Method for preparing a super absorbent polymer

Patent metadata

Field	Value
Publication number	US-9433921-B2
Application number	US-201414911220-A
Country	US
Kind code	B2
Filing date	Jul 17, 2014
Priority date	Aug 27, 2013
Publication date	Sep 6, 2016
Grant date	Sep 6, 2016

Abstract

The present invention relates to a method for preparing a super absorbent polymer. The method for preparing a super absorbent polymer according to the present invention comprises the steps of: carrying out a thermal polymerization or a photopolymerization of a monomer composition including a water-soluble ethylene-based unsaturated monomer and a polymerization initiator to form a hydrogel polymer; drying the hydrogel polymer; pulverizing the dried polymer; mixing a fine powder having a particle diameter of 180 μm or less and a polymer having a particle diameter of 300 μm or more among the pulverized polymer; and adding steam to the mixture to carry out a reassembling. According to the present invention, the super absorbent polymer having a high fine powder aggregation strength can be obtained.

First claim

What is claimed is:

1. A method for preparing a super absorbent polymer, comprising the steps of:
carrying out a thermal polymerization or a photopolymerization of a monomer composition including a water-soluble ethylene-based unsaturated monomer and a polymerization initiator to form a hydrogel polymer;
drying the hydrogel polymer;
pulverizing a dried polymer;
mixing a fine powder having a particle diameter of 180 μm or less and a polymer having a particle diameter of 300 μm or more among a pulverized polymer;
and adding steam to a mixture to carry out a reassembling.

2. The method according to claim 1 , wherein a temperature of the steam is 100° C. to 200° C.

3. The method according to claim 1 , wherein the reassembling step is carried out by adding the steam in an amount of 30 to 300 parts by weight, based on 100 parts by weight of the entire mixture to which the fine powder having the particle diameter of 180 μm or less and the polymer having the particle diameter of 300 μm or more are added.

4. The method according to claim 1 , wherein the reassembling step is carried out by mixing the fine powder having the particle diameter of 180 μm or less in an amount of 50 to 98% by weight and the polymer having the particle diameter of 300 μm or more in an amount of 2 to 50% by weight.

5. The method according to claim 1 , wherein the reassembling step is carried out by further mixing water.

6. The method according to claim 1 , wherein after the reassembling step, the method further comprises a step of drying a reassembled polymer.

7. The method according to claim 6 , wherein after the step of drying the reassembled polymer, the method further comprises a step of pulverizing or classifying a dried reassembled polymer.

8. The method according to claim 7 , further comprising a step of surface-crosslinking the pulverized or classified reassembled polymer.

9. The method according to claim 7 , wherein a weight ratio of particles of 180 μm or below is less than about 10%, based on the entire weight of the reassembled polymer after the pulverization.

Assignees

• Lg Chemical Ltd

Inventors

• Ryu Chul Hee
• Kim Gi Cheul

Classifications

• C08F2/00 Primary

  Processes of polymerisation · CPC title

• C08J3/075

  Macromolecular gels · CPC title

• B01J20/267 Primary

  Cross-linked polymers · CPC title

• C08F2/10

  Aqueous solvent · CPC title

• C08L101/14

  the macromolecular compounds being water soluble or water swellable, e.g. aqueous gels · CPC title