Coatings for high temperature components

Patent metadata

Field	Value
Publication number	US-9440287-B2
Application number	US-201414460504-A
Country	US
Kind code	B2
Filing date	Aug 15, 2014
Priority date	Aug 15, 2014
Publication date	Sep 13, 2016
Grant date	Sep 13, 2016

Abstract

A method for forming a coating on a substrate is provided. To an assembly 10 including a substrate 12 , a porous matrix 14 on the substrate 12 , and an impregnating material 16 on or within the porous matrix 14 , the method includes applying an amount of energy 18 from an energy source 20 effective to melt the impregnating material 16 and a portion of the substrate. In this way, the impregnating material 16 impregnates the porous matrix 14 . The method further includes cooling the assembly 10 to provide a coating 26 comprising the porous matrix 14 integrated with the substrate 12.

First claim

What we claim is:

1. A method of coating a substrate comprising:
to an assembly comprising a substrate, a porous matrix on the substrate, and an impregnating material on or within the porous matrix, applying an amount of energy from an energy source effective to melt the impregnating material and a portion of the substrate such that the impregnating material impregnates the porous matrix; and
cooling the assembly to provide a coating comprising the impregnated porous matrix integrated with the substrate;
wherein the porous matrix comprises a material having a higher melting temperature than that of the impregnating material.

2. The method of claim 1 , wherein the substrate and the impregnating material comprise a composition selected from the group consisting of a superalloy material, titanium aluminide, a cermet material, and a ceramic material.

3. The method of claim 1 , further comprising forming the assembly via:
disposing the porous matrix on the substrate; and
disposing the impregnating material on or within the porous matrix.

4. The method of claim 1 , wherein the porous matrix comprises a metal oxide selected from the group consisting of alumina, antimony(III) oxide, boria, chromium oxide, cobalt oxide, copper oxide, europium oxide, iron oxide, nickel oxide, silica, tin oxide, titanium oxide, yttrium oxide, zinc oxide, zirconium oxide, and combinations thereof.

5. The method of claim 1 , wherein the porous matrix comprises a ceramic material selected from the group consisting of alumina, zirconia, silica, silicon carbide, silicon nitride, aluminum nitride, silicon oxynitride, silicon carbonitride, mullite, cordierite, beta spodumene, aluminum titanate, a strontium aluminum silicate, a lithium aluminum silicate, and combinations thereof.

6. The method of claim 1 , wherein the porous matrix further comprises a material selected from the group consisting of a fullerene structure, a carbon yarn, a carbon fiber, a carbon nanobud, a graphene structure, a diamond-like carbon coated material, a carbon honeycomb, a carbon fabric, and combinations thereof.

7. The method of claim 1 , further comprising:
adding a high temperature material to a top of the assembly, wherein the high temperature material is selected from the group consisting of a metal oxide material, titanium aluminide, a cermet material, and a ceramic material;
melting the high temperature material during the applying an amount of energy from an energy source; and
cooling the molten high temperature material to form an outer layer therefrom on the coating which is integrated with the porous matrix.

8. The method of claim 7 , wherein the high temperature material comprises a metal oxide material selected from the group consisting of alumina, antimony(III) oxide, boria, chromium oxide, cobalt oxide, copper oxide, europium oxide, iron oxide, nickel oxide, silica, tin oxide, titanium oxide, yttrium oxide, zinc oxide, zirconium oxide, and combinations thereof.

9. The method of claim 7 , wherein a portion of the impregnating material is melted during the applying an amount of energy from an energy source.

10. The method of claim 7 , further comprising:
adding a flux powder to the assembly; and
melting the flux powder during the applying an amount of energy from an energy source to form a removable slag layer on the outer layer of the coating.

11. The method of claim 1 , wherein the porous matrix has a non-uniform porosity therethrough.

12. The method of claim 1 , wherein an amount of porosity remains in the porous matrix after the cooling.

13. A method for forming a coating on a substrate comprising:
to an assembly comprising a substrate, a porous matrix on the substrate, an impregnating material on or within the porous matrix, and a high temperature material selected from the group consisting of a metal oxide material, titanium aluminide, a cermet material, and a ceramic material on an outer portion of the assembly, applying an amount of energy to the assembly from an energy source,
wherein the amount of energy is effective to melt the high temperature material, the impregnating material, and a portion of the substrate such that the impregnating material impregnates the porous matrix;
wherein the porous matrix comprises a material having a higher melting temperature than that of the impregnating material; and

cooling the assembly to provide a coating comprising a network integrated with the substrate, the network comprising the porous matrix and an outer layer formed from the high temperature material.

14. The method of claim 13 , wherein the substrate and the impregnating material comprise a material selected from the group consisting of a superalloy material, titanium aluminide, a cermet material, and a ceramic material.

15. The method of claim 13 , further comprising forming the assembly via:
disposing the porous matrix on the substrate;
disposing the impregnating material on or within the porous matrix; and
disposing the high temperature material on the impregnating material.

16. The method of claim 13 , wherein the porous matrix and the high temperature material comprise a metal oxide material selected from the group consisting of alumina, antimony(III) oxide, boria, chromium oxide, cobalt oxide, copper oxide, europium oxide, iron oxide, nickel oxide, silica, tin oxide, titanium oxide, yttrium oxide, zinc oxide, zirconium oxide, and combinations thereof.

17. The method of claim 13 , wherein the porous matrix and the high temperature material comprise a ceramic material selected from the group consisting of alumina, zirconia, silica, silicon carbide, silicon nitride, aluminum nitride, silicon oxynitride, silicon carbonitride, mullite, cordierite, beta spodumene, aluminum titanate, a strontium aluminum silicate, a lithium aluminum silicate, and combinations thereof.

18. The method of claim 13 , wherein an amount of porosity remains in the porous matrix after the cooling.

Assignees

• Siemens Energy Inc

Inventors

• Bruck Gerald J
• Kamel Ahmed

Classifications

• B22F7/002 Primary

  of porous nature · CPC title

• F01D9/02

  Nozzles; Nozzle boxes; Stator blades; Guide conduits {, e.g. individual nozzles (nozzle boxes F01D9/047)} · CPC title

• C23C28/3455

  with a refractory ceramic layer, e.g. refractory metal oxide, ZrO2, rare earth oxides or a thermal barrier system comprising at least one refractory oxide layer · CPC title

• C23C28/321

  with at least one metal alloy layer · CPC title

• B23K26/348

  in combination with arc heating, e.g. tungsten inert gas [TIG], metal inert gas [MIG] or plasma welding · CPC title