Semi-crystalline semi-aromatic polyamide

Patent metadata

Field	Value
Publication number	US-9428612-B2
Application number	US-16160207-A
Country	US
Kind code	B2
Filing date	Jan 23, 2007
Priority date	Jan 26, 2006
Publication date	Aug 30, 2016
Grant date	Aug 30, 2016

Abstract

The invention relates to a semi-crystalline semi-aromatic polyamide comprising A-A-B-B units derived from (a) dicarboxylic acids consisting of a mixture of aromatic dicarboxylic acid and aliphatic dicarboxylic acid and (b) diamines consisting of a mixture of long chain aliphatic diamine and short chain aliphatic diamine, wherein (a-i) the aromatic dicarboxylic acid consists for at least 80 mole % of terephthalic acid, and (a-ii) the aliphatic dicarboxylic acid constitutes at least 5 mole % of the dicarboxylic acids, (b-i) the short chain aliphatic diamine constitutes at least 10 mole % of the diamines, and (c) the aromatic dicarboxylic acid and the long chain aliphatic diamine constitute 60-90 mole % of the total molar amount of dicarboxylic acids and diamines.

First claim

The invention claimed is:

1. A semi-crystalline semi-aromatic polyamide comprising units derived from diamines (A-A units) comprising aliphatic diamine and from dicarboxylic acids (B-B units) comprising terephthalic acid, wherein:
(a) the dicarboxylic acids consist of a mixture of aromatic dicarboxylic acid and aliphatic dicarboxylic acid, wherein
(i) the aromatic dicarboxylic acid consists for at least 80 mole % of terephthalic acid, relative to the total amount of aromatic dicarboxylic acid, and
(ii) the molar amount of the aliphatic dicarboxylic acid is at least 5 mole %, relative to the total amount of dicarboxylic acids, and the aliphatic dicarboxylic acid is chosen from the group consisting of adipic acid (C6), suberic acid (C8), sebacic acid (C10), dodecanoic acid (C12) and mixtures thereof,

(b) the diamines consist of a mixture of long chain aliphatic diamine with 6-12 carbon atoms and short chain aliphatic diamine selected from the group consisting of 1,4 -butane diamine, 1,5 -pentanediamine and mixtures thereof, wherein the molar amount of the short chain aliphatic diamine is at least 10 mole %, relative to the total amount of diamines, and
(c) the sum of the molar amount of the aromatic dicarboxylic acid and the long chain aliphatic diamine is 60-90 mole %, relative to the total molar amount of dicarboxylic acids and diamines.

2. The semi-aromatic polyamide according to claim 1 , wherein the long chain aliphatic diamine is chosen from the group consisting of hexane diamine, 2 -methyl-, 1 ,5 -pentanediamine, C8 -diamine, C9 -diamine, 2 -methyl- ,1,8 -octanediamine, C10 -diamine, C11 -diamine, C12 -diamine and mixtures thereof, preferably hexane diamine, C8 -diamine, C9 -diamine, C10 -diamine and mixtures thereof.

3. The semi-aromatic polyamide according to claim 1 , wherein the polyamide comprises units other than A-A and B-B units, in an amount of at most 10 mass %, relative to the total molar mass of the polyamide.

4. The semi-aromatic polyamide according to claim 1 , wherein the short chain diamine consists of 1,4 -butane diamine.

5. A process for the preparation of a semi-aromatic polyamide comprising a polymerization step wherein dicarboxylic acids comprising terephthalic acid and diamines comprising aliphatic diamine are cocondensed to form a polyamide comprising A-A units and B-B units, and wherein the dicarboxylic acids and diamines have a composition according to claim 1 .

6. The process according to claim 5 , wherein the polymerization step is a melt or solution polymerization step.

7. A polymer composition comprising a semi-aromatic polyamide according to claim 1 and at least one additive.

8. A molded part which comprises the polymer composition according to claim 7 .

9. A molded part which comprises the semi-aromatic polyamide according to claim 1 .

10. The molded part according to claim 9 , wherein the molded part is an automotive engine part, an electric or electronic component, an aerospace part or a part for household applications.

Assignees

• Rulkens Rudy
• Crombach Robert C B
• Dsm Ip Assets Bv

Inventors

• Rulkens Rudy
• Crombach Robert C B

Classifications

• C08G69/26 Primary

  derived from polyamines and polycarboxylic acids · CPC title

• C08L77/06

  Polyamides derived from polyamines and polycarboxylic acids (C08L77/10 takes precedence) · CPC title

• C08G69/265 Primary

  from at least two different diamines or at least two different dicarboxylic acids · CPC title

• C08G81/028

  containing polyamide sequences · CPC title

• C08G69/02

  Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids · CPC title