Aromatic polycarbonate resin composition

Patent metadata

Field	Value
Publication number	US-9428608-B2
Application number	US-201314442892-A
Country	US
Kind code	B2
Filing date	Nov 15, 2013
Priority date	Nov 17, 2012
Publication date	Aug 30, 2016
Grant date	Aug 30, 2016

Abstract

The present invention provides an aromatic polycarbonate resin composition having a high molecular weight and less amount of a heterologous structure, retaining good qualities, and excellent in thermal stability, and an improved preparation process thereof.

First claim

The invention claimed is:

1. An aromatic polycarbonate resin composition which comprises a structural unit represented by the following formula (II), and at least one of structural units represented by the following formulae (1) and (2), wherein either of the structural units represented by the formulae (1) and (2) is contained in an amount of 2000 ppm or less in terms of a diphenolic acid, and a cyclic carbonate represented by the following formula (h3) is contained in an amount of 3000 ppm or less:

wherein R 1 and R 2 each independently represent a halogen atom, an alkyl group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, a cycloalkyl group having 6 to 20 carbon atoms, an aryl group having 6 to 20 carbon atoms, a cycloalkoxy group having 6 to 20 carbon atoms or an aryloxy group having 6 to 20 carbon atoms, p and q each represent an integer of 0 to 4, X represents a single bond or a group selected from the group of the following (II′);

wherein R 3 and R 4 each independently represent a hydrogen atom, an alkyl group having 1 to 10 carbon atoms or an aryl group having 6 to 10 carbon atoms, or R 3 and R 4 may be bonded to each other to form an aliphatic ring;

wherein X is the same as defined in the formula (II);

wherein Ra and Rb each independently represent a hydrogen atom, a halogen atom, a linear or branched alkyl group having 1 to 30 carbon atoms which may contain an oxygen atom or a halogen atom, a cycloalkyl group having 3 to 30 carbon atoms which may contain an oxygen atom or a halogen atom, an aryl group having 6 to 30 carbon atoms which may contain an oxygen atom or a halogen atom, or an alkoxy group having 1 to 15 carbon atoms which may contain an oxygen atom or a halogen atom, or Ra and Rb may be bonded to each other to form a ring.

2. The aromatic polycarbonate resin composition according to claim 1 , wherein the structural unit represented by the formula (1) is contained in an amount of 2000 ppm or less in terms of a diphenolic acid.

3. The aromatic polycarbonate resin composition according to claim 1 , wherein the structural units represented by the formulae (1) and (2) are each contained in an amount of 2000 ppm or less in terms of a diphenolic acid.

4. The aromatic polycarbonate resin composition according to claim 1 , wherein the structural units represented by the formulae (1) and (2) are contained in total in an amount of 5000 ppm or less in terms of a diphenolic acid.

5. The aromatic polycarbonate resin composition according to claim 1 , wherein a structural unit represented by the following formula (3) is further contained in an amount of 150 ppm or less in terms of a diphenolic acid:

wherein X is the same as defined in the formula (II).

6. The aromatic polycarbonate resin composition according to claim 1 , which has a weight average molecular weight (Mw) of 30,000 to 100,000.

7. The aromatic polycarbonate resin composition according to claim 1 , wherein an N value (a structural viscosity index) represented by the following numerical formula (1) is 1.25 or less:
N value=(log( Q 160 value)−log( Q 10 value))/(log 160−log 10)  (1).

8. The aromatic polycarbonate resin composition according to claim 1 , wherein a molecular weight (Mw) retention ratio after a heat detention test (at 360° C. for 60 minutes) is 50% or more.

9. A method for preparing the aromatic polycarbonate resin composition as set forth in claim 1 , which comprises
a highly polymerizing step of reacting an aromatic polycarbonate prepolymer and an aliphatic diol compound represented by the following formula (g2) in the presence of a transesterification catalyst to obtain a highly polymerized aromatic polycarbonate resin, and
a cyclic carbonate-removing step of removing at least part of the cyclic carbonate by-produced in the highly polymerizing step out of the reaction system:

wherein Ra and Rb each independently represent a hydrogen atom, a halogen atom, a linear or branched alkyl group having 1 to 30 carbon atoms which may contain an oxygen atom or a halogen atom, a cycloalkyl group having 3 to 30 carbon atoms which may contain an oxygen atom or a halogen atom, an aryl group having 6 to 30 carbon atoms which may contain an oxygen atom or a halogen atom, or an alkoxy group having 1 to 15 carbon atoms which may contain an oxygen atom or a halogen atom, or Ra and Rb may be bonded to each other to form a ring, R 5 to R 8 each independently represent a hydrogen atom, a halogen atom or a linear or branched alkyl group having 1 to 5 carbon atoms; and n represents an integer of 0 to 30.

10. The preparation process according to claim 9 , wherein the aliphatic diol compound represented by the formula (g2) is a compound represented by the following formula (g3):

wherein Ra and Rb each independently represent a hydrogen atom, a halogen atom, a linear or branched alkyl group having 1 to 30 carbon atoms which may contain an oxygen atom or a halogen atom, a cycloalkyl group having 3 to 30 carbon atoms which may contain an oxygen atom or a halogen atom, an aryl group having 6 to 30 carbon atoms which may contain an oxygen atom or a halogen atom, or an alkoxy group having 1 to 15 carbon atoms which may contain an oxygen atom or a halogen atom, or Ra and Rb may be bonded to each other to form a ring.

11. The preparation process according to claim 10 , wherein the aliphatic diol compound is selected from the group consisting of 2-butyl-2-ethylpropane-1,3-diol, 2,2-diisobutylpropane-1,3-diol, 2-ethyl-2-methylpropane-1,3-diol, 2,2-diethylpropane-1,3-diol, and 2-methyl-2-propylpropane-1,3-diol.

Assignees

• Mitsubishi Gas Chemical Co

Inventors

• Isahaya Yoshinori
• Hirashima Atsushi
• Harada Hidefumi
• Ito Maki
• HAYAKAWA Jun-ya
• Isobe Takehiko
• Tokutake Taichi
• Shinkai Yousuke

Classifications

• C08G64/06 Primary

  not containing aliphatic unsaturation · CPC title

• C08G64/307

  and phenols · CPC title

• C08G64/42

  Chemical after-treatment · CPC title

• C08G64/406

  Purifying; Drying · CPC title