Conversion of plastics to olefin and aromatic products with product recycle

Patent metadata

Field	Value
Publication number	US-9428695-B2
Application number	US-201313764932-A
Country	US
Kind code	B2
Filing date	Feb 12, 2013
Priority date	Feb 12, 2013
Publication date	Aug 30, 2016
Grant date	Aug 30, 2016

Abstract

A method of producing olefins and aromatic compounds from a feedstock is accomplished by introducing a hydrocarbon feedstock and a catalyst composition within a reactor. At least a portion of the reactor is at a reactor temperature of from 470° C. to 730° C. The catalyst composition is comprised of a fluidized catalytic cracking (FCC) catalyst and a ZSM-5 zeolite catalyst, wherein the amount of ZSM-5 zeolite catalyst makes up from greater than 0 wt. % of the total weight of the FCC catalyst and the ZSM-5 zeolite catalyst. At least a portion of the feedstock is converted to products of at least one of olefins and aromatic compounds within the reactor, with at least some of the products being contained in a liquid product stream. At least a portion of the liquid product stream is directed to different downstream processes to increase production of at least one of olefins and aromatic compounds.

First claim

We claim:

1. A method of producing olefins and aromatic compounds from a feedstock, the method comprising:
contacting a plastic feedstock and a catalyst composition at a temperature of from 420° C. to 730° C. within a reactor, the catalyst composition comprising a non-fresh fluidized catalytic cracking (FCC) catalyst and a ZSM-5 zeolite catalyst, the amount of ZSM-5 zeolite catalyst of the catalyst composition makes up from 10 wt. % to 50 wt. % of the total weight of the FCC catalyst and the ZSM-5 zeolite catalyst to simultaneously increase production of both light gas olefins and aromatics, the feedstock and the catalyst composition being at a catalyst-to-feed ratio of from 6 or greater;
allowing at least a portion of the feedstock to be converted to products of olefins and aromatic compounds within the reactor, at least some of the products being contained in a liquid product stream; and
directing at least a portion of the liquid product stream to one or more of the following (A) through (E), wherein:
(A) is a catalytic reformer under conditions suitable for producing aromatics to form reformed products containing aromatic compounds and non-aromatic compounds, and directing the reformed products to a separating unit to provide an aromatic-rich separated product and a non-aromatic-rich separated product from at least a portion of the reformed products and recycling the non-aromatic-rich product to the reactor;
(B) is a separation unit to provide an aromatic-rich separated product and a non-aromatic-rich separated product, the non-aromatic-rich separated product containing at least one of paraffins, iso-paraffins, and naphthenes and directing at least a portion of the non-aromatic-rich separated product to the reactor;
(C) is a hydroprocessing unit under conditions suitable for hydroprocessing to provide a hydroprocessed product and recycling at least a portion of the hydroprocessed product to the reactor;
(D) is a separation unit to provide an aromatic-rich separated product and a non-aromatic-rich separated product, and directing at least a portion of the non-aromatic-rich separated product as a feed to a hydroprocessing unit under conditions suitable for hydroprocessing to provide a hydroprocessed product and recycling at least a portion of the hydroprocessed product to the reactor; and
(E) is a pyrolysis reactor to provide a liquid and gas pyrolysis product stream of which the liquid product is separated into an aromatics-rich product and a non-aromatics-rich product, the non-aromatic-rich product being further hydroprocessed and then recycled back to the reactor.

2. The method of claim 1 , wherein:
the FCC catalyst is comprised of at least one of an X-type zeolite, a Y-type zeolite, mordenite, faujasite, nano-crystalline zeolites, MCM mesoporous materials, SBA-15, a silico-alumino phosphate, a gallophosphate, and a titanophosphate.

3. The method of claim 1 , wherein:
the amount of ZSM-5 zeolite catalyst of the catalyst composition makes up from 30 wt. % to 45 wt. % of the total weight of the FCC catalyst and the ZSM-5 zeolite catalyst.

