Adiabatic regeneration of sulfur capturing adsorbents

Patent metadata

Field	Value
Publication number	US-9446384-B2
Application number	US-201113982862-A
Country	US
Kind code	B2
Filing date	Dec 14, 2011
Priority date	Feb 2, 2011
Publication date	Sep 20, 2016
Grant date	Sep 20, 2016

Abstract

The present invention provides a process for regeneration of the sulfur capturing spent adsorbents after sulfur capturing using a hydrolyzing agent under adiabatic conditions. In accordance with the process of the present invention hydrolyzing agent is introduced to the spent adsorbent in a controlled manner such that the exothermic heat generated within the adsorbent bed does not rise above the predetermined temperature limit.

First claim

The invention claimed is:

1. A process for adiabatic wet regeneration of spent adsorbent bed after sulfur capturing in the presence of a hydrolyzing agent; said process comprising the following steps:
i. a first purging step of removing trapped liquid hydrocarbons from the spent adsorbent bed after sulfur capturing by passing a vapor phase hydrocarbon stream;
ii. a second purging step of removing the vapor phase traces of trapped hydrocarbons from the spent adsorbent bed after sulfur capturing by passing a non-reactive regeneration gas stream, wherein the second purging is carried out for a period of 1 hour to 4 hours;
iii. removing sulfur impurities by introducing the hydrolyzing agent to the spent adsorbent bed through the non-reactive regeneration gas, while increasing a temperature of the spent absorbent bed within a limit ranging from 36° C. to 100° C. above an initial bed temperature,
wherein the hydrolyzing agent is having a concentration in the range of 100 ppm to 2000 ppm and is introduced for a period in the range of 0.5 hour to 2.0 hours,
wherein the temperature of the spent absorbent bed after the second purging step of the spent adsorbent bed after sulfur capturing is in the range of 100° C. to 250° C.;
iv. continuing the passage of the hydrolyzing agent with increasing concentration to the spent adsorbent bed till a point of time when the bed temperature remains constant even upon the passage of the hydrolyzing agent at its peak concentration;
v. further continuing the passage of the hydrolyzing agent at its peak concentration to the spent adsorbent bed after sulfur capturing till a point when the adsorbent bed temperature starts to decline; and
vi. discontinuing the passage of the hydrolyzing agent to the spent adsorbent bed after sulfur capturing and increasing the temperature of the non-reactive regeneration gas to a temperature in the range of 270° C. to 350° C. for a period of 5 hours to 15 hours, to obtain a regenerated adsorbent bed;

wherein the total time required for regeneration of the spent adsorbent bed is in the range of 30 hours to 40 hours.

2. The process as claimed in claim 1 , wherein the non-reactive regeneration gas is Nitrogen.

3. The process as claimed in claim 1 , wherein the non-reactive regeneration gas is Nitrogen with moisture content up to 5 ppm.

4. The process as claimed in claim 1 , wherein the temperature of the non-reactive regeneration gas stream passing through the spent adsorbent bed after sulfur capturing during the second purging is in the range of 25° C. to 250° C.

5. The process as claimed in claim 1 , wherein the hydrolyzing agent is water vapor.

6. The process as claimed in claim 1 , wherein the peak concentration of the hydrolyzing agent is in the range of 1000 ppm to 2000 ppm.

7. The process as claimed in claim 1 , wherein the hydrolyzing agent at its peak concentration is passed to the adsorbent bed for a period in the range of 5 hours to 10 hours.

8. The process as claimed in claim 1 , in which equilibrium sulfur loading capacity of the regenerated adsorbent is in the range of 0.2 to 0.3 wt %.

Assignees

• Das Asit
• Gupta Ajay
• Vaja Bharat Kumar
• Tulsi Govind
• Bisht Harender
• Sinha Jeyavel
• Jagutse Shubhangi
• Mandal Sukumar
• Reliance Ind Ltd

Inventors

• Das Asit
• Gupta Ajay
• Vaja Bharat Kumar
• Tulsi Govind
• Bisht Harender
• Sinha Jeyavel
• Jagutse Shubhangi
• Mandal Sukumar

Classifications

• C10G25/12

  Recovery of used adsorbent · CPC title

• B01J20/3458

  in the gas phase · CPC title

• B01J20/3433

  of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425 · CPC title

• C10G2300/807

  Steam · CPC title

• C10G2300/202

  Heteroatoms content, i.e. S, N, O, P · CPC title