Organic resin laminate, methods of making and using the same, and articles comprising the same

Patent metadata

Field	Value
Publication number	US-9441133-B2
Application number	US-201113259855-A
Country	US
Kind code	B2
Filing date	Aug 26, 2011
Priority date	Aug 26, 2011
Publication date	Sep 13, 2016
Grant date	Sep 13, 2016

Abstract

An organic resin laminate comprising an organic resin substrate and a multilayer coating system thereon has weather resistance and mar resistance. The multilayer coating system includes an outermost layer (I) which is a hard film resulting from plasma polymerization of an organosilicon compound and an intermediate layer (II) which is a cured film of a composite coating composition (2) comprising inorganic oxide nanoparticle and vinyl copolymer.

First claim

What is claimed is:

1. An organic resin laminate having weather resistance and mar resistance, comprising an organic resin substrate and a multilayer coating system on a surface of the substrate,
the multilayer coating system including an outermost layer (I) which is a hard film resulting from plasma polymerization of an organosilicon compound and an intermediate layer (II) which is a cured film formed from a composite coating composition (2), the intermediate layer (II) having one surface disposed contiguous to the outermost layer and another surface disposed contiguous to the organic resin substrate,
wherein the composite coating composition (2) comprises
(2-A) an inorganic oxide nanoparticle;
(2-B) a vinyl copolymer; and
(2-C) a solvent;
wherein the inorganic oxide nanoparticle comprises at least one of silica, zinc oxide, titanium oxide, and cerium oxide;
wherein the vinyl copolymer has an organic UV-absorptive group and a reactive group; and
wherein the reactive group is selected from among alkoxysilyl, hydroxyl, epoxy, carboxylic acid and amino groups;

wherein the outermost layer (I) includes an inner sub-layer and an outer sub-layer, wherein the inner sub-layer has a refractive index in the range of 1.449 to 1.463 and the outer sub-layer has a refractive index in the range of 1.430 to 1.434;
wherein the inner sub-layer has a nano-indentation hardness in the range of 1.616 to 1.676 GPa and the outer sub-layer has a nano indentation hardness in the range of 2.265 to 2.667GPa; and
wherein the inner sub-layer is contiguous with the intermediate layer (II).

2. The laminate of claim 1 , wherein the outermost layer (I) is a hard film obtained from plasma polymerization and oxidation of an organosilicon compound and comprising silicon, oxygen, carbon, and hydrogen.

3. The laminate of claim 1 , wherein the substrate is a single layer and wherein the multilayer coating system is in physical contact with the surface of the substrate.

4. The laminate of claim 1 , wherein the substrate is a multilayer substrate comprising a coextruded or laminated base resin and cap-layer, wherein the multilayer coating system is in physical contact with the surface of the substrate.

5. The laminate of claim 4 , wherein the cap-layer comprises a material selected from the group consisting of a urethane resin, an acrylic resin, and combinations comprising at least one of the foregoing.

6. The laminate of claim 1 , wherein the outermost layer (I) has a total thickness in the range of 2.5 to 5.0 μm.

7. The laminate of claim 1 , wherein the outermost layer (I) has a total thickness in the range of 2.7 to 3.5 μm.

8. The laminate of claim 1 , wherein the laminate exhibits a pass rate of at least 97% in the adhesion test of ASTM D3359 Method B and ASTM D870 using de-ionized water at 65° C. for 3 days and a delta haze value of less than 2% in the Taber abrasion test of ASTM D1044 using 1000 cycles.

9. The laminate of claim 1 , wherein the vinyl copolymer (2-B) is a copolymer comprising (2-B-i) 5 wt % to 50 wt % of a vinyl monomer having an organic UV absorptive group, (2-B-ii) 2 wt % to 30 wt % of a vinyl monomer having a reactive group selected from among alkoxysilyl, hydroxyl, epoxy, carboxylic acid, amino groups, and combinations comprising at least one of the foregoing reactive groups, and (2-B-iii) 20 wt % to 93 wt % of another monomer capable of copolymerizing with the vinyl monomers.

10. The laminate of claim 9 , wherein the reactive group is selected from among alkoxysilyl, hydroxyl, epoxy groups, and combinations comprising at least one of the foregoing reactive groups.

