Insulated wire for vehicle use and cable for vehicle use

Patent metadata

Field	Value
Publication number	US-9443645-B2
Application number	US-201313916520-A
Country	US
Kind code	B2
Filing date	Jun 12, 2013
Priority date	Jul 3, 2012
Publication date	Sep 13, 2016
Grant date	Sep 13, 2016

Abstract

An insulated wire for vehicle use includes a conductor and an insulating layer disposed on an outer circumference of the conductor. The insulating layer comprises a halogen-free flame retardant cross-linkable resin composition containing a base polymer, and a silane coupling agent and a metal hydroxide which are added to the base polymer. The base polymer includes, as major components, (a) an ethylene-vinyl acetate copolymer (EVA) and (b) an acid-modified olefin resin having a Tg of −55° C. or lower at a ratio (a):(b) of 70:30 to 100:0 and has an acetic acid content (VA) of 50% to 70% by mass. The silane-coupling agent is added in an amount of 1 to 5 parts by mass and the metal hydroxide is added in an amount of 100 to 250 parts by mass relative to 100 parts by mass of the base polymer.

First claim

What is claimed is:

1. An insulated wire for vehicle use comprising:
a conductor; and
an insulating layer disposed on an outer circumference of the conductor, wherein the insulating layer comprises a halogen-free flame retardant cross-linkable resin composition containing a base polymer, and a silane coupling agent and a metal hydroxide which are added to the base polymer;
the base polymer includes, as major components, (a) an ethylene-vinyl acetate copolymer (EVA) and (b) an acid-modified olefin resin having a glass transition temperature (Tg) determined by DSC of −55° C. or lower at a ratio (a):(b) of 70:30 to 100:0 and has an acetic acid content (VA) of 50% to 70% by mass;
the silane-coupling agent is added in an amount of 1 to 5 parts by mass relative to 100 parts by mass of the base polymer; and
the metal hydroxide is added in an amount of 100 to 250 parts by mass relative to 100 parts by mass of the base polymer, wherein the EVA includes two or more types of EVAs and includes 5% to 10% by mass of an EVA having a melt flow rate (MFR) of 15 g/10 min or more
wherein the silane coupling agent includes one or more vinyl silane compounds, one or more amino silane compounds, one or more epoxy silane compounds, one or more acrylsilane compounds, one or more polysulfide silane compounds and one or more mercaptosilane compounds.

2. A cable for vehicle use comprising:
a conductor;
an insulating layer disposed on an outer circumference of the conductor; and
a sheath disposed on an outer circumference of the insulating layer, wherein the sheath comprises a halogen-free flame retardant cross-linkable resin composition containing a base polymer, and a silane coupling agent and a metal hydroxide which are added to the base polymer;
the base polymer includes, as major components, (a) an ethylene-vinyl acetate copolymer (EVA) and (b) an acid-modified olefin resin having a glass transition temperature (Tg) determined by DSC of −55° C. or lower at a ratio (a):(b) of 70:30 to 100:0 and has an acetic acid content (VA) of 50% to 70% by mass;
the silane-coupling agent is added in an amount of 1 to 5 parts by mass relative to 100 parts by mass of the base polymer; and
the metal hydroxide is added in an amount of 100 to 250 parts by mass relative to 100 parts by mass of the base polymer, wherein the EVA includes two or more types of EVAs and includes 5% to 10% by mass of an EVA having a melt flow rate (MFR) of 15 g/10 min or more
wherein the silane coupling agent includes one or more vinyl silane compounds, one or more amino silane compounds, one or more epoxy silane compounds, one or more acrylsilane compounds, one or more polysulfide silane compounds and one or more mercaptosilane compounds.

3. The insulated wire for vehicle use according to claim 1 , wherein the base polymer includes, as major components, (a) an ethylene-vinyl acetate copolymer (EVA) and (b) an acid-modified olefin resin having a glass transition temperature (Tg) determined by DSC of −55° C. or lower at a ratio (a):(b) of 70:30 to 90:10.

4. The cable for vehicle use according to claim 2 , wherein the base polymer includes, as major components, (a) an ethylene-vinyl acetate copolymer (EVA) and (b) an acid-modified olefin resin having a glass transition temperature (Tg) determined by DSC of −55° C. or lower at a ratio (a):(b) of 70:30 to 90:10.

5. The insulated wire for vehicle use according to claim 1 , wherein the acid-modified olefin resin includes ultralow-density polyethylene, ethylene-methyl acrylate copolymers, ethylene-ethyl acrylate copolymers, ethylene-butene-1 copolymers, ethylene-hexene-1 copolymers, and ethylene-octene-1 copolymers which have been subjected to acid modification.

6. The cable for vehicle use according to claim 2 , wherein the acid-modified olefin resin includes ultralow-density polyethylene, ethylene-methyl acrylate copolymers, ethylene-ethyl acrylate copolymers, ethylene-butene-1 copolymers, ethylene-hexene-1 copolymers, and ethylene-octene-1 copolymers which have been subjected to acid modification.

7. The insulated wire for vehicle use according to claim 1 , wherein the acid is a material selected from the group consisting of maleic acid, maleic anhydride, and fumaric acid.

8. The cable for vehicle use according to claim 2 , wherein the acid is a material selected from the group consisting of maleic acid, maleic anhydride, and fumaric acid.

9. The insulated wire for vehicle use according to claim 1 , wherein the metal hydroxide is a material selected from the group consisting of aluminum hydroxide, magnesium hydroxide, and calcium hydroxide.

10. The cable for vehicle use according to claim 2 , wherein the metal hydroxide is a material selected from the group consisting of aluminum hydroxide, magnesium hydroxide, and calcium hydroxide.

11. The cable for vehicle use according to claim 2 , wherein the insulating layer includes at least one polymer selected from the group consisting of ethylene-butene-1 copolymer rubber, polybutylene naphthalate, polybutylene terephthalate, polyphenylene oxide, and polyether ether ketone.

12. The insulated wire for vehicle use according to claim 1 , wherein the metal hydroxide has a surface-treated agent.

13. The cable for vehicle use according to claim 2 , wherein the metal hydroxide has a surface-treated agent.

14. The insulated wire for vehicle use according to claim 12 , wherein the surface-treated agent includes is a material selected from the group consisting of a silane coupling agent, a titanate coupling agent and a fatty acid.

15. The cable for vehicle use according to claim 13 , wherein the surface-treated agent is a material selected from the group consisting of a silane coupling agent, a titanate coupling agent and a fatty acid.

16. The insulated wire for vehicle use according to claim 1 , wherein the silane-coupling agent is not a surface-treated agent for the metal hydroxide.

17. The cable for vehicle use according to claim 2 , wherein the silane-coupling agent is not a surface-treated agent for the metal hydroxide.

Assignees

• Hitachi Cable
• Hitachi Metals Ltd

Inventors

• Iwasaki Makoto
• Segawa Kentaro
• Kimura Hitoshi

Classifications

• C08K3/22

  of metals · CPC title

• C08K5/14

  Peroxides · CPC title

• H01B3/448

  from other vinyl compounds · CPC title

• Y10T428/2958

  Metal or metal compound in coating · CPC title

• C08K2003/2227

  of aluminium · CPC title