Mixtures, methods and compositions pertaining to conductive materials

Patent metadata

Field	Value
Publication number	US-9441117-B2
Application number	US-201313843271-A
Country	US
Kind code	B2
Filing date	Mar 15, 2013
Priority date	Mar 20, 2012
Publication date	Sep 13, 2016
Grant date	Sep 13, 2016

Abstract

This invention pertains to mixtures and methods that can be used to produce materials comprising an electrically and/or thermally conductive coating as well as compositions that are materials that possess an electrically and/or thermally conductive coating. The mixtures and methods can be used to fabricate transparent conductive films and other transparent conductive materials.

First claim

We claim:

1. A mixture, comprising:
a) at least one alcohol solvent selected from the group consisting of methyl alcohol, isopropyl alcohol and a mixture thereof;
b) at least one ester solvent selected from the group consisting of methyl acetate, ethyl acetate, butyl acetate and isopropyl acetate;
at least one cellulose ether solvated in the solvents a) and b); and
d) anisotropic conductive nanoparticles uniformly dispersed in the mixture,
wherein:
a proportion of the at least one alcohol solvent a) in the mixture is from about 70% to about 99.5% by volume of the mixture; and
a proportion of the at least one ester solvent b) in the mixture is not greater than about 30% by volume of the mixture.

2. The mixture of claim 1 , wherein a proportion of the alcohol solvent a) in the mixture is from 70% to 90% by volume of the mixture.

3. The mixture of claim 1 , further comprising at least one conductive polymer.

4. The mixture of claim 1 , wherein:
the anisotropic conductive nanoparticles d) and the cellulose ether c) re solids; and
a proportion of the solids in the mixture ranges from about 0.01 to about 80 weight percent of the mixture.

5. The mixture of claim 1 , wherein the anisotropic conductive nanoparticles e) are metal nanowires, metal flakes, metal nanospheres, metal nanotubes, carbon nanotubes, graphene, or any possible combination thereof.

6. The mixture of claim 1 , wherein a weight ratio of the anisotropic conductive nanoparticles d) to the cellulose ether c) ranges from about one part (by weight) anisotropic conductive nanoparticles d) to ten thousand parts (by weight) cellulose ether c) to about ninety-five parts (by weight) anisotropic conductive nanoparticles d) to one part (by weight) cellulose ether c).

7. The mixture of claim 1 , wherein a proportion of the at least one alcohol solvent a) in the mixture is from about 75% to about 99.5% by volume of the mixture.

8. The mixture of claim 1 , wherein the anisotropic conductive nanoparticles d) comprise a non-conductive binder, resin or additive coating that inhibits conduction between the anisotropic conductive nanoparticles d).

9. The mixture of claim 1 , wherein the mixture further comprises a non-conductive binder, resin or additive that is capable of inhibiting conduction between the anisotropic conductive nanoparticles d).

10. A method, comprising:
a) contacting at least part of at least one surface of a substrate with the mixture of claim 1 ; and
b) permitting the alcohol solvent i) and the ester solvent ii) of the mixture to evaporate to thereby form a conductive layer on the substrate.

11. The method of claim 10 , wherein a proportion of the alcohol solvent a) in the mixture is from 70% to 90% by volume of the mixture.

12. The method of claim 10 , wherein the mixture further comprises at least one conductive polymer.

13. The method of claim 10 , wherein the anisotropic conductive nanoparticles iv) are metal nanowires, metal flakes, metal nanospheres, metal nanotubes, carbon nanotubes, graphene, or any possible combination thereof.

14. The method of claim 10 , wherein a weight ratio of the anisotropic conductive nanoparticles iv) to the cellulose ether iii) ranges from about one part (by weight) anisotropic conductive nanoparticles iv) to ten thousand parts (by weight) cellulose ether iii) to about ninety-five parts (by weight) anisotropic conductive nanoparticles iv) to one part (by weight) cellulose ether iii).

15. The method of claim 10 , wherein a proportion of the at least one alcohol solvent i) in the mixture is from about 75% to about 99.5% by volume of the mixture.

16. The method of claim 10 , wherein the anisotropic conductive nanoparticles iv) comprise a non-conductive binder, resin or additive coating that inhibits conduction between the anisotropic conductive nanoparticles iv).

17. The method of claim 10 , wherein the mixture further comprises a non-conductive binder, resin or additive that is capable of inhibiting conduction between the anisotropic conductive nanoparticles iv).

18. A composition, comprising a substrate with the mixture of claim 1 applied thereto to thereby form a substantially uniform coating on at least part of at least one surface of said substrate.

19. The composition of claim 18 , wherein a proportion of the alcohol solvent a) in the mixture is from 70% to 90% by volume of the mixture.

20. The composition of claim 18 , wherein a proportion of the alcohol solvent a) in the mixture is from about 75% to 99.5% by volume.

21. The composition of claim 18 , wherein the anisotropic conductive nanoparticles d) are metal nanowires, metal flakes, metal nanospheres, metal nanotubes, carbon nanotubes, graphene, or any possible combination thereof.

22. The composition of claim 18 , wherein the anisotropic conductive nanoparticles d) are silver nanowires.

23. The composition of claim 18 , wherein the anisotropic conductive nanoparticles d) comprise a non-conductive binder, resin or additive coating that inhibits conduction between the anisotropic conductive nanoparticles d).

24. The composition of claim 18 , wherein the mixture further comprises a non-conductive binder, resin or additive that is capable of inhibiting conduction between the anisotropic conductive nanoparticles d).

Assignees

• Basf Se

Inventors

• Schultz David
• Glass James
• Garcia Benjamin W C

Classifications

• Y10T428/25

  Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles · CPC title

• C09K5/08

  Materials not undergoing a change of physical state when used (C09K5/16, C09K5/20 take precedence) · CPC title

• C09D139/06

  Homopolymers or copolymers of N-vinyl-pyrrolidones · CPC title

• C08K2003/0806

  Silver · CPC title

• C09D101/26

  Cellulose ethers · CPC title