Process for catalyst activation

Patent metadata

Field	Value
Publication number	US-9440211-B2
Application number	US-201514919853-A
Country	US
Kind code	B2
Filing date	Oct 22, 2015
Priority date	Nov 30, 2010
Publication date	Sep 13, 2016
Grant date	Sep 13, 2016

Abstract

The invention relates generally to a catalyst activator, and in particular to a catalyst activator for heat conditioning a catalyst, comprising: a) a vessel for containing a catalyst charge having an internal diameter of at least 1.2 meters and/or an internal volume of at least 5 m 3 ; b) a fluidization grid plate disposed in said vessel, said fluidization grid plate and having an upper major surface and a lower major surface; c) an array of generally conical depressions in said upper major surface that overlap by less than 17%; and d) an array of holes perforating said fluidization grid plate, said holes extending from at least some of said generally conical depressions through said lower surface.

First claim

The invention claimed is:

1. A process for activating a batch of polymerisation catalyst which comprises fluidising the batch of polymerisation catalyst in a fluidisation zone of an activator vessel, wherein the activator vessel comprises a fluidisation zone and a disengagement zone above the fluidisation zone, the diameter of the fluidisation zone of the activator vessel being at least 1 m, the height of the fluidised bed of catalyst being at least twice the diameter of the fluidisation zone and the height of the disengagement zone being between 1 to 3 m.

2. A process according to claim 1 wherein the height of the fluidised bed of catalyst is at least three times the diameter, for example at least four times the diameter.

3. A process according to claim 1 wherein the height of the fluidised bed of catalyst is between 2 and 8 m, and preferably between 4 and 8 m.

4. A process according to claim 1 wherein the expansion on fluidisation is above 100%, such as at least 120%.

5. A process according to claim 1 wherein the diameter of the fluidisation zone of the activator vessel is at least 1.2 m, and preferably at least 1.5 m.

6. A process according to claim 1 wherein the settled bed has a depth between 1.8 and 3 m.

7. A process according to claim 1 wherein the settled bed has a bulk volume of greater than 1.5 m 3 .

8. A process according to claim 1 wherein the height of the disengagement zone is between 1 to 2 bed diameters.

9. A process according to claim 1 wherein the height of the disengagement zone is between 0.25 to 0.75 times the height of the fluidisation zone.

10. A process according to claim 1 wherein the disengagement zone has the same cross-sectional area as the fluidisation zone such that the fluidisation zone and disengagement zone form a single cylindrical activator vessel having a total height between 3 and 11 m.

11. A process for activating a batch of polymerisation catalyst which comprises fluidising the batch of polymerisation catalyst in a fluidisation zone of an activator vessel, the diameter of the fluidisation zone of the activator vessel being at least 1.2 m and the height of the fluidised bed of catalyst being at least twice the diameter of the fluidisation zone.

12. A process according to claim 11 wherein the height of the fluidised bed of catalyst is at least three times the diameter, for example at least four times the diameter.

13. A process according to claim 11 wherein the height of the fluidised bed of catalyst is between 2 and 8 m, and preferably between 4 and 8 m.

14. A process according to claim 11 wherein the expansion on fluidisation is above 100%, such as at least 120%.

15. A process according to claim 11 wherein the diameter of the fluidisation zone of the activator vessel is at least 1.5 m.

16. A process according to claim 11 wherein the settled bed has a depth between 1.8 and 3 m.

17. A process according to claim 11 wherein the settled bed has a bulk volume of greater than 1.5 m 3 .

18. A process according to claim 11 wherein the activator vessel comprises a fluidisation zone and a disengagement zone above the fluidisation zone, the height of the disengagement zone being between 1 to 3 m.

19. A process according to claim 11 wherein the activator vessel comprises a fluidisation zone and a disengagement zone above the fluidisation zone, the height of the disengagement zone being between 1 to 2 bed diameters.

20. A process according to claim 11 wherein the activator vessel comprises a fluidisation zone and a disengagement zone above the fluidisation zone, the disengagement zone having the same cross-sectional area as the fluidisation zone such that the fluidisation zone and disengagement zone form a single cylindrical activator vessel having a total height between 3 and 11 m.

Assignees

• Ineos Europe Ag

Inventors

• King Alex
• Lee Stephen Kevin
• Walworth Brent R

Classifications

• B01J23/26 Primary

  Chromium · CPC title

• B01J8/44

  Fluidisation grids · CPC title

• B01J2208/00991

  Disengagement zone in fluidised-bed reactors · CPC title

• C08F4/78

  selected from chromium, molybdenum or tungsten · CPC title

• B01J2208/00415

  electric resistance heaters · CPC title