Method for making carbon nanotube composite structure

Patent metadata

Field	Value
Publication number	US-9434815-B2
Application number	US-201414261562-A
Country	US
Kind code	B2
Filing date	Apr 25, 2014
Priority date	Jan 22, 2014
Publication date	Sep 6, 2016
Grant date	Sep 6, 2016

Abstract

A method for making a carbon nanotube composite structure includes suspending a carbon nanotube layer in a reactor. A polymer monomer solution and an oxidant solution are gasified by a pressure to form polymer monomer solution gas and oxidant solution gas. The polymer monomer solution gas is polymerized and chemically bonded to the carbon nanotube layer in initiation of the oxidant solution gas.

First claim

What is claimed is:

1. A method for making a carbon nanotube composite structure comprising:
providing a polymer monomer solution and an oxidant solution formed by dissolving an oxidant in a solvent;
gasifying the polymer monomer solution and the oxidant solution to form a polymer monomer solution gas and an oxidant solution gas by a pressure; and
suspending a carbon nanotube layer comprising a plurality of carbon nanotubes combined by van der Waals attractive force in the polymer monomer solution gas and the oxidant solution gas.

2. The method of claim 1 , comprising suspending the carbon nanotube layer in a reactor by two separate supporters or a ring shaped substrate.

3. The method of claim 2 , wherein the carbon nanotube layer is perpendicular to a lower sidewall and parallel to two sidewalls of the reactor.

4. The method of claim 1 , wherein the carbon nanotube layer comprises at least one drawn carbon nanotube film, at least one flocculated carbon nanotube film, or at least one pressed carbon nanotube film.

5. The method of claim 1 , wherein the carbon nanotube layer comprises two drawn carbon nanotube films comprising the plurality of carbon nanotubes, and an angle between aligned directions of the plurality of carbon nanotubes in the two drawn carbon nanotube films is in a range from about 0 degrees to about 90 degrees.

6. The method of claim 1 , comprising providing the polymer monomer solution in a first vessel located on upside of a first pipe and connected to the first pipe, and making the polymer monomer solution flow into the first pipe from the first vessel.

7. The method of claim 6 , comprising applying the pressure so that the polymer monomer solution in the first pipe become the polymer monomer solution gas, and directing the polymer monomer solution gas into a reactor connected to the first pipe.

8. The method of claim 1 , wherein the oxidant solution is in a second vessel located on upside of a second pipe and connected to the second pipe, and the oxidant solution flow into the second pipe from the second vessel.

9. The method of claim 8 , comprising applying the pressure so that the oxidant solution in the second pipe become the oxidant solution gas, and directing the oxidant solution gas into a reactor connected to the second pipe.

10. The method of claim 1 , wherein the pressure is provided by a compressed air source or ultrasonic generator.

11. The method of claim 1 , wherein the pressure is applied so that a flow speed of the polymer monomer solution gas and the oxidant solution gas is in a range from about 25 sccm to about 50 sccm, and the pressure is applied for from about 0.5 minutes to about 15 minutes.

12. The method of claim 1 , wherein the polymer monomer solution is aniline solution, and the oxidant solution is ammonium persulphate solution.

13. The method of claim 12 , wherein the pressure is applied so that a flow speed of aniline solution gas and ammonium persulphate solution gas is in a range from about 30 sccm to about 40 sccm, and the pressure is applied for from about 1 minute to about 4 minutes.

14. The method of claim 1 , wherein the polymer monomer solution gas is polymerized and chemically bonded to each of the plurality of carbon nanotubes by covalent bond.

15. A method for making a carbon nanotube composite structure comprising:
gasifying a polymer solution to form a polymer solution gas by a pressure; and
suspending a carbon nanotube layer comprising a plurality of carbon nanotubes joined end-to-end by van der Waals attractive force and arranged approximately along a same direction in the polymer solution gas.

16. The method of claim 15 , wherein the polymer solution is in a first vessel located on upside of a first pipe and connected to the first pipe, and the polymer solution flow into the first pipe from the first vessel.

17. The method of claim 16 , comprising applying the pressure so that the polymer solution in the first pipe become the polymer solution gas, and directing the polymer solution gas into a reactor connected to the first pipe.

18. The method of claim 15 , wherein the pressure is provided by a compressed air source or ultrasonic generator.

19. A method for making a carbon nanotube composite structure comprising:
suspending a carbon nanotube layer comprising a plurality of carbon nanotubes parallel to a surface of the carbon nanotube layer in a reactor; and
gasifying a polymer monomer solution and an oxidant solution to form a polymer monomer solution gas and an oxidant solution gas by a pressure, and filling the reactor with the polymer monomer solution gas and the oxidant solution gas, wherein the oxidant solution is formed by dissolving an oxidant in a solvent.

Assignees

• Univ Tsinghua
• Hon Hai Prec Ind Co Ltd

Inventors

• Yin yan-li
• Liu Chang-Hong
• Fan Shou-Shan

Classifications

• C08G73/0266 Primary

  Polyanilines or derivatives thereof · CPC title

• C01B31/0253

  Chemistry & Metallurgy · mapped topic

• C08F116/06

  Polyvinyl alcohol {; Vinyl alcohol} · CPC title

• C08L23/12

  Polypropene · CPC title

• C08G61/126

  with a five-membered ring containing one sulfur atom in the ring · CPC title