11. The laminate of claim 1 , wherein the composite coating composition (2) further comprises (2-D) a silicone resin obtained from (co)hydrolytic condensation of a member selected from alkoxysilanes having the general formulae (1) to (3) and partial hydrolytic condensates thereof,
(R 1 ) m (R 2 ) n Si(OR 3 ) 4−m−n   (1)

wherein R 1 and R 2 are each independently hydrogen or a substituted or unsubstituted monovalent hydrocarbon group, R 1 and R 2 may bond together, R 3 is C 1 -C 3 alkyl, m and n are independently 0 or 1, and m+n is 0, 1 or 2,
(R 4 O) 3−p (R 6 ) p Si—R 8 —Si(R 7 ) q (OR 5 ) 3−q   (2)

wherein R 4 and R 5 are each independently C 1 -C 3 alkyl, R 6 and R 7 are each independently hydrogen or a substituted or unsubstituted monovalent hydrocarbon group, R 8 is oxygen, phenylene, or substituted or unsubstituted C 2 -C 10 alkylene, p and q are independently 0 or 1,
X—[(R 15 )Si(R 16 ) y (OR 17 ) 3−y ] z   (3)

wherein X is a 1,3,5-trimethylcyclotrisiloxane residue, 1,3,5,7-tetramethylcyclotetrasiloxane residue or isocyanurate residue, R 15 is C 1 -C 3 alkylene, R 16 is hydrogen or a substituted or unsubstituted monovalent hydrocarbon group, R 17 is C 1 -C 3 alkyl, y is 0 or 1, and z is an integer of 3 to 4.

12. The laminate of claim 11 , wherein the silicone resin (2-D) is obtained from alkoxysilanes of formulae (1), (2) and (3) which are combined such that a ratio of (1)/[(2)+(3)] is from 50/50 to 0/100 in Si-mol %.

13. The laminate of claim 11 , wherein in formula (1), R 1 is a monovalent hydrocarbon group substituted with a methyl or UV absorptive group, m=1, n=0, and R 3 is methyl, in formula (2), R 8 is substituted or unsubstituted C 2 -C 8 alkylene, p=q=0, R 4 and R 5 are methyl, and in formula (3), X is isocyanurate residue, y=0, R 15 is propylene, R 17 is methyl, and z=3.

14. The laminate of claim 1 , wherein the silicone resin (2-D) is obtained from hydrolytic condensation of a member selected from alkoxysilanes having formulae (2) and (3) and partial hydrolytic condensates thereof.

15. The laminate of claim 1 , wherein the silicone resin (2-D) is obtained from hydrolytic condensation of an alkoxysilane having formula (3) and partial hydrolytic condensate thereof.

16. The laminate of claim 1 , wherein the composite coating composition (2) further comprises an organic UV absorber and/or organic UV stabilizer other than (2-B).

17. The laminate of claim 1 , wherein the organic resin substrate is a molded polycarbonate resin.

18. A method of making an organic resin laminate, comprising:
forming a an organic resin substrate;
applying a composite coating composition (2) to a surface of the substrate, wherein the composite coating composition comprises
(2-A) an inorganic oxide nanoparticle ;
(2-B) a vinyl copolymer; and
(2-C) a solvent;
wherein the inorganic oxide nanoparticle comprises at least one of silica, zinc oxide, titanium oxide, and cerium oxide;
wherein the vinyl copolymer has an organic UV-absorptive group and a reactive group; and
wherein the reactive group is selected from among alkoxysilyl, hydroxyl, epoxy, carboxylic acid and amino groups;

forming an outermost layer (I) onto the composite coating composition by plasma polymerization of an organosilicon compound; and
curing the coating composition (2) to form an intermediate layer (II); wherein the outermost layer (I) includes an inner sub-layer and an outer sub-layer, wherein the inner sub-layer is contiguous with the intermediate layer (II)
wherein the inner sub-layer has a refractive index in the range of 1.449 to 1.463 and the outer sub-layer has a refractive index in the range of 1.430 to 1.434; and
wherein the inner sub-layer has a nano-indentation hardness in the range of 1.616 to 1.676 GPa and the outer sub-layer has a nano indentation hardness in the range of 2.265 to 2.667 GPa.

Assignees

• Gilliam Mary
• Higuchi Koichi
• Exatec Llc
• Shinetsu Chemical Co

Inventors

• Gilliam Mary
• Higuchi Koichi

Classifications

• C08J7/0423

  with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder · CPC title

• C08J2369/00

  Characterised by the use of polycarbonates; Derivatives of polycarbonates · CPC title

• B32B33/00

  Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class · CPC title

• C08J2443/04

  Homopolymers or copolymers of monomers containing silicon · CPC title

• C08J2433/14

  of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen · CPC title