Process for converting FCC naphtha into aromatics

Patent metadata

Field	Value
Publication number	US-9434894-B2
Application number	US-201414309623-A
Country	US
Kind code	B2
Filing date	Jun 19, 2014
Priority date	Jun 19, 2014
Publication date	Sep 6, 2016
Grant date	Sep 6, 2016

Abstract

A method and apparatus for processing hydrocarbons are described. The method includes fractionating a hydrocarbon stream to form at least two fractions. The first fraction is reformed to form a reformate stream, and the reformate stream is introduced into an aromatics processing zone to produce aromatic products. At least a portion of the second fraction is cracked in a fluid catalytic cracking unit. A selectively hydrogenated light naphtha stream is formed by separating the cracked hydrocarbon stream into at least two streams and selectively hydrogenating the light naphtha stream, or selectively hydrogenating the cracked hydrocarbon stream and separating the hydrogenated cracked hydrocarbon stream into at least two streams. Aromatics are extracted from the selectively hydrogenated light naphtha stream forming an extract stream and a raffinate stream. The extract stream is hydrotreated, sent to the aromatics processing zone to produce additional aromatic products.

First claim

What is claimed:

1. A method for processing hydrocarbons comprising:
fractionating a hydrocarbon stream in a fractionation unit to form at least two fractions including a first fraction and a second fraction;
reforming the first fraction in a reforming unit to form a reformate stream;
introducing the reformate stream into an aromatics processing zone to produce select aromatic products;
cracking at least a portion of the second fraction in a fluid catalytic cracking unit to form a cracked hydrocarbon stream;
forming a selectively hydrogenated light naphtha stream by separating the cracked hydrocarbon stream into at least two streams including a light naphtha stream and a heavy naphtha stream and selectively hydrogenating the light naphtha stream, or selectively hydrogenating the cracked hydrocarbon stream and separating the hydrogenated cracked hydrocarbon stream into at least two streams including a light naphtha stream and a heavy naphtha stream;
extracting aromatics from the selectively hydrogenated light naphtha stream in an aromatic extraction unit to form an extract stream and a raffinate stream containing olefins; and
introducing the extract stream into the aromatics processing zone to produce additional aromatic products.

2. The method of claim 1 wherein the selectively hydrogenated light naphtha stream is formed by separating the cracked hydrocarbon stream into at least two streams including the light naphtha stream and the heavy naphtha stream and selectively hydrogenating the light naphtha stream.

3. The method of claim 2 further comprising at least one of:
hydrotreating the heavy naphtha stream and blending the hydrogenated heavy naphtha stream into gasoline; and
blending a portion of the selectively hydrogenated light naphtha stream with gasoline.

4. The method of claim 1 further comprising:
blending the raffinate stream containing the olefins with gasoline.

5. The method of claim 1 wherein the selectively hydrogenated light naphtha stream is formed by selectively hydrogenating the cracked hydrocarbon stream and separating the hydrogenated cracked hydrocarbon stream into at least two streams including a light naphtha stream and a heavy naphtha stream.

6. The method of claim 1 further comprising combining at least a portion of the reformate stream with the extract stream.

7. The method of claim 6 wherein combining at least the portion of the reformate stream with the extract stream comprises combining the reformate stream with the extract stream before introducing the combined stream into the aromatics processing zone.

8. The method of claim 1 wherein the aromatics processing zone comprises at least a second aromatic extraction unit and a separation unit, and wherein introducing the reformate stream into the aromatics processing zone comprises introducing the reformate stream into the second aromatic extraction unit, and further comprising:
extracting aromatics from the reformate stream in the second aromatic extraction unit to form a reformate extract stream and a reformate raffinate stream;
and wherein the extract stream is hydrotreated before introducing the extract stream into the aromatics processing zone, and wherein introducing the extract stream into the aromatics processing zone comprises combining the hydrotreated extract stream with the reformate extract stream and further processing the combined stream in the separation unit.

