Method for removing residual titanium from a polyester solution

Patent metadata

Field	Value
Publication number	US-9447250-B2
Application number	US-201214377932-A
Country	US
Kind code	B2
Filing date	Feb 13, 2012
Priority date	Feb 13, 2012
Publication date	Sep 20, 2016
Grant date	Sep 20, 2016

Abstract

The present invention provides a method for reducing level of titanium in an aqueous solution of polyester in a safe and effective way, while avoiding hydrolysis of the polyester.

First claim

What is claimed is:

1. A method for removing residual organic titanium from an aqueous solution of a polyester comprising residual organic titanium, comprising steps of:
(a) adjusting pH of the aqueous solution to a value from about 4.0 to about 5.0 by adding phosphoric acid or an acidic salt thereof;
(b) treating the aqueous solution obtained in said step (a) with an oxidant that is hydrogen peroxide or peroxyacetic acid to result in a titanium-containing solid; and
(c) removing the solid from the reaction mixture obtained in said step (b).

2. The method according to claim 1 , further comprising a step between step (b) and step (c): adjusting the pH of the reaction mixture obtained in step (b) to a value from about 6.0 to about 7.0 with an alkali, wherein said alkali used is in the form of an alkaline solution.

3. The method according to claim 2 , wherein said alkali used in the form of an alkaline solution having a pH value from about 8.0 to about 11.0.

4. The method according to claim 1 , wherein the pH of the aqueous solution is adjusted to a value of about 4.0 in said step (a).

5. The method according to claim 1 , wherein the oxidant is used in an amount of from about 0.2% to about 5.0% by weight, relative to the weight of the polyester in the aqueous solution used in said step (a).

6. The method according to claim 1 , wherein said step (b) is carried out at a temperature from room temperature to about 80° C.

7. The method according to claim 1 , wherein the treating time of said step (b) is from about 0.5 hour to about 4.0 hours.

8. The method according to claim 1 , wherein the step (c) is carried out by filtration.

9. The method according to claim 1 , wherein a filter aid is introduced into the aqueous solution in one or more steps of (a)-(c).

10. The method according to claim 9 , wherein the filter aid is selected from the group consisting of BH-20, BH-40, hyflosupercel, and a combination thereof.

11. The method according to claim 9 , wherein the filtration in step (c) is carried out at a temperature from about 40° C. to about 90° C.

12. The method according to claim 8 , wherein the filtration in step (c) is carried out under a pressure from about 1.0 atm to about 4.0 atm.

13. The method according to claim 8 , wherein the filtration time in step (c) is from about 1.0 hour to about 2.0 hours.

14. The method according to claim 1 , wherein the polyester comprising residual organic titanium is obtained from the preparation of polyester in the presence of a titanium-based catalyst.

15. The method according to claim 1 , wherein the aqueous solution used in step (a) is obtained by dissolving the polyester comprising residual organic titanium into water, and optionally filtering the solution.

16. The method according to claim 14 , wherein the titanium-based catalyst is an organic titanate.

17. The method according to claim 16 , wherein the organic titanate is tetraalkyl titanate selected from the group consisting of tetraisopropyl titanate, tetrabutyl titanate and a combination thereof.

18. The method according to claim 1 , wherein the polyester is a soil-release polyester or a polyether-polyester block copolymer.

19. The method according to claim 1 , wherein the concentration of the polyester in the aqueous solution used in said step (a) is from about 10% to about 90% by weight.

Assignees

• Neyraval Philippe
• Soto Natalie
• Lin Daobing
• Wang Mingjuan
• Rhodia Operations

Inventors

• Neyraval Philippe
• Soto Natalie
• Lin Daobing
• Wang Mingjuan

Classifications

• C08G63/90

  Purification; Drying · CPC title

• C08G63/85 Primary

  Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof {(C08G63/823 takes precedence)} · CPC title

• C08J2367/02

  Polyesters derived from dicarboxylic acids and dihydroxy compounds; (C08J2367/06 takes precedence) · CPC title

• C08J11/00 Primary

  Recovery or working-up of waste materials (recovery of plastics B29B17/00; polymerisation processes involving purification or recycling of waste polymers or their depolymerisation products C08B, C08C, C08F, C08G, C08H) · CPC title