Colouring solution for selectively treating the surface of dental ceramic and related methods

Patent metadata

Field	Value
Publication number	US-9439838-B2
Application number	US-201214237207-A
Country	US
Kind code	B2
Filing date	Jul 27, 2012
Priority date	Aug 11, 2011
Publication date	Sep 13, 2016
Grant date	Sep 13, 2016

Abstract

The invention relates to a solution to be selectively applied to individual parts of the surface of dental ceramic(s) and a process for using the solution in the dental field. More specifically the invention relates to a solution comprising a) a solvent, b) an effect agent, and c) a complexing agent. The invention also relates to a kit comprising the solution and to a method of using the solution for selectively treating of parts of the surface dental ceramic(s). The invention also relates to a application instrument suitable for applying the solution.

First claim

The invention claimed is:

1. A process of selectively treating parts of the surface of a dental ceramic comprising the steps of
a) providing a solution and a dental ceramic having an outer surface,
wherein the solution comprises
a solvent being miscible with water but not being water,
an effect agent comprising metal ions, the effect caused by the effect agent being either colouring, providing fluorescence or a combination thereof,
a complexing agent being able to form a complex with the metal ions of the effect agent,
wherein the complex is soluble in the solvent, the solution having a viscosity above about 200 mPa*s at 23° C.,
wherein the water-content of the solution is below about 10 wt.-% with respect to the whole composition,

b) applying the solution to only a part of the outer surface of the dental ceramic,
c) optionally drying the dental ceramic, and
d) optionally firing the dental ceramic.

2. The process according to claim 1 , wherein the dental ceramic comprises ZrO 2 , Al 2 O 3 , TiO 2 or mixtures thereof.

3. The process according to claim 2 , wherein the dental ceramic fulfills at least one of the following conditions: a) the dental ceramic is in a pre-sintered stage, b) the dental ceramic is wet.

4. A process of selectively treating parts of the surface of a dental ceramic comprising the steps of
a) providing a solution and a dental ceramic having an outer surface,
wherein the solution comprises
a solvent being miscible with water but not being water and having a molecular weight from about 60 to about 1,000 g/mol,
an effect agent comprising metal ions, the effect caused by the effect agent being either colouring, providing fluorescence or a combination thereof,
a complexing agent being able to form a complex with the metal ions of the effect agent,
wherein the complex is soluble in the solvent, the solution having a viscosity above about 200 mPa*s at 23° C.,
wherein the water-content of the solution is below about 10 wt.-% with respect to the whole composition,

b) applying the solution to only a part of the outer surface of the dental ceramic,
c) optionally drying the dental ceramic, and
d) optionally firing the dental ceramic.

5. The process according to claim 4 , wherein the solvent comprises a polyalcohol.

6. The process according to claim 4 , wherein the solvent comprises ethylene glycol, polyethylene glycols, glycerol, or mixtures thereof.

7. The process according to claim 4 , wherein the solvent comprises glycerol.

8. A process of selectively treating parts of the surface of a dental ceramic comprising the steps of
a) providing a solution and a dental ceramic having an outer surface,
wherein the solution comprises
a solvent being miscible with water but not being water and having a molecular weight from about 100 to about 5,000 g/mol,
an effect agent comprising metal ions, the effect caused by the effect agent being either colouring, providing fluorescence or a combination thereof,
a complexing agent being able to form a complex with the metal ions of the effect agent,
wherein the complex is soluble in the solvent, the solution having a viscosity above about 200 mPa*s at 23° C.,
wherein the water-content of the solution is below about 10 wt.-% with respect to the whole composition,

b) applying the solution to only a part of the outer surface of the dental ceramic,
c) optionally drying the dental ceramic, and
d) optionally firing the dental ceramic.

9. The process according to claim 8 , wherein the solvent comprises polyethylene glycol.

10. The process according to claim 8 , wherein the polyethylene glycol is of the formula: R1O—(CH2-CH2-O)m-R1, where R1 is H, Acyl, Alkyl, Aryl, Alkylaryl, Polypropylglycol, or Poly-THF, and m is about 2 to about 100.

11. The process according to claim 10 , where R1 is H, Acetyl, Methyl, Ethyl, Propyl, Butyl, Hexyl, Octyl, Nonyl, Decyl, Lauryl, Tridecyl, Myristyl, Palmityl, Stearyl, Oleyl, Allyl, Phenyl, p-Alkylphenyl, Polypropyleneglycol, or Poly-THF.

12. The process according to claim 10 , where m is 2 to 20.

Assignees

• Jahns Michael
• Doebert Philipp
• Hauptmann Holger
• Kindler Grit
• 3M Innovative Properties Co

Inventors

• Jahns Michael
• Doebert Philipp
• Hauptmann Holger
• Kindler Grit

Classifications

• A61K6/849

  comprising inorganic cements · CPC title

• A61K6/20

  Protective coatings for natural or artificial teeth, e.g. sealings, dye coatings or varnish · CPC title

• A61K6/65 Primary

  Dyes · CPC title

• C04B41/85 Primary

  with inorganic materials · CPC title

• A61K6/78

  Pigments · CPC title