Systems and methods for producing hydrogen gas

Patent metadata

Field	Value
Publication number	US-9434612-B2
Application number	US-201213691552-A
Country	US
Kind code	B2
Filing date	Nov 30, 2012
Priority date	Nov 30, 2012
Publication date	Sep 6, 2016
Grant date	Sep 6, 2016

Abstract

Systems and methods for thermally decomposing hydrocarbon feedstock may comprise a hydrocarbon feedstock, a non-oxidizing carrier gas, one or more heat exchangers, and a reaction chamber. The carrier gas may be used to transfer heat to the hydrocarbon feedstock. The heat exchanger(s) may be configured to heat the carrier gas. And the reaction chamber may be configured to receive hydrocarbon feedstock and heated carrier gas. Inside the reaction chamber, the hydrocarbon feedstock and the heated carrier gas may mix with one another causing the thermal decomposition reaction. The thermal decomposition reaction occurs in a substantially oxidant-free environment thereby eliminating or greatly reducing the production of carbon oxide byproducts. Hydrogen gas may be separated from a gaseous product stream that is thereafter collected from the reaction chamber. A portion of the gaseous product stream may be thermally coupled to the carrier gas and may thereafter be recycled through the system.

First claim

The invention claimed is:

1. A method for thermally decomposing gaseous hydrocarbon feedstock, comprising:
heating a non-oxidative carrier gas with a heat exchanger such that the carrier gas if mixed with a volume of gaseous hydrocarbon feedstock would cause at least partial decomposition of the volume of gaseous hydrocarbon feedstock;
delivering a first volume of gaseous hydrocarbon feedstock into a reaction chamber;
delivering the carrier gas into the reaction chamber through one or more porous walls such that the carrier gas and the first volume of gaseous hydrocarbon feedstock mix within the reaction chamber and the carrier gas transfers heat to the first volume of gaseous hydrocarbon feedstock within the reaction chamber causing the decomposition of the first volume of gaseous hydrocarbon feedstock, wherein the decomposition reaction occurs in a substantially oxidant-free environment, and wherein the decomposition of the first volume of gaseous hydrocarbon feedstock results in a product comprising hydrogen gas and carbon substances;
removing at least a first portion of the carbon substances from the reaction chamber; and
delivering a portion of the first portion of the carbon substances back into the reaction chamber for use as a catalyst in a decomposition reaction of another-volume of gaseous hydrocarbon feedstock.

2. The method of claim 1 , further comprising:
collecting a first gaseous product stream, wherein the first gaseous product stream comprises hydrogen gas and carrier gas.

3. The method of claim 2 , further comprising:
heating at least a portion of the first gaseous product stream.

4. The method of claim 3 , wherein the first gaseous product stream further comprises hydrocarbons, and wherein the hydrocarbons are removed from the first gaseous product stream before completion of the heating of the portion of the first gaseous product stream.

5. The method of claim 3 , further comprising:
delivering a second volume of gaseous hydrocarbon feedstock into the reaction chamber;
delivering the portion of first gaseous product stream into the reaction chamber such that the portion of the first gaseous product stream and the second volume of gaseous hydrocarbon feedstock mix within the reaction chamber and the portion of the first gaseous product stream transfers heat to the second volume of gaseous hydrocarbon feedstock within the reaction chamber causing the decomposition of the second volume of gaseous hydrocarbon feedstock, and wherein the decomposition of the second volume of gaseous hydrocarbon feedstock results in a product comprising hydrogen gas and carbon substances; and
collecting a second gaseous product stream, wherein the second gaseous product stream comprises hydrogen gas and carrier gas.

6. The method of claim 1 , wherein the hydrocarbon feedstock comprises a compound with the formula C n H m , wherein n is 1, 2, 3 or 4, and m is independently selected from 2, 4, 6, 8 or 10.

7. The method of claim 6 , wherein the hydrocarbon feedstock comprises one or more of the following: CH 4 , C 2 H 2 , C 2 H 4 , C 2 H 6 , C 3 H 8 , and C 4 H 10 .

8. The method of claim 1 , wherein the hydrocarbon feedstock comprises natural gas.

9. The method of claim 1 , wherein the carrier gas is continuously delivered into the reaction chamber through the one or more porous walls.

10. The method of claim 1 , wherein substantially all of the heated carrier gas is delivered into the reaction chamber through the one or more porous walls.

