Compound, tautomer of compound or salt of compound or tautomer, method for producing same, coloring composition, dyeing method, and dyed article
US-12240842-B2 · Mar 4, 2025 · US
US9447282B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9447282-B2 |
| Application number | US-201414228776-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 28, 2014 |
| Priority date | Dec 21, 2012 |
| Publication date | Sep 20, 2016 |
| Grant date | Sep 20, 2016 |
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Electrowetting apparatus including a compound comprising a plurality of colorant moieties and a linker. The plurality of colorant moieties includes a first colorant moiety having a first net dipole and a second colorant moiety having a second net dipole, wherein the plurality of colorant moieties are linked by and disposed around the linker so that the first net dipole and the second net dipole at least partially cancel each other.
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What is claimed is: 1. Electrowetting apparatus comprising a compound which is a dye comprising: a plurality of colorant moieties comprising: a first colorant moiety having a first net dipole, and a second colorant moiety having a second net dipole, wherein at least one of the plurality of colorant moieties is of a dye class selected from the group consisting of: an azo dye having the general formula: a bisazo dye having the general formula: an anthraquinone dye having the general formula: a coumarine dye having the general formula: a naphthaquinone dye having the general formula: a squaraine dye having the general formula: a stilbene dye having the general formula: and an indophenol dye having the general formula: wherein each of A 1 to A 64 is independently selected from the group consisting of: a linker, hydrogen (H), an alkyl group having at least one carbon atom, an alkyl group having 1 to 32 carbon atoms, a halogen atom, an alkyl group, an alkenyl group, an oxo group, an alkoxy group, a thiol group, a hydroxyl group, a thioalkyl group, an aryl group, a heteroaryl group, an amine group, a nitro group, a cyano group, an amide group, a sulphonyl group, a carboxy group, and a trifluoromethyl group; and a linker, the plurality of colorant moieties linked by and disposed around the linker so that the first net dipole and the second net dipole at least partially cancel each other. 2. The electrowetting apparatus according to claim 1 , wherein one or more of the following applies: each of the plurality of colorant moieties comprises at least one chromophore, the plurality of colorant moieties are disposed around the linker so that a net dipole of the compound is substantially zero, or the compound reduces backflow by at least one or more of: 50%, 60%, 70%, 80%, 90%, 95%, or 98%. 3. The electrowetting apparatus according to claim 1 , wherein the first colorant moiety and the second colorant moiety are disposed around the linker so that the first net dipole and the second net dipole are at least partially opposed to each other. 4. The electrowetting apparatus according to claim 3 , wherein the plurality of colorant moieties comprises only the first colorant moiety and the second colorant moiety, wherein, with the compound having a substantially linear geometry, the first net dipole and the second net dipole are substantially coincident along a linear axis. 5. The electrowetting apparatus according to claim 3 , wherein the linker is divalent for linking the first colorant moiety and the second colorant moiety. 6. The electrowetting apparatus according to claim 5 , wherein the linker has a general formula selected from the group consisting of: wherein each n independently is one or more of 1, 2, 3, 4, 5, 6, 7 or 8; one or more of the following applies: X and Y are each independently selected from the group consisting of: hydrogen (H), a halogen atom, an alkyl group, an alkenyl group, an aryl group, an alkoxy group, and a thioalkyl group, or a pair of X and Y on the same carbon, taken together, is one or more of: an oxo group, an acetal group, or a thioacetal group; and T is one or more of: oxygen (O), or sulphur (S). 7. The electrowetting apparatus according to claim 5 , wherein the linker has a formula selected from the group consisting of: 8. The electrowetting apparatus according to claim 1 , wherein the plurality of colorant moieties comprising at least one further colorant moiety having at least one further net dipole, wherein the plurality of colorant moieties are disposed around the linker so that the first net dipole, the second net dipole and the at least one further net dipoles at least partially cancel each other. 9. The electrowetting apparatus according to claim 8 , wherein the at least one further colorant moiety comprises a third colorant moiety having a third net dipole. 10. The electrowetting apparatus according to claim 9 , wherein the linker is trivalent for linking the first colorant moiety, the second moiety, and the third colorant moiety. 11. The electrowetting apparatus according to claim 10 , wherein the linker links the first colorant moiety, the second colorant moiety and the third colorant moiety in a disposition around the linker such that the first net dipole, the second net dipole and the third net dipole at least partially cancel each other. 12. The electrowetting apparatus according to claim 11 , wherein the linker is selected from the group consisting of: wherein each n independently is one or more of: 1, 2, 3, 4, 5, 6, 7, or 8; Q is one or more of: N or P; and one or more of the following applies: each of X 1 and Y 1 is independently selected from the group consisting of: a hydrogen (H) and an alkyl group, or a pair of X 1 and Y 1 on the same carbon, taken together, is an oxo group. 13. The electrowetting apparatus according to claim 8 , wherein the at least one further colorant moiety comprises a third colorant moiety having a third net dipole and a fourth colorant moiety having a fourth net dipole. 14. The electrowetting apparatus according to claim 13 , wherein the linker is tetravalent for linking the first colorant moiety, the second colorant moiety, the third colorant moiety and the fourth colorant moiety. 15. The electrowetting apparatus according to claim 14 , wherein the linker links the first colorant moiety, the second colorant moiety, the third colorant moiety and the fourth colorant moiety in a disposition around the linker such that the first net dipole, the second net dipole, the third net dipole and the fourth net dipole at least partially cancel each other. 16. The electrowetting apparatus according to claim 15 , wherein the linker is selected from the group consisting of: wherein each n independently is one or more of: 1, 2, 3, 4, 5, 6, 7 or 8; one or more of the following applies: each of X 2 and Y 2 is independently selected from the group consisting of: hydrogen (H) and an alkyl group, or a pair of X 2 and Y 2 on the same carbon, taken together, is an oxo group; and alkyl 1 is one or more of: an alkyl group having at least one carbon atom, or an alkyl group having 1 to 32 carbon atoms.
Trisazo dyes of the type [IMAGE cpc-sch-C09B-1013.gif] · CPC title
of the naphthalene series, e.g. naphthazarin · CPC title
in which the coupling component is a heterocyclic compound · CPC title
Coumarine dyes · CPC title
Disazomethine dyes · CPC title
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