Lithium-ion cell having a high-capacity anode and a high-capacity cathode

Patent metadata

Field	Value
Publication number	US-9437370-B2
Application number	US-201213385561-A
Country	US
Kind code	B2
Filing date	Feb 27, 2012
Priority date	Feb 27, 2012
Publication date	Sep 6, 2016
Grant date	Sep 6, 2016

Abstract

A lithium-ion cell comprising: (A) a cathode comprising graphene as the cathode active material having a surface area to capture and store lithium thereon and wherein said graphene cathode is meso-porous having a specific surface area greater than 100 m 2 /g; (B) an anode comprising an anode active material for inserting and extracting lithium, wherein the anode active material is mixed with a conductive additive and/or a resin binder to form a porous electrode structure, or coated onto a current collector in a coating or thin film form; (C) a porous separator disposed between the anode and the cathode; (D) a lithium-containing electrolyte in physical contact with the two electrodes; and (E) a lithium source disposed in at least one of the two electrodes when the cell is made. This new Li-ion cell exhibits an unprecedentedly high energy density.

First claim

We claim:

1. A lithium-ion cell comprising:
(a) a positive electrode (cathode) comprising graphene as the only cathode active material having a surface area to capture and store lithium thereon and wherein said graphene cathode is meso-porous having a specific surface area greater than 100 m 2 /g;
(b) a negative electrode (anode) comprising an anode active material for inserting and extracting lithium during a charge and discharge of said cell, wherein said anode active material is mixed with a conductive additive and/or a resin binder to form a porous electrode structure, or coated onto a current collector in a coating or thin film form, and wherein said anode active material is not pre-lithiated and is lithium-free when the cell is made, and wherein the anode active material is selected from the group consisting of:
(A) non-lithiated silicon (Si), germanium (Ge), tin (Sn), lead (Pb), antimony (Sb), bismuth (Bi), zinc (Zn), aluminum (Al), titanium (Ti), cobalt (Co), nickel (Ni), manganese (Mn), cadmium (Cd), and mixtures thereof;
(B) non-lithiated alloys or intermetallic compounds of Si, Ge, Sn, Pb, Sb, Bi, Zn, Al, Ti, Co, Ni, Mn, Cd, and their mixtures;
(C) non-lithiated oxides, carbides, nitrides, sulfides, phosphides, selenides, tellurides, or antimonides of Si, Ge, Sn, Pb, Sb, Bi, Zn, Al, Fe, Ti, Co, Ni, Mn, Cd, and mixtures or composites thereof;
(D) non-lithiated salts or hydroxides of Sn; and
(E) non-lithiated graphite or carbon materials in a particle or fibrous form; and combinations thereof;

(c) a porous separator disposed between the anode and the cathode;
(d) a lithium-containing electrolyte in ionic contact with the anode and the cathode; and
(e) a lithium source disposed in at least one of the two electrodes when the cell is made.

2. The lithium-ion cell of claim 1 wherein said graphene cathode active material is selected from a single-layer sheet or multi-layer platelet of graphene, graphene oxide, graphene fluoride, hydrogenated graphene, nitrogenated graphene, boron-doped graphene, nitrogen-doped graphene, functionalized graphene, reduced graphene oxide, or a combination thereof.

3. The lithium-ion cell of claim 1 wherein said graphene cathode active material is pristine graphene containing no oxygen.

4. The lithium-ion cell of claim 1 wherein said anode active material is silicon, germanium, tin, or tin oxide.

5. The lithium-ion cell of claim 1 wherein said cathode has a specific surface area greater than 500 m 2 /g.

6. The lithium-ion cell of claim 1 wherein said cathode has a specific surface area greater than 1,000 m 2 /g.

7. The lithium-ion cell of claim 1 wherein said cathode has a specific surface area greater than 1,500 m 2 /g.

8. The lithium-ion cell of claim 1 wherein said cathode active material contains a single-layer graphene sheet.

9. The lithium-ion cell of claim 1 wherein said cathode contains a conductive additive and/or a resin binder and said cathode forms a meso-porous structure having a pore size in the range of 2 nm and 50 nm.

10. The lithium-ion of claim 1 wherein said cathode further contains a conductive filler selected from graphite or carbon particles, carbon black, expanded graphite, carbon nanotube, carbon nano-fiber, carbon fiber, conductive polymer, or a combination thereof.

11. The lithium-ion cell of claim 1 , wherein the lithium source comprises a lithium chip, lithium alloy chip, lithium foil, lithium alloy foil, lithium powder, lithium alloy powder, surface stabilized lithium particles, a mixture of lithium metal or lithium alloy with a lithium intercalation compound, lithium or lithium alloy film coated on a surface of an anode or cathode active material, or a combination thereof.

12. The lithium-ion cell of claim 1 wherein said anode active material contains a high rate capable anode material selected from nano-scaled particles or filaments of a transition metal oxide, Co304, Mn304, Fe304, or a combination thereof.

13. The lithium-ion cell of claim 1 wherein said anode active material contains a nano material having a dimension less than 100 nm.

14. The lithium-ion cell of claim 1 , wherein the anode active material is a nano particle, nano disc, nano platelete, nano wire, nano-rod, nano belt, nano scroll, nano tube, nano filament, nano coating, or nano film.

15. The lithium-ion cell of claim 1 , further comprising an anode current collector and/or cathode current collector that is a porous, electrically conductive material selected from metal foam, metal web or screen, perforated metal sheet, metal fiber mat, metal nanowire mat, porous conductive polymer film, conductive polymer nano-fiber mat or paper, conductive polymer foam, carbon foam, carbon aerogel, carbon xerox gel, graphene foam, graphene oxide foam, reduced graphene oxide foam, carbon fiber paper, graphene paper, graphene oxide paper, reduced graphene oxide paper, carbon nano-fiber paper, carbon nano-tube paper, or a combination thereof.

16. The lithium-ion cell of claim 1 , wherein a discharge operation of said cell involves intercalating lithium into an inter-graphene space in a multi-layer graphene platelet and capturing and storing lithium on surfaces of a single-layer graphene sheet or multi-layer graphene platelet.

17. The lithium-ion cell of claim 1 , wherein the electrolyte is organic liquid electrolyte, ionic liquid electrolyte, gel electrolyte, polymer electrolyte, or solid electrolyte containing a first amount of lithium ions when said cell is made.

Assignees

• Chen Guorong
• Zhamu Aruna
• Wang Xiging
• Jang Bor Z
• Wang Yanbo
• Fang Qing
• Nanotek Instruments Inc

Inventors

• Chen Guorong
• Zhamu Aruna
• Wang Xiging
• Jang Bor Z
• Wang Yanbo
• Fang Qing

Classifications

• H01M4/387

  Tin or alloys based on tin · CPC title

• H01M4/485

  of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy (H01M4/505, H01M4/525 take precedence) · CPC title

• H01M4/483

  for non-aqueous cells (H01M4/485 takes precedence) · CPC title

• H01M4/587

  for inserting or intercalating light metals · CPC title

• H01G11/50 Primary

  specially adapted for lithium-ion capacitors, e.g. for lithium-doping or for intercalation · CPC title