Sol-gel transition control of coatings by addition of solidifiers for conformal coatings on textured glass

Patent metadata

Field	Value
Publication number	US-9441119-B2
Application number	US-201113072860-A
Country	US
Kind code	B2
Filing date	Mar 28, 2011
Priority date	Mar 28, 2011
Publication date	Sep 13, 2016
Grant date	Sep 13, 2016

Abstract

Embodiments of the invention generally relate to methods and compositions for forming conformal coatings on textured substrates. More specifically, embodiments of the invention generally relate to sol-gel processes and sol-gel compositions for forming low refractive index conformal coatings on textured transparent substrates. In one embodiment a method of forming a conformal coating on a textured glass substrate is provided. The method comprises coating the textured glass substrate with a sol-gel composition comprising a solidifier. It is believed that use of the solidifier expedites the sol-gel transition point of the sol-gel composition leading to more conformal deposition of coatings on textured substrates.

First claim

What is claimed is:

1. A method of making a sol-gel composition, comprising:
mixing a film forming precursor, an acid or base containing catalyst, water, and an alcohol containing solvent to form a reaction mixture by at least one of a hydrolysis and polycondensation reaction; and
subsequently adding a solidifier to the reaction mixture;
wherein the solidifier is added in an amount sufficient to expedite the sol-gel transition point without solidifying the sol when added to the sol-gel composition prior to application of the sol-gel composition to a substrate, and
wherein the sol-gel composition comprises up to 0.1 wt. % of the solidifier in the total sol-gel composition.

2. The method of claim 1 , wherein the solidifier is selected from the group comprising: gelatin, sodium acrylate, sodium acryloyldimethyl taurate, isohexadecane, polyoxyethylene (80) sorbitan monooleate, silica gel, polyethylene glycol (PEG) having a molecular mass between 200 and 1,000, low molecular mass organic gelators, charge neutralizers, cellulose derivatives, and combinations thereof.

3. The method of claim 2 , wherein the solidifier is selected from the group comprising polyethylene glycol (PEG) having a molecular mass between 200 and 1,000 and hydroxypropylcellulose.

4. The method of claim 1 , further comprising:
adding a porosity forming agent to the reaction mixture.

5. The method of claim 4 , wherein the porosity forming agent is selected from the group of self assembling molecular porogens comprising: polyoxyethylene stearyl ether, benzoalkoniumchloride (BAC), cetyltrimethylammoniumbromide (CTAB), 3-glycidoxypropyltrimethoxysilane, polyethyleneglycol (PEG), ammonium lauryl sulfate (ALS), dodecyltrimethylammoniumchloride (DTAC), polyalkyleneoxide modified hepta-methyltrisiloxane, and combinations thereof.

6. The method of claim 1 , wherein the solidifier is present in the sol-gel system in an amount from 0.0001 to 0.1 wt. % of the total weight of the sol-gel composition.

7. The method of claim 1 , wherein the film forming precursor is a silane containing precursor or silicon alkoxide containing precursor selected from the group comprising: tetraethylorthosilicate (TEOS), 3-glycidoxypropyltrimethoxysilane (Glymo), octadecyltrimethoxysilane (OTS), propyltriethoxysilane (PTES), (heptadecafluoro) ,1,2,2-tetrahydrodecyltrimethoxysilane, methyltriethoxysilane (MTES), hexamethyldisilazane (HMDS), and combinations thereof.

8. The method of claim 1 , wherein the sol remains in low viscosity liquid phase after addition of the solidifier.

9. The method of claim 1 , wherein the solidifier is polyoxyethylene (80) sorbitan monooleate.

10. The method of claim 1 , wherein the sol-gel composition further comprises silica nanoparticles.

11. A composition for forming a sol-gel system, comprising:
a film forming precursor;
wherein the film forming precursor is a silicon containing precursor selected from the group comprising: tetraethylorthosilicate (TEOS), 3-glycidoxypropyltrimethoxysilane (Glymo), octadecyltrimethoxysilane (OTS), propyltriethoxysilane (PTES), (heptadecafluoro) 1,1,2,2-tetrahydrodecyltrimethoxysilane, hexamethyldisilazane (HMDS), methyltriethoxysilane (MTES), and combinations thereof;
wherein the silicon containing precursor is present at a concentration between 1 wt. % and 10 wt. %;
an acid or base containing catalyst present at a concentration between 0.001 wt. % and 0.1 wt. %;
an alcohol containing solvent present at a concentration between 80 wt. % and 95 wt. %;
a solidifier present at a concentration between 0.0001 wt. % and 0.1 wt. %; and
water present at a concentration between 0.001 wt. % and 0.1 wt. %;
wherein the solidifier is added in an amount sufficient to expedite the sol-gel transition point without solidifying the sol when added to the sol-gel composition prior to application of the sol-gel composition to a substrate, and
wherein the sol-gel composition comprises up to 0.1 wt. % of the solidifier in the total sol-gel composition.

12. The composition of claim 11 , wherein the solidifier is selected from the group comprising: gelatin, sodium acrylate, sodium acryloyldimethyl taurate, isohexadecane, polyoxyethylene (80) sorbitan monooleate, silica gel, polyethylene glycol (PEG) having a molecular mass between 200 and 1,000, low molecular mass organic gelators, charge neutralizers, cellulose derivatives, and combinations thereof.

13. The composition of claim 11 , wherein the solidifier is selected from the group comprising polyethylene glycol (PEG) having a molecular mass between 200 and 1,000 and hydroxypropylcellulose.

14. The composition of claim 11 , wherein the sol remains in low viscosity liquid phase after addition of the solidifier.

15. The composition of claim 11 , wherein the solidifier is polyoxyethylene (80) sorbitan monooleate.

16. The composition of claim 11 , further comprising silica nanoparticles.

Assignees

• Kalyankar Nikhil D
• Kumar Nitin
• Sun Zhi-Wen
• Intermolecular Inc

Inventors

• Kalyankar Nikhil D
• Kumar Nitin
• Sun Zhi-Wen

Classifications

• C23C18/1245

  Inorganic substrates other than metallic · CPC title

• C03C17/02

  with glass (C03C17/34, C03C17/44 take precedence) · CPC title

• C09D7/1266 Primary

  Chemistry & Metallurgy · mapped topic

• C08L1/284

  with hydroxylated hydrocarbon radicals · CPC title

• C03C1/008

  for the production of films or coatings · CPC title