4. The method of claim 1 , wherein:
the temperature is from 570° C. to 680° C.

5. The method of claim 1 , wherein:
said temperature is at least one of 1) a time-interval average catalyst bed temperature of from 420° C. to 730° C. wherein the time interval is 3 minutes or less from the start of the reaction; 2) a temperature in the reactor of from 420° C. to 730° C. at at least one location that is from 0.3 L or less from the at least one inlet where the feedstock and the catalyst composition are introduced, where L is the length of the reactor flow path; and 3) a weight-averaged catalyst bed temperature in the reactor of from 420° C. to 730° C. weight-averaged at two or more locations that is from 0.3 L or less and/or to 0.3 L or greater from the at least one inlet where the feedstock and the catalyst composition are introduced, where L is the length of the reactor flow path.

6. The method of claim 1 , wherein:
the feedstock comprises at least one of polyolefins, polyethylene, polypropylene, polystyrene, polyethylene terephthalate (PET), polyvinyl chloride (PVC), polyamide, polycarbonate, polyurethane, polyester, natural and synthetic rubber, tires, filled polymers, composites, plastic alloys, and plastics dissolved in a solvent.

7. The method of claim 1 , wherein:
the reactor is at least one of a fluidized bed reactor, bubbling bed reactor, slurry reactor, rotating kiln reactor, and packed bed reactor.

8. The method of claim 1 , wherein:
at least a portion of the liquid product stream is directed to (A).

9. The method of claim 1 , wherein:
at least a portion of the liquid product stream is directed to (B).

10. The method of claim 1 , wherein:
at least a portion of the liquid product stream is directed to (C).

11. The method of claim 1 , wherein:
at least a portion of the liquid product stream is directed to (D).

12. The method of claim 1 , wherein:
at least a portion of the liquid product stream is directed to (E).

13. A method of producing olefins and aromatic compounds from a plastic feedstock, the method comprising:
contacting a plastic feedstock and a catalyst composition at a temperature of from 420° C. to 730° C. within a reactor, said temperature being at least one of 1) a time-interval average catalyst bed temperature of from 420° C. to 730° C. wherein the time interval is 3 minutes or less from the start of the reaction; 2) a temperature in the reactor of from 420° C. to 730° C. at at least one location that is from 0.3 L or less from the at least one inlet where the plastic feedstock and the catalyst composition are introduced, where L is the length of the reactor flow path; and 3) a weight-averaged catalyst bed temperature in the reactor of from 420° C. to 730° C. weight-averaged at two or more locations that is from 0.3 L or less and/or to 0.3 L or greater from the at least one inlet where the plastic feedstock and the catalyst composition are introduced, where L is the length of the reactor flow path, and wherein the catalyst composition comprises a non-fresh fluidized catalytic cracking (FCC) catalyst and a ZSM-5 zeolite catalyst, wherein the amount of ZSM-5 zeolite catalyst makes up from 10 wt. % to 50 wt. % of the total weight of the non-fresh FCC catalyst and the ZSM-5 zeolite catalyst to simultaneously increase production of both light gas olefins and aromatics, the feedstock and the catalyst composition being at a catalyst-to-feed ratio of from 6 or greater;
allowing at least a portion of the plastic feedstock to be converted to products of at least one of olefins and aromatic compounds within the reactor, at least some of the products being contained in a liquid product stream; and
directing at least a portion of the liquid product stream to one or more of the following (A)-(E), wherein:
(A) is a catalytic reformer under conditions suitable for producing aromatics to form reformed products containing aromatic compounds and non-aromatic compounds, and directing the reformed products to a separating unit to provide an aromatic-rich separated product and a non-aromatic-rich separated product from at least a portion of the reformed products and recycling the non-aromatic-rich product to the reactor;
(B) is a separation unit to provide an aromatic-rich separated product and a non-aromatic-rich separated product, and directing at least a portion of the non-aromatic-rich separated product to the reactor;
(C) is a hydroprocessing unit under conditions suitable for hydroprocessing to provide a hydroprocessed product and recycling at least a portion of the hydroprocessed product to

Assignees

• Saudi Basic Ind Corp

Inventors

• Narayanaswamy Ravichander
• Ramamurthy Krishna Kumar
• Sreenivasan P S

Classifications

• C10G69/04

  including at least one step of catalytic cracking in the absence of hydrogen · CPC title

• B01J29/82

  Phosphates {(B01J29/005 takes precedence)} · CPC title

• B01J29/18

  of the mordenite type · CPC title

• B01J29/90

  Regeneration or reactivation · CPC title

• B01J29/40

  of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively · CPC title