9. The method of claim 1 further comprising at least one of:
hydrotreating the heavy naphtha stream and blending the hydrotreated heavy naphtha stream into gasoline; and
blending a portion of the light naphtha stream into gasoline.

10. The method of claim 1 further comprising introducing selectively hydrotreated pyrolysis naphtha to the aromatic extraction unit.

11. The method of claim 1 wherein the aromatics processing zone comprises at least a second aromatic extraction unit, a separation unit, and a toluene disproportionation and transalkylation process unit, and wherein introducing the extract stream into the aromatics processing zone comprises introducing the extract stream into the toluene disproportionation and transalkylation process unit, and further comprising hydrotreating the extract stream in the toluene disproportionation and transalkylation process unit.

12. The method of claim 1 further comprising hydrotreating the extract stream prior to introducing the extract stream into the aromatics processing zone.

13. A method for processing hydrocarbons comprising:
fractionating a hydrocarbon stream in a fractionation unit to form at least two fractions including a C 6 -C 10 fraction and a C 11+ fraction;
reforming the C 6 -C 10 fraction in a reforming unit to form a reformate stream;
introducing the reformate stream to an aromatics processing zone to produce select aromatic products;
cracking at least a portion of the C 11+ fraction in a fluid catalytic cracking unit to form a cracked stream;
forming a selectively hydrogenated first stream comprising at least C 6 -C 9 hydrocarbons by separating the cracked stream into at least two streams including the first stream comprising at least the C 6 -C 9 hydrocarbons and a second stream comprising C 10+ hydrocarbons and selectively hydrogenating the first stream comprising at least the C 6 -C 9 hydrocarbons, or selectively hydrogenating the cracked stream and separating the hydrogenated cracked stream into at least two streams including the first stream comprising at least the C 6 -C 9 hydrocarbons and a second stream comprising C 10+ hydrocarbons;
extracting aromatics from the selectively hydrogenated first stream comprising at least the C 6 -C 9 hydrocarbons in an aromatic extraction unit to form an extract stream and a raffinate stream containing olefins; and
introducing the extract stream into the aromatics processing zone to produce additional aromatic products.

14. The method of claim 13 wherein the selectively hydrogenated first stream comprising at least C 6 -C 9 hydrocarbons is formed by separating the cracked stream into at least two streams including the first stream comprising at least the C 6 -C 9 hydrocarbons and the second stream comprising C 10+ hydrocarbons and selectively hydrogenating the first stream comprising at least the C 6 -C 9 hydrocarbons.

15. The method of claim 14 further comprising at least one of:
hydrotreating the second stream comprising the C 10+ hydrocarbons and blending the hydrotreated second stream comprising C 10+ hydrocarbons into gasoline; and
blending a portion of the selectively hydrogenated first stream comprising at least the C 6 -C 9 hydrocarbons with gasoline.

16. The method of claim 13 further comprising introducing selectively hydrotreated pyrolysis naphtha to the aromatic extraction unit.

17. The method of claim 13 wherein the selectively hydrogenated first stream comprising at least C 6 -C 9 hydrocarbons is formed by selectively hydrogenating the cracked stream and separating the hydrogenated cracked stream into at least two streams including the first stream comprising at least the C 6 -C 9 hydrocarbons and a second stream comprising C 10+ hydrocarbons.

18. The method of claim 13 further comprising combining at least a portion of the reformate stream with the extract stream before introducing the combined stream into the aromatics processing zone.

19. The method of claim 13 wherein the aromatics processing zone comprises at least a second aromatic extraction unit and a separation unit, and wherein introducing the reformate strea

Assignees

• Uop Llc

Inventors

• Mehlberg Robert
• Noe Robert Jason Lee
• Negiz Antoine
• Zink Steven F

Classifications

• C10G69/08 Primary

  including at least one step of reforming naphtha · CPC title

• C10G35/04

  Catalytic reforming · CPC title

• C10G69/04

  including at least one step of catalytic cracking in the absence of hydrogen · CPC title

• C10G45/68

  Aromatisation of hydrocarbon oil fractions · CPC title

• C10G69/14

  plural parallel stages only · CPC title