Method and apparatus for degassing a liquid and analytical device having the apparatus

Patent metadata

Field	Value
Publication number	US-9435729-B2
Application number	US-201213717818-A
Country	US
Kind code	B2
Filing date	Dec 18, 2012
Priority date	Dec 19, 2011
Publication date	Sep 6, 2016
Grant date	Sep 6, 2016

Abstract

A method for degassing a liquid by means of a piston pump unit having a receiving chamber serving for accommodating the liquid to be degassed and connected with at least one supply line and at least one drain line, and a piston seated in the receiving chamber for performing stroke movements. The piston provides a liquid sealing of the receiving chamber on one end. The following steps are included: drawing liquid via the supply line into the receiving chamber by performing a first stroke movement of the piston in the case of blocked drain line and open supply line; producing a negative pressure in the receiving chamber by continuing the first stroke movement of the piston in the case of blocked supply line and blocked drain line; and opening the drain line and removing a gas phase present in the receiving chamber from the receiving chamber via the drain line by performing a second stroke movement of the piston directed counter to the first stroke movement in the case of an opened drain line and blocked supply line.

First claim

The invention claimed is:

1. An apparatus for performing a method for degassing a liquid comprising:
a piston pump unit comprising a receiving chamber serving for accommodating a liquid to be degassed;
a piston movable in said receiving chamber and sealing said receiving chamber on one end;
a liquid supply comprising the liquid to be degassed;
at least one supply line connecting said receiving chamber with said liquid supply;
at least a first drain, line connected with said receiving chamber;
a valve unit, by means of which said at least one supply line and said first drain line are selectively blockable, at least at times; and
a control unit configured to control the apparatus for performing the method for degassing a liquid comprising the steps:
controlling the valve unit to block said first drain line and to connect said liquid supply via the at least one supply line with the receiving chamber and controlling the piston to perform a first stroke movement of the piston and to draw the liquid from said liquid supply via said at least one supply line into the receiving chamber;
controlling the valve unit to block both said first drain line and said at least one supply line and controlling the piston to continue the first stroke movement in such a way, that a negative pressure is produced in the receiving chamber;
controlling the valve unit to open said first drain line and to block said at least one supply line and controlling the piston to perform a second stroke movement in direction opposed to the first stroke movement and to remove a gas phase present in the receiving chamber from said receiving chamber via said first drain line.

2. The apparatus as claimed in claim 1 , further comprising:
heating means for heating liquid contained in said receiving chamber.

3. The apparatus as claimed in claim 1 , further comprising:
a waste container;
a second drain line, and
a receiving container, wherein:
said receiving chamber is connected via said first drain line with said waste container for accommodating the gas phase removed from said receiving chamber, and via the second drain line with said receiving container for the degassed liquid.

4. The apparatus as claimed in claim 3 , wherein:
said valve unit comprises a 4/4 valve.

5. The apparatus according to claim 1 ,
said valve unit comprising one of: one or more valves with associated control mechanisms.

6. The apparatus according to claim 3 ,
said valve unit comprising one of: one or more valves with associated control mechanisms or a multiport valve.

7. The apparatus as claimed in claim 3 ,
said valve unit comprising a multiport valve, which is configured to be actuated by the control unit to be set into four different states, wherein:
in a first state, said multiport valve connects said liquid supply via said at least one supply line with said receiving chamber and blocks said first and second drain lines,
in a second state, said multiport valve blocks said at least one supply line, said first drain line and said second drain line,
in a third state, said multiport valve connects said waste container with said receiving chamber via said first drain line and blocks said at least one supply line and said second drain line,
in a fourth state, said multiport valve connects said receiving container with said receiving chamber via said at least second drain line and blocks said at least one supply line and said first drain line.

8. The apparatus as claimed in claim 1 , wherein:
said piston pump comprises a syringe cylinder and said piston is axially movably seated in the syringe cylinder,
said receiving chamber is surrounded by the syringe piston and the syringe cylinder and said syringe cylinder comprises a syringe outlet which opens ihto the receiving chamber.

9. The apparatus as claimed in claim 7 ,
said syringe outlet is connected with the liquid supply line and the first drain line via the valve unit.

10. The apparatus as claimed in claim 3 , wherein:
said piston pump comprises a syringe cylinder and said piston is axially movably seated in the syringe cylinder,
said receiving chamber is surrounded by the syringe piston and the syringe cylinder and said syringe cylinder comprises a syringe outlet which opens into the receiving chamber, and
said syringe outlet is connected with the liquid supply line and the first and second drain lines via the valve unit.

11. The apparatus as claimed in claim 10 , further comprising:
a receiving container;
a second drain line connecting the receiving container and the receiving chamber via said valve unit;
and said valve unit is configured to be actuated by the control unit to be set into a forth state, in which said valve unit connects said receiving container with said receiving chamber via said at least second drainline and blocks said at least one supply line and said first drain line.

12. The apparatus as claimed in claim 10 , wherein:
said valve unit comprising one of: one or more valves with associated control mechanisms or a multiport valve.

13. The apparatus as claimed in claim 10 , wherein:
the control unit is configured to control the apparatus for performing the method for degassing the liquid comprising the steps:
setting the valve unit in said first state and controlling the piston to perform a first stroke movement of the piston and to draw the liquid from said liquid supply via said at least one supply line into the receiving chamber;
setting the valve unit in said second state and controlling the piston to continue the first stroke movement in such a way, that a negative pressure is produced in the receiving chamber;
setting the valve unit in said third state and controlling the piston to perform a second stroke movement in direction opposed to the first stroke movement and to remove a gas phase present in the receiving chamber from said receiving chamber via said first drain line.

Assignees

• Endress + Hauser Conducta Ges Für Mess- Und Regeltechnik Mbh + Co Kg
• Endress & Hauser Conducta Gmbh & Co Kg

Inventors

• Bernhard Ralf

Classifications

• B01D19/0036 Primary

  Flash degasification (the other groups take precedence) · CPC title

• G01N21/51

  inside a container, e.g. in an ampoule (G01N21/53 takes precedence) · CPC title

• G01N21/17 Primary

  Systems in which incident light is modified in accordance with the properties of the material investigated (where the material investigated is optically excited causing a change in wavelength of the incident light G01N21/63) · CPC title