Polymer in multicoat color and/or effect paint systems

Patent metadata

Field	Value
Publication number	US-9434855-B2
Application number	US-201314012198-A
Country	US
Kind code	B2
Filing date	Aug 28, 2013
Priority date	Aug 28, 2012
Publication date	Sep 6, 2016
Grant date	Sep 6, 2016

Abstract

Disclosed is a polymer which is prepared by reacting
(a) dimer fatty acids with (b) at least one polyether of general structural formula (I)

where R is a C 3 to C 6 alkylene radical and n is selected accordingly such that said polyether has a number-average molecular weight of 450 to 2200 g/mol, components (a) and (b) are used in a molar ratio of 0.7/2.3 to 1.3/1.7, and the resulting polymer has a number-average molecular weight of 1500 to 5000 g/mol and an acid number <10 mg KOH/g. Also disclosed is a pigmented aqueous basecoat material which comprises this polymer, and the use of said polymer in pigmented aqueous basecoat materials. It further relates to a method for producing multicoat paint systems, and also to the multicoat paint systems producible by means of said method. Moreover, the present invention relates to the refinish of defect areas on multicoat paint systems.

First claim

The invention claimed is:

1. A polymer comprising the reaction product of
(a) dimer fatty acids with
(b) at least one polyether of general structural formula (I)

where R is a C 4 to C 6 alkylene radical and n is selected accordingly such that said polyether has a number-average molecular weight of 450 to 2200 g/mol, components (a) and (b) are used in a molar ratio of 0.7/2.3 to 1.3/1.7, and the resulting polymer has a number-average molecular weight of 1500 to 5000 g/mol and an acid number of <10 mg KOH/g,
wherein when the polymer is incorporated into a pigmented aqueous basecoat material, the pigmented aqueous basecoat material is effective to form a film upon application to a substrate.

2. The polymer of claim 1 , wherein the dimer fatty acids used comprise at least 90% by weight of dimeric molecules, less than 5% by weight of trimeric molecules, and less than 5% by weight of monomeric molecules and other by-products.

3. The polymer of claim 1 , wherein the dimer fatty acid used is prepared from linolenic, linoleic and/or oleic acid and comprises at least 98% by weight of dimeric molecules, less than 1.5% by weight of trimeric molecules, and less than 0. 5% by weight of monomeric molecules and other by-products, and has an iodine number of <10 g/100 g.

4. The polymer of claim 1 , wherein the polyether of general structural formula (I) is polytetrahydrofuran and comprises a number-average molecular weight of 800 to 1200 g/mol.

5. The polymer of claim 1 , wherein components (a) and (b) are used in a molar ratio of 0.9/2.1 to 1.1/1.9.

6. The polymer of claim 1 , wherein the resulting polymer has a number-average molecular weight of 3000 to 4000 g/mol.

7. The polymer of claim 1 , wherein the resulting polymer has an acid number of <5 mg KOH/g.

8. A pigmented aqueous basecoat material comprising at least one polymer comprising the reaction product of
(a) dimer fatty acids with
(b) at least one polyether of general structural formula (I)

where R is a C 3 to C 6 alkylene radical and n is selected accordingly such that said polyether has a number-average molecular weight of 450 to 2200 g/mol, components (a) and (b) are used in a molar ratio of 0.7/2.3 to 1.3/1.7, and the resulting polymer has a number-average molecular weight of 1500 to 5000 g/mol and an acid number of <10 mg KOH/g,
wherein the pigmented aqueous basecoat material is effective to form a film upon application to a substrate.

9. The pigmented aqueous basecoat material of claim 8 , wherein the at least one polymer is present in an amount of 0.1% to 30% by weights, based on the total weight of the pigmented aqueous basecoat material.

10. The pigmented aqueous basecoat material of claim 8 , further comprising, as a further binder, at least one polyurethane resin.

11. The pigmented aqueous basecoat material of claim 8 , wherein the polyether general structural formula (I) is polypropylene glycol or polytetrahydrofuran and comprises a number-average molecular weights of 800 to 1200 g/mol.

12. A method of promoting adhesion, comprising adding a polymer to a pigmented aqueous basecoat material, the polymer comprising the reaction product of
(a) dimer fatty acids with
(b) at least one polyether of general structural formula (I)

where R is a C 3 to C 6 alkylene radical and n is selected accordingly such that said polyether has a number-average molecular weight of 450 to 2200 g/mol, components (a) and (b) are used in a molar ratio of 0.7/2.3 to 1.3/1.7, and the resulting polymer has a number-average molecular weight of 1500 to 5000 g/mol and an acid number of <10 mg KOH/g,
wherein when the polymer is incorporated into the pigmented aqueous basecoat material, the pigmented aqueous basecoat material is effective to form a film upon application to a substrate.

13. The method of claim 12 , wherein the polyether of general structural formula (I) is polypropylene glycol or polytetrahhydrofuran and comprises a number-average molecular weight of 800 to 1200 g/mol.

14. A method for producing a multicoat paint system, comprising
(1) applying the pigmented aqueous basecoat material of claim 8 to a substrate,
(2) forming a basecoat film,
(3) applying a clearcoat material to the basecoat film, and subsequently
(4) curing the basecoat film together with the clearcoat film.

15. The method of claim 14 , wherein said substrate from stage (1) comprises a multicoat paint system which has defect areas.

16. A multicoat paint system made by the method of claim 14 .

17. A pigmented aqueous basecoat material comprising at least one polymer comprising the reaction product of
(a) dimer fatty acids consisting of at least 90% by weight of dimeric molecules and less than 5% by weight of trimeric molecules with
(b) at least one polyether of general structural formula (I)

where R is a C 3 to C 6 alkylene radical and n is selected accordingly such that said polyether has a number-average molecular weight of 450 to 2200 g/mol, components (a) and (b) are used in a molar ratio of 0.7/2.3 to 1.3/1.7, and the resulting polymer has a number-average molecular weight of 1500 to 5000 g/mol and an acid number of <10 mg KOH/g,
wherein the pigmented aqueous basecoat material is effective to form a film upon application to a substrate.

Assignees

• Basf Coatings Gmbh

Inventors

• Hoffmann Peter
• Steinmetz Bernhard
• Lavalaye Jorn
• Reuter Hardy

Classifications

• C08G18/4252

  derived from polyols containing polyether groups and polycarboxylic acids · CPC title

• C09D167/08

  Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids · CPC title

• C08G63/676

  in which at least one of the two components contains aliphatic unsaturation · CPC title

• C08G63/00

  Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule (polyester-amides C08G69/44; polyester-imides C08G73/16) · CPC title

• Y10T428/31551

  Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.] · CPC title