Asphalt oxidation process using liquid jet ejection

Patent metadata

Field	Value
Publication number	US-9447327-B2
Application number	US-201414484484-A
Country	US
Kind code	B2
Filing date	Sep 12, 2014
Priority date	Nov 29, 2010
Publication date	Sep 20, 2016
Grant date	Sep 20, 2016

Abstract

Provided is a process for increasing the softening temperature of asphalts by use of liquid jet ejector with a diptube connected to the discharge connection of the liquid jet ejector for ejecting an air/asphalt mixture below a liquid level in an oxidizer vessel. The liquid jet ejector is used as both an air compressor and an air/oil mixer. The liquid jet ejector motive fluid is hot asphalt and the entrained vapor is air. The combined liquid jet ejector with a diptube process provides for an improvement in asphalt air blowing efficiency by requiring less cumulative air to produce a given asphalt softening temperature.

First claim

What is claimed is:

1. A process for increasing the softening point of asphalt comprising the following steps:
providing a liquid jet ejector comprising a motive inlet, a motive nozzle, a suction port, a main ejector body, a venturi throat and diffuser, and a discharge connection;
conducting a preheated asphalt feed including fresh asphalt and recycled oxidized asphalt, at a temperature from 125° C. to 300° C., as the motive liquid into the motive inlet of the liquid jet ejector;
drawing atmospheric air or compressed air into the suction port of the liquid jet ejector;
mixing the preheated asphalt within the main ejector body with the air from the suction port of the liquid jet ejector to form an air/asphalt mixture;
conducting the air/asphalt mixture to a heated and pressurized oxidizer vessel via a diptube connected to the discharge connection of the liquid jet ejector;
ejecting the air/asphalt mixture from an exit port of the diptube positioned below a liquid level in the oxidizer vessel;
collecting an off-gas from the overhead of the oxidizer vessel and an oxidized asphalt product stream from the bottoms of the oxidizer vessel, wherein said oxidized asphalt product stream has softening temperature greater than the preheated asphalt feed; and
recycling a portion of the oxidized asphalt product stream back to the liquid jet ejector to form the recycled oxidized asphalt.

2. The process of claim 1 wherein the oxidizer vessel is operated at a temperature from 150° C. to 300° C. with the proviso that it be at least 10° C. greater than the temperature of the preheated asphalt feed being conducted to said motive inlet of the liquid jet ejector.

3. The process of claim 2 wherein the oxidizer vessel is operated at a temperature from 200° C. to 270° C.

4. The process of claim 1 wherein the recycled oxidized asphalt feed rate is at least 5 times greater than that of the fresh asphalt feed rate.

5. The process of claim 4 wherein the recycled oxidized asphalt feed rate is at least 20 times greater than that of the fresh asphalt feed rate.

6. The process of claim 1 wherein the oxidizer vessel is operated at a pressure of from 0 to 10 barg.

7. The process of claim 6 wherein the oxidizer vessel is operated at a pressure of from 0 to 5 barg.

8. The process of claim 1 wherein the air feed rate is at least a stoichiometric amount based on the preheated asphalt feed rate.

9. The process of claim 1 further including the step of injecting steam from a steam generator to the oxidizer vessel.

10. The process of claim 9 wherein the injecting steam to the oxidizer vessel is above or below the liquid mixture in the oxidizer vessel.

11. The process of claim 1 wherein the air is compressed.

12. The process of claim 1 wherein the air is atmospheric.

13. The process of claim 1 wherein the exit port of the diptube is positioned at least 1 inch below the liquid level in the oxidizer vessel.

14. The process of claim 1 wherein the exit port of the diptube is positioned at least 5 inches below the liquid level in the oxidizer vessel.

15. The process of claim 1 wherein the exit port of the diptube is positioned from 6 to 12 inches from a bottom of the oxidizer vessel.

16. The process of claim 1 wherein the cumulative air required to produce said oxidized asphalt product stream softening temperature is at least 10% less than a process not including a diptube positioned below a liquid level in the oxidizer vessel.

17. The process of claim 1 wherein the cumulative air required to produce said oxidized asphalt product stream softening temperature is at least 50% less than a process not including a diptube positioned below a liquid level in the oxidizer vessel.

Assignees

• Aldous Keith K
• Exxonmobil Res & Eng Co

Inventors

• Aldous Keith K

Classifications

• B01F5/0413

  Operations & Transport · mapped topic

• C10C3/04 Primary

  by blowing or oxidising {, e.g. air, ozone} · CPC title

• C08L95/00

  Compositions of bituminous materials, e.g. asphalt, tar, pitch · CPC title

• B01F25/312

  with Venturi elements; Details thereof · CPC title