Methods for preparing nanoparticle-containing thermoplastic composite laminates

Patent metadata

Field	Value
Publication number	US-9447260-B2
Application number	US-64160309-A
Country	US
Kind code	B2
Filing date	Dec 18, 2009
Priority date	Jun 28, 2007
Publication date	Sep 20, 2016
Grant date	Sep 20, 2016

Abstract

High quality thermoplastic composites and composite laminates containing nanoparticles and/or nanofibers, and methods of producing such composites and laminates are disclosed. The composites comprise a thermoplastic polymer and a plurality of nanoparticles, and may include a fibrous structural reinforcement. The composite laminates are formed from a plurality of nanoparticle-containing composite layers and may be fused to one another via an automated process.

First claim

What is claimed as new and desired to be secured by Letters Patent of the United States is:

1. A method of producing a nanoparticle-containing composite laminate comprising:
contacting a fibrous structural reinforcement with a thermoplastic polymer matrix resin and a plurality of nanoparticles to form a plurality of nanoparticle-containing composites, wherein the nanoparticles comprise at least one of nanofibers and nanotubes;
layering the plurality of nanoparticle-containing composites; and
fusing the layers sequentially to one another via a moving heated head process to form a completed laminate in which the thermoplastic polymer matrix resin has full crystallinity.

2. The method of producing a nanoparticle-containing composite laminate according to claim 1 wherein the thermoplastic polymer matrix resin and plurality of nanoparticles are combined and the fibrous structural reinforcement is contacted with the combination of thermoplastic polymer resin and plurality of nanoparticles.

3. The method of producing a nanoparticle-containing composite laminate according to claim 1 wherein the moving heated head process comprises an automated process.

4. The method of producing a nanoparticle-containing composite laminate according to claim 3 wherein the automated process is selected from automated heated head tape placement, automated heated head tow placement, automated heated head fiber placement, and automated heated head tape laying.

5. The method of producing a nanoparticle-containing composite laminate according to claim 1 wherein said laminate includes at least one non-fibrous structural reinforced layer formed by combining a thermoplastic polymer matrix resin with a plurality of nanoparticles to form a nanoparticle-containing composite.

6. The method of producing a nanoparticle-containing composite laminate according to claim 1 , wherein the step of contacting a fibrous structural reinforcement with a thermoplastic polymer matrix resin and a plurality of nanoparticles comprises at least one of: melt coating, calendaring, dip impregnation with a resin solution or molten resin, and melt pressing the fibrous structural reinforcement in a film of the nanoparticle-containing thermoplastic polymer.

7. The method of producing a nanoparticle-containing composite laminate according to claim 1 wherein the fibrous structural reinforcements comprise at least one of: glass fibers, silicon carbide fibers, alumina, titania, boron, carbon, graphite fibers, and fibers formed from organic polymers such as aromatic polyamides, polyethylenes, polyolefins, polyarylates, and polyaryl ethers.

8. The method of producing a nanoparticle-containing composite laminate according to claim 1 , wherein the nanoparticles have a particle size greater than 500 nm to less than 999 nm.

9. The method of producing a nanoparticle-containing composite laminate according to claim 1 , wherein the nanoparticles have a particle size greater than 200 nm and less than 999 nm.

10. The method of producing a nanoparticle-containing composite laminate according to claim 1 wherein the fibrous structural reinforcements comprise from about 20 vol % to about 80 vol % of the total composite.

11. The method of producing a nanoparticle-containing composite laminate according to claim 1 wherein the moving heated head process comprises a processes in which a heated head moves laterally relative to a previously fused layer that remains stationary or the heated head and the previously fused layer move laterally relative to one another.

12. A method of producing a nanoparticle-containing composite laminate comprising:
contacting a fibrous structural reinforcement with a thermoplastic polymer matrix resin and a plurality of nanoparticles to form a plurality of nanoparticle-containing composites, wherein the nanoparticles comprise at least one of nanofibers and nanotubes;
layering the plurality of nanoparticle-containing composites with respect to each other to form adjacent layers; and
fusing the composites sequentially only at adjoining surfaces between the adjacent layers by moving a melt region of the composites without melting each layer through its respective thickness.

13. The method of producing a nanoparticle-containing composite laminate according to claim 12 wherein the melt region is moved by moving a heated head laterally relative to a previously fused layer that remains stationary, or moving both the heated head and the previously fused layer laterally relative to one another.

14. A method of producing a nanoparticle-containing composite laminate comprising:
mixing at least one of nanotubes and nariofibers with a thermoplastic polymer resin;
contacting a fibrous structural reinforcement with the thermoplastic polymer to form an elongated composite strip in which the thermoplastic polymer resin is fully amorphous or semi-crystalline;
layering the elongated composite strips; and
fusing the layers sequentially to one another via a moving heated head process to produce full crystallinity in the thermoplastic polymer of a completed laminate.

Assignees

• Gruber Mark B
• Jensen Brian J
• Cano Roberto J
• Nasa

Inventors

• Gruber Mark B
• Jensen Brian J
• Cano Roberto J

Classifications

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• C08L71/00

  Compositions of polyethers obtained by reactions forming an ether link in the main chain (of polyacetals C08L59/00; of epoxy resins C08L63/00; of polythioether-ethers C08L81/02; of polyether-sulfones C08L81/06); Compositions of derivatives of such polymers · CPC title

• B32B27/20

  using fillers, pigments, thixotroping agents · CPC title

• C08K7/06

  Elements · CPC title

• B32B2262/06

  Vegetal fibres · CPC title