Method of ore processing

Patent metadata

Field	Value
Publication number	US-9447480-B2
Application number	US-201213981823-A
Country	US
Kind code	B2
Filing date	Jan 25, 2012
Priority date	Jan 25, 2011
Publication date	Sep 20, 2016
Grant date	Sep 20, 2016

Abstract

A method of selectively leaching a metal such as nickel from an ore or ore processing intermediate comprising the metal and cobalt. The ore or ore processing intermediate is contacted with an acidic leach solution comprising an amount of an oxidising agent sufficient to oxidise a major portion of the cobalt to thereby cause it to be stabilised in the solid phase while a major portion of the metal is dissolved for subsequent recovery.

First claim

The invention claimed is:

1. A method of selectively leaching a metal selected from the group consisting of nickel, copper and zinc from a solid ore or solid ore processing intermediate comprising the metal and cobalt, the method including:
providing a mixture comprising an acidic leach solution and an oxidizing agent; and
mixing the mixture with the solid ore or solid ore intermediate,
wherein there is sufficient oxidizing agent to stabilize a substantial portion of the cobalt to cause it to be stabilized in a solid phase while greater than 95% by mass of the metal is selectively dissolved.

2. The method of claim 1 wherein the metal is nickel.

3. The method of claim 1 wherein the solid ore or solid ore processing intermediate is a mixed nickel-cobalt hydroxide precipitate.

4. The method of claim 1 wherein the oxidizing agent has sufficient oxidizing potential to oxidize cobalt(II) to cobalt(III).

5. The method of claim 4 wherein the oxidizing agent has an oxidative potential of greater than about 0.5 V (SHE).

6. The method of claim 4 wherein the oxidizing agent has an oxidative potential of greater than 0.5 V to 3.0 V (SHE).

7. The method of claim 1 wherein the acidic leach solution has a pH from about 1 to about 6.

8. The method of claim 7 wherein the acidic leach solution has a pH from about 2 to about 5.

9. The method of claim 6 wherein the oxidizing agent has an oxidative potential of about 0.5 V to about 3.0 V (SHE) at a pH from 0 to 6.

10. The method of claim 9 wherein the oxidizing agent has an oxidative potential of about 0.5 V to about 1.0 V (SHE) at a pH from 4 to 6.

11. The method of claim 9 wherein the oxidizing agent has an oxidative potential of about 1.0 V to about 2.0 V (SHE) at a pH from 1 to 4.

12. The method of claim 1 wherein the oxidizing agent is selected from the group consisting of persulphates, peroxides, permanganates, perchlorates, ozone, oxides and chlorine.

13. The method of claim 1 further including controlling a rate of addition of the oxidizing agent.

14. The method of claim 1 further including heating the acidic leach solution to greater than 50° C.

15. The method of claim 1 wherein the oxidizing agent is present in the acidic leach solution in 80% to 200% stoichiometric equivalents to combined cobalt and manganese in the solid ore or solid ore processing intermediate.

16. The method of claim 1 wherein the solid ore or solid ore processing intermediate further comprises manganese and treatment with the amount of oxidizing agent causes a substantial portion of the manganese to be stabilized in a solid phase while a substantial portion of the metal is dissolved.

17. The method of claim 1 wherein, after a leaching process is complete, extracted metal can be recovered directly from the acidic leach solution by electrowinning or hydrogen reduction.

18. A method of recovering nickel and cobalt from a mixed nickel-cobalt hydroxide precipitate including:
(a) providing a mixture comprising an acidic leach solution and an oxidizing agent, wherein there is sufficient oxidizing agent to stabilize a substantial portion of the cobalt to cause it to be stabilized in a solid phase while greater than 95% by mass of the nickel is selectively dissolved;
(b) mixing the mixture with the mixed nickel-cobalt hydroxide precipitate;
(c) separating the cobalt in the solid phase from the acidic leach solution containing dissolved nickel to recover the cobalt in the solid phase; and
(d) recovering the nickel from the acidic leach solution.

19. The method of claim 18 wherein the mixed nickel-cobalt hydroxide precipitate further comprises manganese and addition of an amount of oxidizing agent also causes a substantial portion of the manganese to be stabilized in a solid phase.

20. A method of selectively leaching a metal selected from the group consisting of nickel, copper and zinc from a solid ore or solid ore processing intermediate comprising the metal and cobalt, the method including:
a) providing a mixture comprising an acidic leach solution and an oxidizing agent; and
b) mixing the mixture with the solid ore or solid ore processing intermediate,
wherein there is sufficient oxidizing agent to stabilize a substantial portion of the cobalt to cause it to be stabilized in a solid phase while greater than 95% by mass of the metal is selectively dissolved within 5 hours.

Assignees

• Vaughan James
• Hawker William
• Univ Queensland

Inventors

• Vaughan James
• Hawker William

Classifications

• C22B15/0071 Primary

  containing sulfur · CPC title

• C22B19/02

  Preliminary treatment of ores; Preliminary refining of zinc oxide · CPC title

• C22B23/0484

  in acidic type solutions · CPC title

• C22B23/0415

  with acids or salt solutions except ammonium salts solutions · CPC title

• C22B3/06 Primary

  in inorganic acid solutions {, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions} · CPC title