Method and apparatus for liquefying a hydrocarbon stream

Patent metadata

Field	Value
Publication number	US-9435583-B2
Application number	US-44204207-A
Country	US
Kind code	B2
Filing date	Sep 20, 2007
Priority date	Sep 22, 2006
Publication date	Sep 6, 2016
Grant date	Sep 6, 2016

Abstract

A method and apparatus for liquefying a hydrocarbon stream such as natural gas from a feed stream. A feed stream is provided and passed through at least two cooling stages. Each cooling stage involves one or more heat exchangers. One of the heat exchangers involves a first refrigerant circuit having a first refrigerant stream, and a second of the heat exchangers involves a second refrigerant circuit having a second refrigerant stream. The liquefied hydrocarbon stream is expanded and a flash vapor is separated to provide a liquefied hydrocarbon product stream and a gaseous stream. The gaseous stream, at least a part of the first refrigerant stream, and at least a part of the second refrigerant stream are passed through a heat exchanger, for the gaseous stream to provide cooling to the first and second refrigerant streams.

First claim

What is claimed is:

1. A method of liquefying a hydrocarbon stream from a feed stream, the method at least comprising the steps of:
(a) providing a feed stream;
(b) passing the feed stream through at least two cooling stages to provide a liquefied hydrocarbon stream, each cooling stage involving one or more heat exchangers, one of said heat exchangers involving a first refrigerant circuit having a first refrigerant stream of a first mixed refrigerant, and a second of said heat exchangers involving a second refrigerant circuit having a second refrigerant stream of a second mixed refrigerant;
(c) separating the first refrigerant stream into a first light refrigerant stream and a first heavy refrigerant stream, and separating the second refrigerant into a second light refrigerant stream and a second heavy refrigerant stream;
(d) expanding the liquefied hydrocarbon stream and separating flashed vapour from the liquefied hydrocarbon stream to provide a liquefied hydrocarbon product stream and a gaseous stream; and
(e) passing the gaseous stream, the first light refrigerant stream and the second light refrigerant stream through an end heat exchanger, for the gaseous stream to provide cooling to the first and second light refrigerant streams.

2. A method as claimed in claim 1 , wherein expanding the liquefied hydrocarbon stream, in step (d) comprises passing the liquefied hydrocarbon stream through one or more expansion stages.

3. A method as claimed in claim 1 , wherein the at least two cooling stages comprise a first cooling stage in the form of a pre-cooling stage followed by a second cooling stage in the form of a main cryogenic cooling stage.

4. A method as claimed in claim 3 , wherein the first cooling stage comprises two or more serial heat exchange steps.

5. A method as claimed in claim 3 , wherein the second cooling stage comprises two or more parallel heat exchange steps.

6. A method as claimed in claim 5 , wherein at least two of the heat exchangers of the second cooling stage involve separate refrigerant circuits, and at least part of the refrigerants of these separate refrigerant circuits provide the first and second light refrigerant streams of step (c).

7. A method as claimed in claim 5 , wherein the first cooling stage provides a pre-cooled hydrocarbon stream, which is divided between two or more part streams, and each part stream is separately liquefied in one or more cryogenic heat exchangers of the second cooling stage, each cryogenic heat exchanger providing a liquefied hydrocarbon part stream, which liquefied hydrocarbon part streams are combined to provide the liquefied hydrocarbon stream of step (b).

8. A method as claimed in claim 1 , wherein the mixed refrigerants of the first and second refrigerant circuits independently comprise two or more components selected from the group comprising nitrogen, methane, ethane, ethylene, propane, propylene, butane and pentane.

9. A method as claimed in claim 1 wherein the gaseous stream exits the end heat exchanger as a warmed gaseous stream, and further comprising a step (f) using the warmed gaseous stream exiting from the end heat exchanger as a fuel gas stream.

10. Apparatus for liquefying a hydrocarbon stream from a feed stream, the apparatus at least comprising:
two cooling stages to provide a liquefied hydrocarbon stream from the feed stream, each cooling stage involving one or more heat exchangers, one of said heat exchangers involving a first refrigerant circuit having a first refrigerant stream of first mixed refrigerant, and a second of said heat exchangers involving a second refrigerant circuit having a second refrigerant stream of a second mixed refrigerant;
a first separator in the first refrigerant circuit to separate the first mixed refrigerant stream into a first light refrigerant stream and a first heavy refrigerant stream and a second separator in the second refrigerant circuit to separate the second mixed refrigerant stream into a second light refrigerant stream and a second heavy refrigerant stream;
an end-flash system comprising a gas/liquid separator to receive the liquefied hydrocarbon stream and to provide a liquefied hydrocarbon product stream and a gaseous stream; and
an end heat exchanger arranged to receive the gaseous stream, the first light refrigerant stream and the second light refrigerant stream, and to allow the gaseous stream to provide cooling to the first and second light refrigerant streams.

11. The apparatus as claimed in claim 10 , wherein the end-flash system further comprises an expansion means.

12. A method as claimed in claim 2 , wherein the at least two cooling stages comprise a first cooling stage in the form of a pre-cooling stage followed by a second cooling stage in the form of a main cryogenic cooling stage.

13. A method as claimed in claim 12 , wherein the first cooling stage comprises two or more serial heat exchange steps.

14. A method as claimed in claim 4 , wherein the second cooling stage comprises two or more parallel heat exchange steps.

15. A method as claimed in claim 12 , wherein the second cooling stage comprises two or more parallel heat exchange steps.

16. A method as claimed in claim 13 , wherein the second cooling stage comprises two or more parallel heat exchange steps.

17. A method as claimed in claim 14 , wherein at least two of the heat exchangers of the second cooling stage involve separate refrigerant circuits, and at least part of the refrigerants of these separate refrigerant circuits provide the first and second light refrigerant streams of step (c).

18. A method as claimed in claim 15 , wherein at least two of the heat exchangers of the second cooling stage involve separate refrigerant circuits, and at least part of the refrigerants of these separate refrigerant circuits provide the first and second light refrigerant streams of step (c).

19. A method as claimed in claim 16 , wherein at least two of the heat exchangers of the second cooling stage involve separate refrigerant circuits, and at least part of the refrigerants of these separate refrigerant circuits provide the first and second light refrigerant streams of step (c).

20. A method as claimed in claim 6 , wherein the first cooling stage provides a pre-cooled hydrocarbon stream, which is divided between two or more part streams, and each part stream is separately liquefied in one or more cryogenic heat exchangers of the second cooling stage, each cryogenic heat exchanger providing a liquefied hydrocarbon part stream, which liquefied hydrocarbon part streams are combined to provide the liquefied hydrocarbon stream of step (b).

Assignees

• Dam Willem
• Kong Ming Teck
• Zoetemeijer Leendert Johannes Arie
• Shell Oil Co

Inventors

• Dam Willem
• Kong Ming Teck
• Zoetemeijer Leendert Johannes Arie

Classifications

• F25J1/0292

  Refrigerant compression by cold or cryogenic suction of the refrigerant gas · CPC title

• F25J1/0267

  using flash gas as heat sink · CPC title

• F25J2205/02

  using simple phase separation in a vessel or drum · CPC title

• F25J1/0271

  Inter-connecting multiple cold equipments within or downstream of the cold box · CPC title

• F25J1/0052

  by vaporising a liquid refrigerant stream · CPC title