Iron porphyrazines as efficient, catalytic and scalable method to produce chlorine dioxide
US-2019256355-A1 · Aug 22, 2019 · US
US9446952B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9446952-B2 |
| Application number | US-38889206-A |
| Country | US |
| Kind code | B2 |
| Filing date | Mar 24, 2006 |
| Priority date | Mar 24, 2005 |
| Publication date | Sep 20, 2016 |
| Grant date | Sep 20, 2016 |
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A process for generating aqueous chlorine dioxide solutions includes adding a solid phase alkali metal chlorite, a solid phase acid, and a solid phase oxidizing agent to an aqueous solution, wherein the solid phase acid ahs a pKa less than 4. Also disclosed are compositions for producing chlorine dioxide solutions.
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What is claimed is: 1. A batch process for generating an aqueous solution of chlorine dioxide, the process consisting of: adding a composition consisting of a solid phase oxidizer to an aqueous solution consisting of water and sodium chlorite; agitating the aqueous solution; and generating chlorine dioxide in the aqueous solution, wherein the solid phase oxidizer is selected from the group consisting of 1,3-dichloro-5,5-dimethylhydantoin and for twenty four hours. 2. The process of claim 1 , wherein the aqueous solution is at 16° C.
from chlorites · CPC title
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