Multistage drawing process for drawing polymeric elongated objects

Patent metadata

Field	Value
Publication number	US-9428599-B2
Application number	US-201213983793-A
Country	US
Kind code	B2
Filing date	Feb 17, 2012
Priority date	Feb 24, 2011
Publication date	Aug 30, 2016
Grant date	Aug 30, 2016

Abstract

The invention relates to a multistage drawing process for the drawing of polymeric elongated objects, containing a first drawing stage and a final drawing stage and optionally containing at least one intermediate drawing stage subsequent to the first drawing stage and prior to the final drawing stage, comprising in the following order the steps of: a. providing a polymeric elongated feed object; b. drawing the elongated object in the first drawing stage with a draw ratio of between 30% and 90% of the maximum drawing ratio achievable in the first drawing step; c. optionally drawing the elongated object in the at least one intermediate drawing stage with a draw ratio of between 30% and 90% of the maximum drawing ratio achievable in the at least one intermediate drawing step; d. drawing the elongated object in the final drawing stage with a draw ratio of at most 5, preferably of at most 3.

First claim

The invention claimed is:

1. A multistage drawing process for drawing polymeric elongated objects, containing a first drawing stage and a final drawing stage and optionally containing at least one intermediate drawing stage subsequent to the first drawing stage and prior to the final drawing stage, the process comprising in the following order the steps of:
(a) providing a polymeric elongated feed object having a tenacity of between 0.025 GPa and 1 GPa;
(b) drawing the elongated object in the first drawing stage with a draw ratio of between 30% and 90% of the maximum drawing ratio achievable in the first drawing step;
(c) optionally drawing the elongated object in the at least one intermediate drawing stage with a draw ratio of between 30% and 90% of the maximum drawing ratio achievable in the at least one intermediate drawing step;
(d) drawing the elongated object in the final drawing stage with a draw ratio of at most 5 to yield a polymeric elongated object having a tenacity greater than 1.5 GPa.

2. The process of claim 1 , wherein the polymeric elongated object is a fiber.

3. The process of claim 2 , wherein the fiber has a length and transverse dimensions, and wherein a ratio of a highest transverse dimension of the fiber to a lowest transverse dimension of the fiber is between 1 and 5.

4. The process of claim 1 , wherein the elongated object is a tape.

5. The process of claim 4 , wherein the tape has a width of between 2 mm and 2000 mm.

6. The process of claim 1 , wherein the elongated object is a solid object having a polymer solvent content of at most 5 wt % based on the total weight of the polymer.

7. The process of claim 1 , wherein the elongated feed object is a calendared solid state tape.

8. The process of claim 1 , wherein the elongated object is a polyolefin elongated object.

9. The process of claim 1 , wherein the elongated object is a high or ultrahigh molecular weight polyethylene elongated object.

10. The process of claim 1 , wherein the elongated feed object is drawn in the first drawing stage with a draw ratio of between 35% and 80%.

11. The process of claim 1 , wherein the drawing in the final drawing stage of the elongated object having a titer (T) and a breakload (BL) is carried out with a drawing force of between 8% and 20% of the breakload (BL) of the elongated object obtained by carrying out the final drawing stage.

12. The process of claim 1 , wherein step (d) is practiced by drawing the elongated object in the final drawing stage with a draw ratio of at most 3.

13. The process of claim 3 , wherein the ratio of the highest transverse dimension to the lowest transverse dimension of the fiber is between 1 and 3.

14. The process of claim 1 , wherein the elongated objected obtained in step (d) has a tensile strength between 1.5 GPa and 3 GPa, a tensile modulus between 80 and 200 GPa, and an elongation at break of at most 2.5%.

Assignees

• Steeman Reinard Jozef Maria
• Simmelink Joseph Arnold Paul Maria
• Dsm Ip Assets Bv

Inventors

• Steeman Reinard Jozef Maria
• Simmelink Joseph Arnold Paul Maria

Classifications

• C08F110/02 Primary

  Ethene · CPC title

• D02J1/228

  Stretching in two or more steps, with or without intermediate steps · CPC title

• B29D99/0078

  Producing filamentary materials · CPC title

• D01D5/12 Primary

  Stretch-spinning methods ({D01D5/098 takes precedence} finishing by stretching D02J1/22) · CPC title

• B29D7/01

  Films or sheets · CPC title