluminum alloy, copper alloy, cobalt alloy, nickel alloy; wherein the iron alloy is steel.

12. The article according to claim 9 , wherein the band gaps of lower energy absorption onset of conjugated polymer of formula P3 is 2.3 eV.

13. The article according to claim 9 , wherein the highest occupied molecular orbital energy level of conjugated polymers of formula P3 is −5.1 eV.

14. The article according to claim 9 , wherein the charge carrier mobility of conjugated polymers of formula P3 is 6.1×10 −5 cm 2 V −1 s −1 .

15. The article according to claim 9 , wherein the conjugated polymer-PCBM blend has a water contact angle in the range of 90° to 110°.

16. A method for protecting an oxidizable or corrodible substrate against corrosion or oxidation which comprises applying thereto a coating composition to produce the article as claimed in claim 9 .

Assignees

• Council Scient Ind Res

Inventors

• Kothandam Krishnamoorthy

Classifications

• C08G2261/3223

  containing one or more sulfur atoms as the only heteroatom, e.g. thiophene · CPC title

• C09D165/02

  Polyphenylenes · CPC title

• C08G2261/3422

  conjugated, e.g. PPV-type · CPC title

• C08G2261/58

  corrosion-inhibiting · CPC title

• C08K3/04

  Carbon · CPC title