Methods and systems for upgrading mixed pyrolysis oil to light aromatics over mixed metal oxide catalysts
US-2024010934-A1 · Jan 11, 2024 · US
US9434614B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9434614-B2 |
| Application number | US-201113335890-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 22, 2011 |
| Priority date | Dec 23, 2010 |
| Publication date | Sep 6, 2016 |
| Grant date | Sep 6, 2016 |
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The present invention relates to a perovskite-type strontium titanate, wherein the strontium titanate is Y- and Ni-doped and has the general formula (Sr,Y)(Ti,Ni)O 3 . A method of preparing the perovskite-type strontium titanate and its use are also provided.
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What is claimed is: 1. A perovskite-type strontium titanate, wherein the strontium titanate is Y- and Ni-doped and has the general formula of (Sr a Y b ) d (Ti 1-c Ni c )O 3 , wherein a+b is greater than 1 and 0.8≦a≦1; 0<b≦0.2; 0<c≦0.1; and 1≦d≦1.2. 2. The perovskite-type strontium titanate of claim 1 , wherein a is from about 0.88 to about 0.98. 3. The perovskite-type strontium titanate of claim 1 , wherein b is from about 0.08 to about 0.12. 4. The perovskite-type strontium titanate of claim 1 , wherein c is from about 0.06 to about 0.08. 5. The perovskite-type strontium titanate of claim 1 having the formula (Sr 0.97 Y 0.10 )(Ti 0.94 Ni 0.06 )O 3 . 6. The perovskite-type strontium titanate of claim 1 having the formula (Sr 0.97 Y 0.10 )(Ti 0.92 Ni 0.08 )O 3 . 7. A catalyst comprising: a perovskite-type strontium titanate, wherein the strontium titanate is Y- and Ni-doped and has the general formula of (Sr a Y b ) d (Ti 1-c Ni c )O 3 , wherein a+b is greater than 1 and 0.8≦a≦1; 0<b≦0.2; 0<c≦0.1; and 1≦d≦1.2. 8. A method comprising: using a catalyst for autothermal reforming of a fuel, wherein the catalyst comprises a perovskite-type strontium titanate, wherein the strontium titanate is Y- and Ni-doped and has the general formula of (Sr a Y b ) d (Ti 1-c Ni c )O 3 , wherein a+b is greater than 1 and 0.8≦a≦1; 0<b≦0.2; 0<c≦0.1; and 1≦d≦1.2. 9. A method for autothermal reforming of a fuel, comprising contacting a catalyst with said fuel, wherein the catalyst comprises a perovskite-type strontium titanate, wherein the strontium titanate is Y- and Ni-doped and has the general formula of (Sr a Y b ) d (Ti 1-c Ni c )O 3 , wherein a+b is greater than 1 and 0.8≦a≦1; 0<b≦0.2; 0<c≦0.1; and 1≦d≦1.2. 10. The method of claim 9 , wherein the fuel is a diesel fuel. 11. The method of claim 9 , wherein the fuel comprises less than about 30 mol % aromatic compounds. 12. The method of claim 9 , wherein the fuel comprises less than about 50 ppm sulfur-containing compounds.
Perovskite-type · CPC title
X-ray diffraction · CPC title
Scanning electron microscopy; Transmission electron microscopy · CPC title
characterised by their physical properties · CPC title
Constitutive chemical elements of heterogeneous catalysts · CPC title
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