Multifunctional sol-gel detector for gaseous compounds and detection and trapping methods therewith

Patent metadata

Field	Value
Publication number	US-9435746-B2
Application number	US-201113992154-A
Country	US
Kind code	B2
Filing date	Dec 14, 2011
Priority date	Dec 16, 2010
Publication date	Sep 6, 2016
Grant date	Sep 6, 2016

Abstract

The invention relates to a multifunctional detector for gaseous compounds, or mixtures of gaseous compounds, selected from NH 2 Cl, NHCl 2 , NCl 3 , total chlorine, NOx, where x=1 or 2, O 3 , and X 2 , where X=Cl, Br, or I, in a sample, said detector including a first sensor including an iodide and a reactive compound selected from starch, amylose, amylopectin, xyloglucan, xylan, chitosan, glycogen, polyvinyl alcohol, cellulose or a cellulose compound, α-cyclodextrin, theobromine, and polypropylene block polymers and polyethylene oxide block polymers, included in a block of sol-gel material that is absorbent in the UV spectrum but not in the visible spectrum. The invention also relates to the uses of said detector.

First claim

The invention claimed is:

1. A multifunctional detector for gaseous compounds or mixtures of gaseous compounds selected from NH 2 Cl; NHCl 2 ; NCl 3 ; total chlorine; NO n , where n=1 or 2; O 3 ; and X 2 , where X=Cl, Br or I in a sample, said detector comprising a first sensor consisting of i) a block of sol-gel material that absorbs in the UV but not in the visible ii) an iodide and iii) a reactive compound selected from starch, amylose, amylopectin, xyloglucan, xylane, chitosan, glycogen, polyvinyl alcohol or a polyvinyl alcohol compound, cellulose or a cellulose compound, α-cyclodextrin, theobromine and block polymers of polypropylene oxides and polyethylene oxides, wherein the iodide and the reactive compound are incorporated into the block of sol-gel material.

2. The multifunctional detector as claimed in claim 1 , characterized in that in a block of sol-gel material of the first sensor, the iodide represents from 0.0054% to 0.55% by weight of the block.

3. The multifunctional detector as claimed in claim 1 , characterized in that in a block of sol-gel material of the first sensor, the reactive compound represents from 0.05% to 0.25% by weight of the block.

4. The multifunctional detector as claimed in claim 1 , suitable for gaseous compounds or mixtures of gaseous compounds selected from NH 2 Cl; NHCl 2 ; NCl 3 ; total chlorine; NO n where n=1 or 2; O 3 ; and X 2 where X=Cl, Br or I in a gaseous sample, said detector further comprising a first compartment containing the first sensor; and a second compartment comprising a second sensor, wherein the second sensor comprises phenol, sodium hydroxide, and sodium nitroprussiate, incorporated into a sol-gel matrix that absorbs in the UV but not in the visible.

5. The multifunctional detector as claimed in claim 4 , wherein the first compartment is sub-compartmentalized in order to contact two portions of the gaseous mixture, wherein the first portion of the gaseous mixture contacts a first sub-compartment containing a first sensor and the second portion of the gaseous mixture contacts a second sub-compartment containing a second first sensor, wherein the first portion of the gaseous mixture passes through a filter comprising a neutral silicate matrix impregnated with sulfamic acid to eliminate all the chlorinated species with the exception of NCl 3 before contacting the first sub-compartment of the first sensor, said filter being placed upstream of the first sensor.

6. The multifunctional detector as claimed in claim 5 , wherein in the filter comprising a neutral silicate matrix, the sulfamic acid represents from 5% to 15% by weight of the total of the silicate and sulfamic acid constituents of the neutral silicate matrix.

7. The multifunctional detector as claimed in claim 5 , wherein in the second sensor, the phenol represents from 10% to 25% by weight of the block of sol-gel material.

8. The multifunctional detector as claimed in claim 5 , wherein in the second sensor, sodium nitroprussiate represents from 0.01% to 0.25% by weight of the block of sol-gel material.

9. The multifunctional detector as claimed in claim 5 , wherein in the second sensor sodium hydroxide represents from 1% to 17% by weight of the block of sol-gel material.

10. A process for detecting gaseous compounds or a mixture of gaseous compounds selected from NH 2 Cl; NHCl 2 ; NCl 3 ; total chlorine; NO n , where n=1 or 2; O 3 ; and X 2 where X=Cl, Br or I contained in a liquid or gaseous sample, comprising exposing the multifunctional detector of claim 5 to a flow of a gas mixture or to a liquid and observing any color change of the blocks of sol-gel material of the first sensor or of the second sensor, and optionally identifying the presence of the gaseous compounds in the sample when a color change is observed.

