Continuous catalyst regeneration in a fluidized bed reactor

Patent metadata

Field	Value
Publication number	US-9427718-B2
Application number	US-201214232476-A
Country	US
Kind code	B2
Filing date	Jul 9, 2012
Priority date	Jul 12, 2011
Publication date	Aug 30, 2016
Grant date	Aug 30, 2016

Abstract

A catalytic reactor including a chamber ( 1 ) and separation means ( 2 ) arranged inside the chamber ( 1 ), said separation means defining at least one reaction area ( 3 ) and at least one regeneration area ( 4 ), the reaction area ( 3 ) being supplied with a reaction flow ( 15, 16 ) and connected, at the outlet thereof, to a first gas tapping device ( 13 ), the regeneration area ( 4 ) being supplied with a regeneration flow ( 17 ) and connected, at the outlet thereof, to a second gas tapping device ( 10 ), the reactor being suitable for including a fluidized bed of catalyst particles ( 5 ) in the reaction area ( 3 ), the separation means ( 2 ) enabling the catalyst particles to pass from the reaction area ( 3 ) to the regeneration area ( 4 ), and the reactor making it possible to move catalyst particles into the regeneration area ( 4 ) so as to enable the return thereof to the reaction area ( 3 ).

First claim

The invention claimed is:

1. A chemical reaction process comprising concomitantly:
feeding by a reaction stream of a fluidized bed of catalyst particles into a reaction zone disposed in a chamber of a reactor,
withdrawing a stream comprising reaction products at an outlet of the reaction zone,
passing, using separating means, the catalyst particles of the fluidized bed from the reaction zone to a regeneration zone disposed inside the chamber of the reactor,
feeding the regeneration zone by a regeneration stream,
regenerating the catalyst particles and pneumatically entraining the catalyst particles into the regeneration zone,
withdrawing an exhaust gas at the outlet of the regeneration zone, and
returning the entrained catalyst particles to the reaction zone;
wherein the deactivation time of the catalyst is from 1 to 20 times greater than regeneration time, the deactivation time being a time when the catalyst particles lose 25% of their initial efficiency and the regeneration time being a time from the deactivation time until the catalyst particles regain up to about 100% of said initial efficiency; wherein the separation means comprises a tubular wall and wherein the reaction zone is disposed outside the tubular wall and the regeneration zone is disposed inside the tubular wall.

2. The process as claimed in claim 1 , wherein the stream of catalyst particles from the reaction zone to the regeneration zone is regulated by the injection of a backpressure gas.

3. The process as claimed in claim 1 , wherein the regeneration stream comprises oxygen.

4. The process as claimed in claim 1 , which is:
a process for dehydrating glycerol to acrolein; or
a process for dehydrating lactic acid to acrylic acid; or
a process for dehydrating 3-hydroxypropionic acid to acrylic acid;
a process for dehydrating 3-hydroxyisobutyric acid to methacrylic acid; or
a process for dehydrating 2-hydroxyisobutyric acid to methacrylic acid; or
a process for selective oxidation such as the oxidation of methanol to formaldehyde or dimethoxymethane; the oxidation of ethanol to acetaldehyde or to diethoxyethane; the oxidation of ortho-xylene or naphthalene to phthalic anhydride, or the oxidation of benzene, butene, butanol, or butane to maleic anhydride;
a process for oxidizing propylene to acrolein, and isobutene or tert-butanol to methacrolein; or
a process for oxidizing acrolein to acrylic acid, and methacrolein to methacrylic acid.

5. The process as claimed in claim 3 , wherein the reaction stream comprises oxygen.

Assignees

• Dubois Jean-Luc
• Patience Grégory
• Arkema France

Inventors

• Dubois Jean-Luc
• Patience Grégory

Classifications

• B01J8/386

  internally, i.e. the particles rotate within the vessel · CPC title

• C07C51/377

  by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups {(C07C51/36 - C07C51/373 take precedence)} · CPC title

• C07C51/313

  with molecular oxygen · CPC title

• C07C51/235

  of —CHO groups or primary alcohol groups · CPC title

• B01J2208/0084

  inside the bed, e.g. baffles · CPC title