11. The method of claim 1 , wherein the carrier gas permeates through the one or more porous walls.

12. The method of claim 3 , wherein heating the portion of the first gaseous product stream comprises:
transferring thermal energy to the portion of the first gaseous product stream using the heat exchanger.

13. A system for thermally decomposing gaseous hydrocarbon feedstock, comprising:
a non-oxidative carrier gas;
a first volume of gaseous hydrocarbon feedstock;
a carbon catalyst;
a heat exchanger configured to heat the carrier gas such that the carrier gas if mixed with a volume of gaseous hydrocarbon feedstock would cause at least partial decomposition of the volume of gaseous hydrocarbon feedstock; and
a reaction chamber comprising one or more porous walls, wherein the reaction chamber is configured to receive each of the first volume of gaseous hydrocarbon feedstock and the carrier gas such that the carrier gas mixes with the first volume of gaseous hydrocarbon feedstock within the reaction chamber, the reaction chamber being configured to receive the carrier gas being delivered through the one or more porous walls, wherein the carrier gas transfers heat to the first volume of gaseous hydrocarbon feedstock within the reaction chamber thereby causing the decomposition of the first volume of gaseous hydrocarbon feedstock to a product comprising hydrogen gas and carbon substances, and wherein the decomposition reaction occurs in a substantially oxidant free environment.

14. The system of claim 13 , further comprising a first gaseous product stream comprising hydrogen gas and carrier gas.

15. The system of claim 14 , wherein at least a portion of the first gaseous product stream is delivered to the heat exchanger and heated by the heat exchanger.

16. The system of claim 15 , wherein the first gaseous product stream further comprises hydrocarbons, and wherein the hydrocarbons are removed from the first gaseous product stream before completion of the heating of the portion of the first gaseous product stream.

17. The system of claim 15 , wherein a second volume of gaseous hydrocarbon feedstock is delivered to the reaction chamber such that the second volume of gaseous hydrocarbon feedstock mixes with a portion of the first gaseous product stream that also is delivered to the reaction chamber and the portion of the first gaseous product stream transfers heat to the second volume of gaseous hydrocarbon feedstock within the reaction chamber causing the decomposition of the second volume of gaseous hydrocarbon feedstock, and wherein the decomposition of the second volume of gaseous hydrocarbon feedstock results in a product comprising hydrogen gas and carbon substances.

18. The system of claim 13 , wherein the hydrocarbon feedstock comprises a compound with the formula C n H m , wherein n is 1, 2, 3 or 4, and m is independently selected from 2, 4, 6, 8 or 10.

19. The system of claim 18 , wherein the hydrocarbon feedstock comprises one or more of the following: CH 4 , C 2 H 2 , C 2 H 4 , C 2 H 6 , C 3 H 8 , and C 4 H 10 .

20. The system of claim 18 , wherein the hydrocarbon feedstock comprises a mixture of two or more of the following: CH 4 , C 2 H 2 , C 2 H 4 , C 2 H 6 , C 3 H 8 , and C 4 H 10 .

21. The system of claim 13 , wherein the hydrocarbon feedstock comprises natural gas.

22. The system of claim 13 , wherein the carrier gas is continuously delivered into the reaction chamber through the one or more porous walls.

23. The system of claim 13 , wherein substantially all of the heated carrier gas is delivered into the reaction chamber through the one or more porous walls.

24. The system of claim 13 , wherein the one or more porous walls are configured to allow the carrier gas to permeate into the reaction chamber.

Assignees

• Elwha Llc
• Elwha Llc

Inventors

• Hyde Roderick A
• Wood Jr Lowell L

Classifications

• B01J7/00

  Apparatus for generating gases (production of inert gas mixtures B01J19/14; for generating specific gases, see the relevant subclasses, e.g. C01B, C10J {; in "air bags" on vehicles B60R21/26; for starter gas F02C7/26; blasting cartridges for producing gas under pressure F42B3/04}) · CPC title

• C01B2203/0833

  Heating by indirect heat exchange with hot fluids, other than combustion gases, product gases or non-combustive exothermic reaction product gases · CPC title

• C01B2203/1235

  Hydrocarbons · CPC title

• C01B2203/0277

  containing a catalytic decomposition step · CPC title

• C01B2203/1247

  Higher hydrocarbons · CPC title