Production of para-xylene

Patent metadata

Field	Value
Publication number	US-9440893-B2
Application number	US-201414153399-A
Country	US
Kind code	B2
Filing date	Jan 13, 2014
Priority date	Jan 31, 2013
Publication date	Sep 13, 2016
Grant date	Sep 13, 2016

Abstract

In a process for producing para-xylene, benzene and/or toluene is alkylated with methanol in the presence of a catalyst under conditions including a temperature of at least 500° C. and an H 2 O partial pressure of at least 12 psia (83 kPaa). The catalyst comprises from 5 to 15 wt % ZSM-5, phosphorus or a compound thereof and a binder and has been steamed at a temperature of at least 900° C. The steamed catalyst has no more than two peaks in the 31 P MAS NMR spectrum in the range of 0 to −50 ppm.

First claim

The invention claimed is:

1. A process for producing para-xylene, the process comprising:
(a) providing a catalyst comprising ZSM-5, phosphorus or a compound thereof and a clay binder, wherein the catalyst contains from 5 to 15 wt % ZSM-5 and has been steamed at a temperature of at least 900° C., wherein said steamed catalyst has a Diffusion Parameter for 2,2 dimethylbutane of about 0.1-15 sec −1 when measured at a temperature of 120° C. and a 2,2 dimethylbutane pressure of 60 torr (8 kPa); and
(b) alkylating benzene and/or toluene with an alkylating agent selected from methanol, dimethyl ether, and mixtures thereof to produce para-xylene and water vapor as a by-product, in the presence of said steamed catalyst under conditions including a temperature of at least 500° C. and an H 2 O partial pressure of at least 4-15 psia (about 104 kPaa), wherein additional steaming of the catalyst occurs during the alkylation reaction and the Diffusion Parameter for 2,2 dimethylbutane of the catalyst does not exceed about 35 sec −1 during the reaction.

2. The process of claim 1 , wherein the catalyst in (a) comprises from 2 to less than 8 wt % of elemental phosphorus.

3. The process of claim 1 , wherein the ZSM-5 is an aluminosilicate having a silica/alumina molar ratio of at least 200.

4. The process of claim 1 , wherein the catalyst contains from 8 to 10 wt % ZSM-5.

5. The process of claim 1 , wherein the catalyst contains from 75 to 90 wt % binder.

6. The process of claim 1 , wherein the catalyst in (a) has been steamed at a temperature of at least 900° C. for between about 10 minutes and about 1.5 hours.

7. The process of claim 1 , wherein said conditions in (b) also include a temperature between about 500 and 700° C., a total reactor pressure of between about 1 atmosphere and 1000 psig (100 and 7000 kPa), a weight hourly space velocity between about 0.5 and about 1000 and a molar ratio of toluene to methanol of at least about 0.2.

8. The process of claim 1 , wherein the upper limit of H 2 O partial pressure is less than 1000 psig (7000 kPa).

9. The process of claim 1 , wherein the silica/alumina molar ratio of the catalyst is less than 1,000.

Assignees

• Exxonmobil Chemical Patents Inc

Inventors

• Helton Terry E
• Tinger Robert G
• Han Lu
• Wight Andrea P

Classifications

• C07C2521/16

  Clays or other mineral silicates · CPC title

• C07C15/08

  Xylenes · CPC title

• C07C2/862 Primary

  the non-hydrocarbon contains only oxygen as hetero-atoms · CPC title

• C07C2529/40

  of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 · CPC title

• C07C2/864 Primary

  the non-hydrocarbon is an alcohol · CPC title