11. A method for detecting of gaseous compounds or mixtures of gaseous compounds selected from NH 2 Cl; NHCl 2 ; NCl 3 ; total chlorine; NO n , where n=1 or 2; O 3 ; and X 2 where X=Cl, Br or I contained in a gas mixture sample, comprising contacting the multifunctional detector of claim 5 with said gas mixture sample and detecting said compounds with said detector.

12. The multifunctional detector as claimed in claim 4 , wherein in the second sensor, the phenol represents from 10% to 25% by weight of the block of sol-gel material.

13. The multifunctional detector as claimed in claim 4 , wherein in the second sensor, sodium nitroprussiate represents from 0.01% to 0.25% by weight of the block of sol-gel material.

14. The multifunctional detector as claimed in claim 4 , wherein in the second sensor sodium hydroxide represents from 1% to 17% by weight of the block of sol-gel material.

15. A process for detecting gaseous compounds or a mixture of gaseous compounds selected from NH 2 Cl; NHCl 2 ; NCl 3 ; total chlorine; NO n , where n=1 or 2; O 3 ; and X 2 where X=Cl, Br or I contained in a liquid or gaseous sample, comprising exposing the multifunctional detector of claim 4 to a flow of a gas mixture or to a liquid and observing any color change of the blocks of sol-gel material of the first sensor or of the second sensor, and optionally identifying the presence of the gaseous compounds in the sample when a color change is observed.

16. A method for detecting gaseous compounds or mixtures of gaseous compounds selected from NH 2 Cl; NHCl 2 ; NCl 3 ; total chlorine; NO n , where n=1 or 2; O 3 ; and X 2 where X=Cl, Br or I contained in a gas mixture sample, comprising contacting the multifunctional detector of claim 4 with said gas mixture sample and detecting said compounds with said detector.

17. The multifunctional detector as claimed in claim 1 , wherein the multifunctional detector further comprises a filter comprising a neutral silicate matrix impregnated with sulfamic acid in order to eliminate all the chlorinated species with the exception of NCl 3 from at least a portion of the gaseous compounds or mixtures of gaseous compounds before bringing into contact with the first sensor.

18. The multifunctional detector as claimed in claim 17 , wherein in the filter comprising a neutral silicate matrix, the sulfamic acid represents from 5% to 15% by weight of the total of the silicate and sulfamic acid constituents of the neutral silicate matrix.

19. The multifunctional detector as claimed in claim 1 , said detector further comprising two first sensors, a first compartment containing one of the two first sensors; and a second compartment containing the other of the two first sensors, wherein the first and second compartments contact two portions of the gaseous mixture, wherein the first portion of the gaseous mixture contacts the first sensor located in the first compartment and the second portion of the gaseous mixture contacts the other first sensor located in the second compartment, wherein the first portion of the gaseous mixture passes through a filter comprising a neutral silicate matrix impregnated with sulfamic acid to eliminate all the chlorinated species with the exception of NCl 3 before contacting the first sensor located in the first compartment, said filter being placed upstream of the first sensor.

20. A method for detecting gaseous compounds or mixtures of gaseous compounds selected from NH 2 Cl; NHCl 2 ; NCl 3 ; total chlorine; NO n , where n=1 or 2; O 3 ; and X 2 where X=Cl, Br or I contained in a gas mixture sample, comprising contacting the multifunctional detector of claim 1 with said gas mixture sample and detecting said compounds with said detector.

21. A process f

Assignees

• Tran-Thi Thu-Hoa
• Garcia Julien
• Nguyen Thi Dinh
• Nguyen Trung-Hieu
• Commissariat Energie Atomique
• Centre Nat De La Rech Scientifique—Crns

Inventors

• Tran-Thi Thu-Hoa
• Garcia Julien
• Nguyen Thi Dinh
• Nguyen Trung-Hieu

Classifications

• Y10T436/19

  Halogen containing · CPC title

• Y10T436/177692

  Oxides of nitrogen · CPC title

• G01N21/783 Primary

  for analysing gases · CPC title

• Y10T436/173845

  Amine and quaternary ammonium · CPC title

• G01N31/224

  for investigating presence of dangerous gases · CPC title